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Contract 2018-15 Phase II Environmental Site Assessment (ESA) Report Cathedral Lane and Max Hooks Road City of Clermont/West WWTF Clermont, Lake County, FL E Sciences Project No. 1-0888-017 October 20, 2009 ENGINEERING : =- ces ENVIRONMENTAL ECOLOGICAL Prepared for: Ms. Michelle Wilkinson Lake County Attorney's Office P.O. Box 7800 Tavares, Florida 32778 34 East Pine Street• Orlando. FL 32801 •Tel 407.481.9006 • Fax 407.481.9627 •WIAN/esciencesinc.com r ENGINEERING Lqamari cos ENVIRONMENTAL ECOLOGICAL 1 October 20,2009 Ms. Michelle Wilkinson Property Management Agent Lake County Attorney's Office P.O. Box 7800 Tavares,FL 32778 Subject: Phase II Environmental Site Assessment(ESA)Report City of Clermont/West WWTF Cathedral Lane and Max Hooks Road Clermont, Lake County,Florida E Sciences Project 1-0888-017-02 Dear Ms. Wilkinson, E Sciences, Incorporated (E Sciences) is pleased to submit this Phase 11 ESA report summarizing the soil and groundwater sampling activities conducted at the above referenced site. The environmental sampling activities were performed in accordance with E Sciences proposal dated September 9,2009. If you have any question or comments regarding the scope of work, please call either of the undersigned at(407)481-9006. Sincerely, E SCIENCES,INC. )4411/4.... Lora J.Hendrick Jeffrey J. Peters,P.G. Staff Scientist Director,Environmental Services P:lProjecrs11-800-89911-0888-01715_deliverables1Phase IIIPhase 11 Report Phase 11 ESA.doc E Sciences, INCORPORATED 34 E, Pine Street•Orlando, FL 32801 ph 407-481-9006 tax 407/481-9627 www.esciencesinc.com TABLE OF CONTENTS 1.0 BACKGROUND 1 2.0 ASSESSMENT ACTIVITIES 3 2.1 Soil Assessment Activities 3 2.2 Groundwater Assessment Activities 3 3.0 RESULTS 5 3.1 Lithology 5 3.2 Soil Laboratory Results 5 3.3 Groundwater Laboratory Results 5 4.0 CONCLUSIONS AND RECOMMENDATIONS 6 Figures: Figure 1 —Site Location Map Figure 2—USGS Topographic Map Figure 3—2007 Aerial Photograph Figure 4—Site Map Figure 5—Groundwater Contour Map(10-08-09) Figure 6—Soil Quality Map(09-22-09) Figure 7—Groundwater Quality Map- VOCs/Semi Volatile Compounds(09-21 &22-2009) Figure 8—Groundwater Quality Map-Nitrates/Metals(09-21 & 22-09 Tables: Table 1 —Soil Analytical Summary- Metals Table 2—Groundwater Analytical Summary-BTEX-Naphthalenes Table 3 —Groundwater Analytical Summary- PAHs Table 4—Groundwater Analytical Summary- Metals Appendices: Appendix A—Background data from ABB 1993 Report Appendix B—Soil Boring Logs Appendix C—Calibration Logs/Groundwater Sampling Logs Appendix D—Laboratory Analytical Report&Chain of Custody Documentation 4 Phase II Environmental Site Assessment October 21,2009 City of Clermont/West WWTF Page 1 Clermont,Lake County,Florida E Sciences Project No. 1-0888-017-02 1.0 BACKGROUND E Sciences was contracted by the Lake County Attorney's Office to conduct a Phase II Environmental Site Assessment(Phase II ESA)on±143 acres located at the northwest corner of the intersection of Cathedral Lane and Max Hooks Road in Clermont, Lake County, Florida(the Site). The Site lies in Sections 21, 22, 27, & 28 Township 22 South and Range 25 East, as referenced on the USGS 7.5 Minute "Clermont West, FL" quadrangle map (Figure 2). A 2007 aerial photograph of the Site is provided as Figure 3. The purpose of this Phase II ESA was to evaluate the quality of the soil beneath the Site, and the groundwater quality along the perimeter and adjacent to the Site, as identified in our Phase I ESA for the property dated December 10, 2008. E Sciences identified the following Recognized Environmental Conditions (RECs) in our prior Phase I ESA: • A former dump facility (Old City of Clermont Dump) is located approximately 800 feet southeast of the Site and operated between the years 1970 and 1975. According to a Phase II Site Inspection Report for the Clermont Dump facility (Clermont Dump), completed in March 1993 by ABB Environmental Services, Inc. (ABB), several complaints from nearby residents regarding dumping activities were reported to the FDEP. According to the Phase II Site Inspection Report, soil and groundwater sampling was completed on the dump site and in the immediate vicinity of the site in 1993. Several contaminants in the monitoring wells sampled (associated with the dumping activities) exceeded the State and Federal maximum contaminant levels (MCLS) for groundwater, including a well located on the southern portion of the Clermont Sprayfield Site. E Sciences met with Lake County on August 28, 2009 to discuss the proposed groundwater sampling activities. During this meeting, re-grading of the Site for future use as a recreational facility was discussed,along with soil quality issues associated with the past usage of the site. It was determined that approximately 40 soil samples at various depths should be obtained to determine if there may be soil quality issues (specifically As, Cd, Cr, and Pb) that may result in soil being removed, or imported, onto the Site during the regrading process. Subsequently, our original proposal to Lake County for groundwater sampling only was revised to include soil sampling on Site at 1,2,3,and 4 foot-intervals at 10 locations across the site. Also in our meeting on August 28, 2009 we discussed the need for performing a soil boring for lithological information for installation of an irrigation well. Further research into the report completed by ABB Environmental Services indicated that there are two aquifers beneath the site; the surficial aquifer and the Floridan aquifer. It is our belief, based upon the geology of the site and GIS information obtained from the St. John's River Water Management District(SJRWMD) website,the depth of an irrigation well would have to be approximately 250 feet deep to penetrate Phase II Environmental Site Assessment October 21,2009 City of Clermont/West WWTF Page 2 Clermont,Lake County,Florida E Sciences Project No. 1-0888-017-02 into the Floridan aquifer. Based upon this information, we did not believe a boring to this depth was warranted and was therefore not proposed with this scope of work. Based on the REC identified in the Phase I ESA,and the meeting with Lake County dated August 28,2009,the following scope of work was proposed and approved: 1. Perform groundwater sampling from four sprayfield monitoring wells (MWs) closest to the former dump facility for the following parameters: a. Priority Pollutant Volatile Organic Compounds (VOCs) by EPA Method S W8260; b. Priority Pollutant Extractable Organics by EPA Method SW8270; c. Priority Pollutant metals by EPA Method SW6010/6020/7470; d. Nitrate-Nitrite by EPA Method 300 e. Ammonia by EPA Method 350.2. During the sampling event, GPS coordinates were recommended to be obtained from these MWs using a sub-meter GPS unit for location on a GIS map that will be provided in the final report. 2. Since no permanent monitoring wells are currently available to sample at the former dump site, four (4) new temporary wells were recommended to be installed at the previous locations of CDGW03, CDGW04, CDGW05, and CDGWO6 for the same parameters as those listed above in item 1. Groundwater elevations and top of casing measurements were recommended to be obtained to formulate local groundwater flow direction. Refer to Appendix A for background information from the March 1993 ABB Report. 3. Due to the proposed construction of the South Lake Regional Park (which will include soil unearthing and redistributing the soil for the construction of ball fields), approximately 40 soil samples were recommended to be collected within the limits of the current sprayfield for the 4 RCRA metals(As,Cd,Cr,Pb)by EPA Method SW6010B; These soil samples were collected at 1, 2, 3, and 4 foot depth (below land surface) intervals at 10 different locations across the site. During this sampling event, GPS coordinates were obtained from these SBs using a sub-meter GPS, Outlined in Section 2.0 is a summary of the field work completed during Phase II assessment activities. Phase 11 Environmental Site Assessment October 21,2009 City of Clermont/West WWTF Page 3 Clermont,Lake County,Florida E Sciences Project No. 1-0888-017-02 2.0 ASSESSMENT ACTIVITIES On September 21 & 22, 2009, E Sciences personnel mobilized to the Site for the purposes of collecting soil and groundwater samples for this assessment. These activities are detailed below. 2.1 Soil Assessment Activities Soil samples were collected at ten(10)locations(SB-1 through SB-10)as illustrated on Figure 4, using a stainless steel hand auger. The soil borings were advanced to 4 feet below land surface (BLS) within the Clermont Sprayfield area. At each boring location, soil lithology was recorded and representative samples were retained at one(1) foot intervals to a depth of four(4)feet BLS. The soil cuttings were returned to their respective boring locations and backfilled to natural grade. A total of forty(40)soil samples were collected and analyzed by EPA Method SW 6010B(arsenic, cadmium, chromium, and lead). The soil samples were collected in pre-cleaned polyurethane containers provided by Test America, placed in a cooler, covered with wetted ice and subsequently transported to the laboratory using chain of custody documentation. Copies of soil boring logs are provided for review in Appendix B. The soil sampling was performed in general accordance with the FIEP SOP's. 2.2 Groundwater Assessment Activities Four (4) direct push groundwater screening points (TW-03, TW-04, TW-05, and TW-06) were advanced at the adjacent former landfill as illustrated on Figure 4. At these locations groundwater samples were obtained through four (4) foot long stainless steel screen points that were advanced to depth intervals of 15 to 19 and 20 to 24 feet BLS. Once in place,groundwater was pumped from the surficial aquifer using a peristaltic pump. While pumping, field parameters (pH, conductivity, temperature, dissolved oxygen and turbidity) were measured using various multimeter probes. These values were recorded on sampling logs and collected until the values stabilized. Additionally, E Sciences collected groundwater samples from four (4) monitoring wells(MW-IS,MW-2S,MW-3S and MW-5S)located along the southern portion of the Clermont Sprayfield Site (closest to the former dump facility). The collected samples were placed in wetted ice and transported to Test America for analysis according to Priority Pollutant Volatile Organic Compounds (VOCs) by EPA Method SW8260, Priority Pollutant Extractable Organics by EPA Method SW8270,Priority Pollutant metals by EPA Method S W6010/6020/7470, Nitrate- Nitrite by EPA Method 300 and Ammonia by EPA Method 350.2. Copies of calibration logs and groundwater sampling logs are provided for review in Appendix C. Groundwater sampling activities were conducted in general accordance with the Chapter 62-160, Florida Administrative Phase 11 Environmental Site Assessment October 21,2009 City of Clermont/West WWTF Page 4 Clermont,Lake County,Florida E Sciences Project No. 1-0888-017-02 Code (F.A.C.), and FDEP standard operating procedures (DEP-SOP-001/O1, DEP-SOP-002/01. and DEP-QA-001/01). In addition, depth to water (DTW) and top of casing (TOC) measurements were obtained by E Sciences personnel as part of the groundwater sampling activities. Groundwater elevations were used to generate a groundwater contour map, as depicted on Figure 5. According to field measurements,the groundwater flow direction was evaluated to be towards the southeast. Phase 11 Environmental Site Assessment October 21, 2009 City of Clermont/West WWTF Page 5 Clermont, Lake County, Florida E Sciences Project No. 1-0888-017-02 3.0 RESULTS 3.1 Lithology Descriptions of the soils encountered in the borings within the sprayfield were classified by the Unified Soil Classification System (USCS) based on visual examination of the soil samples. Stratification boundaries between soil types should be considered approximate, as the actual transition between soil types is usually gradual. During the field sampling activities, soil lithology was evaluated at each boring location. The borings were advanced to four(4) feet BLS. In general, brown fine sand (SP) was observed from ground surface down to a depth of 1-2 feet BLS. Below these depths,dark orange/brown silty sands(SM) were encountered in most borings to depths ranging from 3-4 feet. No suspect odors, visual staining, or other indications of impairment were observed at the boring locations. 3.2 Soil Laboratory Results Based on the results of the laboratory analytical report of the soil samples, all tested parameters were below their applicable Chapter 62-777 Soil Cleanup Target Levels (SCTLs) (as illustrated on Figure 6). The soil analytical information is summarized in Table 1. The complete laboratory report along with the chain of custody documentation is provided in Appendix D. 3.3 Groundwater Laboratory Results Based on the results of the laboratory analytical report for groundwater samples, several chemicals of concern (COCs) were detected above GCTLs in TW-03, TW-04, TW-05, and TW- 06 although the levels have decreased since the previous sampling event in 1992 (as discussed in Section 1.0 of this report). Based on the results of the laboratory analytical report for groundwater samples for MW-1 s, MW- 2s, MW-3s and MW-5s, all tested parameters were below their applicable Chapter 62-777 GCTLs. The groundwater analytical information is summarized in Tables 2,3 & 4 and illustrated on Figures 7 & 8. The complete laboratory report along with the chain of custody documentation is provided in Appendix D. Phase 11 Environmental Site Assessment October 21, 2009 City of Clermont/West WWTF Page 6 Clermont, Lake County, Florida E Sciences Project No. 1-0888-017-02 4.0 CONCLUSIONS AND RECOMMENDATIONS E Sciences has performed this Phase II ESA in accordance with E Sciences' proposal dated September 9, 2009. E Sciences performed groundwater sampling from MW-1S, MW-2S, MW- 3S and MW-5S, which are located on Site and are the closest wells to the former dump facility. None of the tested COCs were above their respective Groundwater Cleanup Target Levels (GCTLs)as stated in Chapter 62-777,Table I. Florida Administrative Code(FAC). E Sciences performed 10 soil borings at various locations across the Site. At each boring location, soil samples were obtained for laboratory analyses at 1, 2, 3, and 4 foot depth intervals. All soil samples were below the Direct Exposure Residential criteria as stated in 62-777,Table II, FAC. Several COCs were detected in the groundwater above GCTLs at the adjacent former City Dump, in TW-03, TW-04, TW-05,and TW-06, although the contaminant levels have decreased since the 1992 sampling event. Due to the decrease in contaminant levels from the previous sampling event, the hydraulic barrier (pond), and the groundwater flow direction towards the southeast (away from the Site),these elevated levels of COC are not considered to be a REC with respect to the Site at this time. Based on the results of the Phase II ESA, no further environmental investigation appears warranted at this time. However, several groundwater monitoring wells are located on-Site that were used for monitoring contaminant levels associated with the former sprayfield activities. Due to the proposed construction the South Lake Regional Park, E Sciences recommends properly abandoning the sprayfield monitoring wells if permit conditions allow. FIGURES I t M ,: •► .561_ ITR• 1 an LLCRESR .alr".- gir/ f - i: 4 r.TER 4 7 ORANe O A IR , Z w COStk 'I 'iApproximate i A. M PA Site Location � 7 C. .4P i F G W quil POL O iND P�o� QO o . HI SBO z;Key Map o0 ., �._ a. W t__ N Y Zi o S o- O w 3 GQ� w. , �9 J m w 0 SS f5 cc II ~ Z Z Q rc C,0 00 q Ot- Li (7 ..4 1 Iiiidi q w +I Z 3 x' 0 o ? N NSR 50 SR 50 =----(5l) --- - AIIIIIIIMM i I COMPASS ROSE DR Ir GANO RD l—---� I i ra Z ______. Approximate Site Boundary O D G� ; o LAKE,SUMi E#QR 70 �?f 'LAKE.DO BLAB i • i i.... .. 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TH BY:/#nw' 1-0888-017 Clermont, Lake County, Florida 1'.equals 2,000' 10/08/2009 -,,,•...,,',.,,,,-..:....s.:::::7;.,:,'.i...... .: ,---ir_i_--;:--- ,. 1~ sx . r N f ~'�1 amu- i -\N \ : • ,K �,4 iN� ' 1 ;t8\-/ ( fr\{ i �`�� \1 ,' r1 1 M-�V54 k..,,l j/ / / ` i• j/.i _r-, ` �'i\\„,-,_—_. .., I '` 1 . 1 i k T r - > : � fir- -_��" '/ aI 11, pm' --��; _:-- ■ r�, . ; y, y , '"� �` /,------ f^ _.- .— __....-- ..-._- • '',� :...7.*, t� foo t.--,Ye . •'-' '^` ,�� _,rte ___-_ r �`_ - Lake • :, ~ __fir !� „_'1_J r 7 i V1r. .S "' l r^' i .n. v �� s` 7 • li a '.� r •*�' .c : •a■,- I` es'' • * i ' w . 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De 00000.) •00 .*n0.•out, i4R777 LEGEND )-4*.•.4n•..*e* **4*** f 40..00..:0* 4 0***** --- Approximate Site Boundary .ir.n*n4**.on*•* ©pe0jp� •r.0 044•••0•••• 400400 ———— Approximate City Dump Boundary .X•000000•.44044 0.00..0 *44...0.4.. *444• 04/400000* •-• Monitoring Well �•- *"�°V00r cx �ac Temporary Monitoring Well „ i. •• j ,, 8�''6 Citrus Grove •`• `. 2;::: �': xxxXXoaD Groundwater elevation and contour ,t''' \Groundwater direction of flow l ig,21 . . .... . , ,, NM Not Measured ,x , 200' 400'. •, ., City of Clermont -West VVVVTF _ `60•0"'`m"" r Groundwater Contour Map r (10-08-2009) IF Soi .f o,^'"'""'sown OW Sections 21,22,27,&28,Township 22S,Range 25E fff�� Phone .1 SCALE: DATE: Clermont,Lake County,Florida ow.w,+ c1E4sEo PROJECT 4/05670 I'o4u.5400• 10/18/2084 By: TH 4/r::,,,; -- 1-0085-017 I I I J "`--� r f S iefairiMMatiraili I se.s 1/41•9I+l: twasftl I/I I I Z.061"Ili III Nix:is,c„", rl • 88-2 r • r • sa.o r nix anICLa • - MILMIZ xr�, r�Ortiz � �� • SB-7 • Jsero cx-i'+ 3FJ riXasB-1 CE,j� l rimillIVICTAFTWarril v ,� tiZI4PLiZiMizi ZTAZ&M NI" "----.. �'ii a Al I+r . 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CO w : N N N N N N O a! -5 V U O) O) m a) a) cO II a) a) co co ' J o O) _ r C N N N O I N E -to 5y J J — C //�-� //N�� //M�� aVV,, /.�-� /N/�N� (.N(.�� //V�� aa`` (Na��, /C-�)� (U).�,� /.,-�� ((.&.�� /o,�o� ((U)�� //�� //C�N� CO d•��V`` /a,.��, U Z co -oZ -o N V lJ G V V V \J lJ V V G \J LJ \J lJ lJ LJ LJ V V V .� N N N N M M M ( V V V N (n N N co U L' d d J O7 [O cO (D moor m m w o m m m O] CD CO (D O] p] (n O > '�> W W (n cn w (n U) U) (n U) U) V) (n U) (n (n (n CO V) V) CO V) U) w d m (a 0 0 LL LL LL LL 0 O N N O > a) d' co J H 0 @ c a) C U O Q, L 0) @ ..- E -E a • 3 Co O C co O a) Q (O N (0 N N 0) u) O N Q Q O N V7 N- u) CO • p J Q• J Q CO (O CO Q M N Q M Q N r r Q N M N N N m @ N C -0 J N - ao , = E. @ C o u @ E E a) N o 'E co O_ 'E V) O N r Q O N _ u] r Q, a0 .- O a0 Q N r r '5^ 2 M N p u) Lc) ,- Q u-i N Q V (.j Q nj u) c0 Q N M CO N N @ NC L L @ a) a)U0 0 f /) N a) J E o c a < c c g Z Z u) 7 2 @ W II II j 5 c N = > > > > > > > > > > U N a) C N N U Q. `� O c0 E N O co •- 0 CO O) Q) CO Q) CO O) m r r _(1 N r @ O O O 0 0 0 0 O O O O O O O O O O O O Z p (n 5. 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C c C C D L m O L TO U) U) U) U) U) U) U) U) Cl) E t N N E c Z Z Z Z Z Z Z Z Jn N C .. N C Q U2 1 Cu L T N T N r N L L V) U) U) V) Ta' vco °2 ELN E r Z Z z Z Z Z Z Z a n J l71 -o - co C C a D o Z iT235 c an II p,F O .co, J L N co CO N N N V M CO a E U C7 n co Z m Y > „o a z W o c0, U m $ t0 _, W JE -0 y N 0 W — Q o m CO cn U) U) cn U) U) U) Cl) __ 0 0 3 I- F Z Z z Z Z Z Z z I � vm � v 2 H En `i n C U N III _ /� n C O O o �0 W N V a C� N LL Z Z V) 5 0ri) 0 O ~ H Z Z Z Z c.-� LU Z V o Q 7,0 II II C U21 L. CO t) a) Z N @ U CO "Oa) N N N 'p d d y co E n EI o _ c a. 10 o 0 0 0 O o N to LO MMLo 4 O O C O I I W NH • X O O O O O6 W z z P m D .I� c LU L c. N — O L N V V V V N V V V I— W 2 coW O O O O O O O Q ID O °) c D D z D D D D -CI: N _ Z U iii r r r N 7Lc) t0 .- to CO .- Lo tO 0 1 C F O O O O6 O O O LL - e 2 C z D x N O O O O N O O C )O LO LU tO N t() to to 0 z 0 z - m o 0 0 0 0 0 c N ` O J N W EN 0 O O O O O O O O 6 N "o C O O O O O O O O J 0 N w N N N N N N N N N CO Y m N N N i, U N 1-2 E N N N N N N N N U _, 0 CO C) C) C) C) Er) C) rn C) COI— N ` N CO O O U , , i i C a CO .. V) N LL U) � LL CO :5 LL CO W CO O. V n. N O. CD n co Q n CO nm N a> M a) to a) o f o E o E o E Z' D U D ,, m E E E E D D liCYL LC U Z n n O. O. N- '‘;C Co CO 02 C 8z C 15 Q) U U .v N O W a` 0 O (-N N O a) C a a) m a> 70a) 9 3 _C O c0 -5' O O N N U V 2 U /�/y/ a) o 3 Li O N O N O co Q L C O L CO U0 O U o 2c >. d .• a) J L 00 E. L U) CO E L N (V E L Z t\I . N Q J `d m c c U co c 0) _ O T N L a) a) m to U N L a0 co • W L N E = N (N E c Z a) m co < O III Z 45 3= o • _-•.•- 04. W E . U m Zo W c m J E O N N co 0 m O O m CO Q E 02 0 3 I— N oN Z 6 c 2 NO O c U a) I v c c To x _ 0- (n N a) 0U U d O w O W N F H Z O < Z Z y N a) 3 IF m ~ CO N II II 3 C � L- _ a) Za) _ N cc) co a ° co a E O C U m 6 N O C `W �n � tea) c N � CV " � T CO z zo a` P m° D _ C C D Wt N OO L_ N 'Cr c (� M C V I"' w W O Q Q U C D C O a) i C1 D Lo Z co p ccFo O- F O OLcL,1 S cc c c D x ci O N O N 2 N a)C 6 ) m O •• c co N o _, a) W E m o0 v a c 0 COU ,n o - a) N W o N NN Q N < 2' U a') E (N m o) U .6 a o (n ai a) 2,U , E -o m a co '- z Q n co n•.� j N m p N OO > E _, N @• .� m a n tL Cl r--- ZS 0 m co U co c9 $ z c a U U (n O w a` D D - 3 3 3 N ° 0) M M M M C) M O V 0) d d N N N N M N N N 00 N N N O C O O 3 O 3 O O O .- N O 0 N N N co N 0 N d W t o 0o t D D D = D 3 3 D m N M M N N N V M a a c a ry c 3 O 3 O D O O 3 1:30) _ N O ..0N (N N N M N U G Q O a .- ,- � -• ,- .- .- O F J N _ O -o a) 0) C C 0 ) N O O (n U N UJ U) U CO U) SZ 3 j CS) Z Z Z Z Z Z Z Z cci Q 0 w F LL LL O I-0 Cl J w U a p E U' N d = o o L O 3 3 3 O O 3 D Z O) O) T 00 2 N N N M N i 1 0 «L. 0) C p N N O - r r .- z, C 0) re O E N a) 10 0 LL. LL Q E N C m 0 L y «� E u o 3 '0 d ac) 3 3 O O = O C v :o vm D o ° oo v' N m v co cn Ln 00 6 c = L o o L rn 0 0 0 0 rn 0 C O O C p •C O O O 0 O O O E Z N O U n a) O m O co D n c E a m . X 0 0 JC > Z v Z CV CV CV eD CV .- Q , -0 N N O N U 0 O 0) N N t2tpp O U c v aLr, p c D D O O 3 O O I— 0 Q' >. C LL C % 0 0 C m N M M N N N V M '.. O O 7.05 O II 1 1 0) `0 0) ,- .- .- .._ J Z Z Q _ co 7 ._ m 0 m = + QL. c • t 0) Z m N o_ 0 .. 0 3 3 3 3 3 'ar Q .- O,_ c d N N ? c N O ) m a CO a 0) Ce c c m W N L O N C u7 c0 <O co )I) CO O Q C O po r- r m ] m p as C > > > > > > D D Z ON p N N TCO C T O) <0 O O O) m m a a) O. O O O O O O O re a) VC U 0) N N 0 N Nu) (0 N N OD O '- [0 C m C M f0 ca WO O 8 D ) = 3 D 3 D D 0 M �° m a) r•-- a> N- a, co co co m N t C N E. O o O O O O O Q a a N • . o N _. o 0 O ). - - a r r r n r r 0 CO 0_ eo N N .- .- .- N LL N d u 0 Q Q O a a, I N N X L D D 2 D = D D D N 0) L o L 2 C n N O n V V V O O m N N u O _I Q Q N a 0 O O O) O) O) 0) O) O) Q) O O O O O O O O O O O O O O O V C c 0) N N N N N (N N N r Z, U E N N N N N N N N U a m d CO O) O) O) O) O) O) O) O) oS A J U C co 00 0) N -y o . i i i _ O E $ )0 "o m U d o cn LL cn LL cn LL cn LL c o a v n Lo n co n ui a — - N 6 c'? u) 6 O E o f O E O E v z (Ts ro Q. n n n cr) 17 w a - 3 ._ 2 N O N (N U O V V) co V) (I) o O O O a> O Z Z Z Z O O O 0 N O 0 O O N 0 > N CC 3 D D 3 3 3 N p N OO N O N O M O N O (;.� U V N N (N O O O O O O O O Z O Z O O O O O O O O O O O O O O N J Q Wa> 3 O O) O) 01 01 O O N N N N N N M O O O O O O O 1 O O U UO o 0 0 0 0 0 o O 0 0 0 0 0 0 ecQ 2 U) E 00 E O O O O o � O O J O O O O O O O O O c c Q Q Q o O o O O O O U H >- a> U J •- : ._ 3 •- ._ Q J 0 UU coO V O V co N O C C_ 0 1!7 r l() Co o co Z E c N N O o O O o O O O O O Q O O IT! n o 0 0 . ec J O w a U a J I— 0 E C> N 0 o • I co o m c E E D D D D •- D a) a N o E o 0 0 0 0 0 0 oN CO a • N C O 3 L O L O O O O O O O Z 0 D N '2 N 0 O O O O O O O D 75 V)N C 2 oz a c E .n LL (n N OU OU 19 Z - N a) - u 5 :~ > E E 3 > D > > : 3 D O U copp - 2 O� L O O O O O O O O O et E 2• D E m • O N O O O O O O O O W (n T y c N U U O O O O O O O O W CO Z• Q M = II Q I— U U E c 3 3 3 - 3 3 3 a, O ,- N O O O ,- co O O O V V 7 o V C Q O 0 Q O O O O O O O �p 0 O O O O o O o p O O O O O O O O F- F- m 0 3 3 3 3 3 3 0ao CY J u7 J O O O O V O O W N N N N N N y @ O 0 O O O O O O O O O O O O O O O O O FO- O F O O O O O O m m x 5 Z O 0 J N O E N O O O O O O O O CO N O O O O O O O O co co U Ii30 _a) N N N N N N N N C O L N '@ a N r r r r r r CV - O N N E N N N N N N N N yj O Z- 0 c ca C) O O rn m rn O rn U z J N (n C U N al i APPENDIX A 41111 - _11 Florida Department o.. _ 1� ifi:,.: :^ 96 Fa _ ',-; Environmental Protection (-:. ,..kra?,rr• =oU }'t``� Twin Towers Office Building 2600 Blair Stone Road Virginia B. Wetherell Lawton Chiles B1 Governor Tallahassee, Florida 32399-2400 Secretary July 16, 1993 p ,,� t);.11t , — ` i` "te• r V ` /,.0 �-C7 �1 `�t^7. Mr. Wayne Saunders, City Manager 1� )1j f, City of Clermont P 5� (:Jr, � , P.O. Box 120219 Itoti Clermont, FL 34712-0219 Subject: Old City of Clermont Dump, Lake County; FLD #981024946 ZI Dear Mr. Saunders: Enclosed is a copy of the final CERCLA Site Inspection report for the subject site. The results of this investigation indicated the presence in the shallow surficial groundwater of aluminum, iron, lead, manganese and benzene at concentrations that exceeded federal and/or state maximum contaminant levels (MCLs) for, drinking water, and significantly exceeded concentrations found in the background sample. Vinyl chloride detected at an estimated (J) concentration of 2J ug/L may exceed state (1 ug/L) and federal (2 ug/L) MCLS, Several additional metals plus cyanide were detected in the groundwater at concentrations that exceed the background levels. Nitrates were found in two nearby private wells at concentrations of 8 ug/L and 7.7 ug/L. Nitrates were not detected in on-site groundwater samples. Based on the results of this investigation, the Department has recommended that a Hazard Ranking System evaluation be completed to determine whether further CERCLA action is required by the U.S. Environmental Protection Agency. In the interim, I recommend that you contact Mr. Richard Tedder at FDEP's Central District office to discuss action that may be required by the City of Clermont to address the contamination. Mr. Tedder can be reached by telephone at 407- 894-7555. If you have any questions concerning the report, please contact me or Joe McGarrity at 904-488-0190. Sincerely, , —A7 Brian M. Moore Environmental Specialist II Bureau of Waste Cleanup Enclosure cc: Dorothy Rayfield, EPA Richard Tedder, FDEP Central District, with enclosures Lindy L. Phillips, with enclosure Joe McGarrity, BWC Printed an reeyded paper, I PHASE II SITE INSPECTION REPORT Old City of Clermont Dump Clermont, Lake County, Florida I U.S. Environmental Protection Agency Site Identification Number: FLD 984197368 Task Assignment Number: HW147-48A ttN1RoNmtr� 111 fii.�i: fA ti 44TE of FLoRA p Florida Department of Environmental Regulation 111 Bureau of Waste Cleanup Site Screening Subsection Tallahassee, Florida 111 March 1993 111 A it II ABB Environmental Services Inc. ASEA BROWN BOVERI /1 INVESTIGATION FINDINGS Groundwater Quality. Groundwater quality analytical results for the environmen- tal samples are presented in Table 4. The USEPA validated analytical data sheets that include the complete suite _of parameters and their respective analytical quantification limits are presented in Appendix A. These data indicate that water quality of the surficial aquifer has potentially been impacted by 1 activities at the Clermont Dump site. The significant findings are summarized as follows. • Based on its apparent upgradient and offsite location, water quality in 1 sample CDGWO2 is most likely to represent background conditions of the surficial aquifer in the area. • Iron concentrations exceeded the State and Federal maximum contaminant level (MCL) in samples CDGWO3 (11,000 micrograms per liter (pg/l] ) , CDGWO4 16,000 pg/l) , CDGWO5 (7,700 pg/l) , and CDGWO6 (8,100 pg/l) . Iron was undetected in the background sample. • Lead was found to be in excess of the State MCL in sample CDGWO5 at 110 pg/l. Lead was not detected in the background sample. • Levels of manganese were above the State and Federal MCL and exceeded the background level by more than four times in CDGWO5 (85 pg/1) and by nearly three times in CDGWO6 (58 pg/l) . • Levels of nitrate and nitrate plus nitrite in the two private residential well samples, though below the MCL, exceeded the background level by a factor of eight. Nitrate levels in the four samples collected from the landfill were below minimum quantitation limits (MQLs) . • Benzene levels detected in well samples CDGWO4 (10 pg/l) and CDGWO6 (20 pg/l) were above the State and Federal MCL; benzene was not detected in the background sample. An estimated concentration of 1J mg/( of benzene I was detected in sample CDGW05. This level is equal to the State MCL, but less than the Federal MCL and the MQL for the background sample. • 1,2-dichloroethene, at concentrations below the Federal MCL, was detected a at estimated concentrations in samples CDGWO3 (3J pg/l) , CDGWO4 (4J pg/l) , and CDGWO5 (2J pg/l) . However, the levels detected were below the MQL reported for the background sample. • Chlorobenzene and ethylbenzene were detected at low levels in sample CDGW04. Chlorobenzene was also detected in CDGWO6 (18 pg/l) . Both com- pounds were undetected in the background sample. • Vinyl chloride at an estimated concentratiop of 2J pg/l was detected in sample CDGW05. Because the concentration is estimated, it could exceed both the State and Federal MCLs (1 pg/l and 2 pg/l, respectively) . clar.p2 adf.3.10.93 15 I I Table 5 (Continued) Summary of USEPA-Validated Laboratory Analytical Results for Soil and Groundwater Samples Phase 11 Site inspection Report Old City of Clermont Dump •Lake County, Florida Concentration detected in sediment sample number: 4 IIICompound CDSD01 CDSDO2 CDSDO3 (background) Volatile organics, in micrograms per kilogram 1 IN Carbon disulfide 6 U 5 U 3 J fieptanone' 10 JN NO ND II Extractable Organics,in micrograms per kilogram Unidentified compounds' 30,000 J 1 700 J I 90,000 J (14) (2) (16) I Pest&cldas and PCBs,In micrograms ND NO ND par kilogram Meters,in milligrams per kilogram I Aluminum 2,400 1,200 4,600 f ar1iJm 68 4 U 4. if Calcium 410 640 810 11111 Ctirornium 1.7 J ' 0.69 12 Copper 4.8 J 1.1 1.8 iron 610 540 220 III Lead 6.4 J 60 J 7 J Ma nestum 170 60 11 280 Manganese 1.1 J 4.1 J 1.8 J iii 111Nickel1.r 4 1:2 U . 3.2 J Potassium 110 J 80 U 180 U MOSodium 8.7 J 68 Zinc 1.1 9.8 2 'Tentatively identified compound. 1 Ili 2Nurn6.r In perenthrroas b rioatee number of urddenRifi.d oornpou ch. Notes: U s•m.A.rial weir analyzed(or but not dateote4. The Marber shown is the miiwman qurAkat on Ji7. J . srtirnated vel as. IIIN ND + none detected. NS + not sampled. N .• or onmptivir evld.rwe of materiel. PCS.. polychlorinated aphanyls. Ft-qu.Sty control hdiCdes that date it.unusable. Compoud may or may not he meant. Remarrying end rsanely.e is ne0eeeery fa verification. ii - oil c1er.pZ ad1.3.30,93 18 • • Cyanide was detected in CDGWO5 (9 pg/P) and was undetected in all other samples, including the background sample. • Aluminum was detected in CDGWO3 (8,500 pg/f) , CDGWO5 (14,000 µg/P) , and CDGWO6 (73,000 pg/f) exceeding the background concentration by three times or greater. All of these_ samples, including CDGWO2 (1,100 pg/P) and CDGWO4 (1,900 pg/P) exceed the State and Federal MCL for aluminum (200 pg/f) . • Levels of nine metals (barium, calcium, chromium, copper, magnesium, mercury, nickel, potassium, and sodium) were also detected in one or more of the samples at concentrations elevated relative to the background sample. However, no FDER or USEPA drinking water standards were violated. Groundwater Occurrence and Flow. Groundwater was encountered beneath the site at depths ranging from 4 to 8 feet below land surface (bls) . Top-of-casing measurements for three of the onsite wells and measured depth-to-water data indicate that groundwater flow in the surficial aquifer on March 26, 1992 was to the northwest over the northern part of the site (Figure 3) . However, the limited number of groundwater elevation measurements taken during the March 1992 SI are insufficient to determine flow direction or gradient across the site. Surface topography and features indicate a west-to-east flow gradient (35J . Contamination of Sediments Onsite. Analytical findings for the sediment samples are presented in Table 4, and the laboratory analytical data sheets that include the complete suite of parameters and their respective analytical quantification limits are presented in Appendix A. These data indicate that onsite sediments do not appear to have been impacted by surface runoff or shallow groundwater discharged from the dump. The significant analytical findings for the sediment samples are summarized as follows. • Sample CDSDO1 was the designated background sediment sample representing conditions in the area. • Lead, manganese, and zinc were detected in CDSDO2 at levels elevated relative to the background sample. clor.p2 edf.3.10.93 19 EXPOSURE ROUTE EVALUATION Soil Exposure. Although site observations suggest that humans and wildlife access the site [35,37) , the potential for onsite exposure appears minimal due to the fact that the fill material is covered with a mantle of sand and vegetation, and runoff does not apEear to be a concern, based on the tendency for rain water to be absorbed by sandy material. Surface Water Migration. Based upon the sediment sample analytical results, migration of contamination in runoff to surrounding wetlands does not appear to be a concern at the site. However, Lakes Minnehaha, Palatlakaha, and Minneola are all located less than 2 miles east of the site. The lakes are all used for recreational fishing, boating, and swimming [3,19 ,20,23] . Habitat for the threatened sand skink is located within 1.8 miles of the site [22,33) . Groundwater Migration. Groundwater used for potable supply occurs in the unconfined Floridan aquifer. The groundwater analytical results suggest that the overlying surficial aquifer has been degraded by past dumping activities. The benzene violations in two of the monitoring well samples and other low level organics indicate a possible groundwater migration concern. Also, concentrations of lead, iron, alminum, and manganese were detected in excess of State and/or Federal MCLs, and vinyl chloride (reported at an estimated concentration) may exceed State and Federal MCLs. Estimates of the populations served by potable wells within a 4-mile radius of the site are summarized in Table 1. Residential wells exist within 0.5 mile of the site; however, two of the wells sampled in the SI did not appear to be impacted by the landfill. Due to the detection of organics and metals in onsite groundwater, further evaluation of the pathway is warranted. Air Migration. Due to the low levels of the few volatile organic contaminants detected at the site, air migration is not a concern at the Clermont Dump. cler.p2 adf.3.10.93 20 CONCLUSIONS AND RECOMMENDATIONS ffff Considering the findings of this investigation and the background information, the following significant conclusions can be made. • Groundwater beneath the site occurs in two aquifers of concern, the unconfined surficial aquifer', and the poorly confined underlying Floridan aquifer. • Groundwater samples collected from monitoring wells at the site indicate that the surficial aquifer may have been impacted by iron, lead, aluminum, manganese, and low levels of benzene and vinyl chloride. • Although the reported levels of benzene are low, the fact that no significant confining unit exists for the Floridan aquifer, combined with the presence of a private residential well within 1/2 mile of the site, makes the groundwater migration route a concern at the Clermont Dump site. • Degradation of water quality of the Floridan aquifer by nitrate was indicated in the two residential wells that were sampled. No significant nitrate concentrations were detected in any of the groundwater samples collected at the landfill, suggesting that other sources are likely responsible. The findings of this screening site inspection should be incorporated into the Hazard Ranking System evaluation of this site by USEPA. Based upon the analytical findings of this sampling event, combined with the presence of groundwater migration targets within 1/2 mile of the site, Clermont Dump should be assigned a low priority for ranking. cl..r.p2 sdf.3.10.93 21 1 i � I C CDPW07 N 4 CI vas►+w s� C i CITY OF CLERMONT ' SPRAYFELD C0INICATX)NS A DSD01 1 _....\ / TOWER WETLAND \ WOOOED • \ N.,_ 1-S yy T— cD7 - 4-5Bl S.�1.'LS� _ _ ._-•--fes DPW01 1 ❑ POND C REsoeicEB WITH WELLS • / (90.a1) \ --.r- 9, `—_, C.cDCN04 • ,y� - ��__ caoWog e: (9027) ( os ) Is \ :` CLERMONT C SD02 POFD I • 1I / , A I , ORANGE GROVES WOODED AREA— A COSDO3 9 ' . 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U O N N o N Q r ci a ® §. g » n •Cifb es N '` O E 2- C't c 1 _ � . c E v S Er' : c ..o E + i 01 ---,---, .......„ •-, .__, ----,--> ii APPENDIX B Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Boring�Vell Number Permit Number: FDEP Facility Identification Number: 53"– Site Name: Borehole Start Date: 1r1,:109 Borehole Start Time: iti 0 0 K AM ❑PM End Date: End Time AM ❑PM C t7t/ of CLe'�2�r'Auflr- f( ls '� Environh ental Contractor: Geologist's Name: 'Environmental Teel nt n's Name: E SCIENCES,INC. — I a @n�Ni� Drilling Company. Pavement Thickne s(inches): Borehole Diameter(inches): Borehole Dept�y(f t): Drilling Method(s): Apparent Borehole DTW(in feet Measured Well DTW(in feet after OV st modeljand check type): \ 'k � Mfiom soil moisture content): water recharges in well): NONE/) ❑HD ❑PID �\ Disposition of Drill Cuttings)check method(s)): ❑Drum ❑Spread ,Backfill ❑Stock Pile ❑Other (describe if other or nnrlrrple items are checked): Borehole Completion(check one): ❑Well ❑Grout ❑Bentonite Backfill ❑Other(describe) in J ° ro 6 7. w ° t C up 3. z 7 13 6•Ti, -, 4' A S g - Sample Description 2 Lab Soil and Groundwater r+ 6- A �, co I Q (include grain size hosed nn IISCS,odors,staining, f. Samples(list sample number and depth aN.'o c Q N O o< and other remarks) c e Sr temporary screen interval) re .;:y, B.- a A a 9 l o F. ,26,/,,el ani P ter @ kik 1 IZ \ O, rrt SfIve \ I -54'6a 5'14I) 1(Oci, Z 1t P27--iit7,,ebit s,� sir IG 1 3gar�� t=0,e SR."'D I 3 Jz 3 Sur 5( tT-5 �� \Y 7i a \ f'. r S t"b 5 L T 5(g. 7 ' _ ii \\ 03 5 (, 7 8 9 10 12 Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Ronn Well Number: Permit Number: FDEP Facility Identification Number: 5$- 2 Site Nameb y. G 04_444� q// Borehole Start Date: g9 Borehole Start Time: ( 1 Z Z CI PM (.y C oJviri End Date: 1 ( 1 End Time: (( 3.7. AM ❑PM Environmental Contractor: Geologist's Name: Environmental Technician's Name: ._ E SCIENCES,INC. DrillCompany: 'Pavement Thiykn�ss(inches): Borehole Diameter hes): Borehole Depth(felt): S N//ll4 Ltf Drilling MethQd(s): Apparent Borehole DTW tin feet Measured Well DTW(inrfee ter''OVA and check type): r7] t-.k J( from soil moisture content): .,� water recharges in well)/ NONE ❑FID El PID Disposition of Drill Cuttings check method(s)): ❑Drum 0 Spread M Backfill ❑Stodc Pile ❑Other (describe if other or multiple hems ore checked): __,JJ Borehole Completion(check one): 0 Well ❑Grout 0 Bentonite lc'Badcfttl U Other(describe) re ' » m a o r�; C "=1 C fZ/1 B' 0 6• A n Sample Description cn 2 Lab Soil and Groundwater- - A b'. 97 tl0 1 a, (include grain size based on USCS,odors,staleleg, Samples(list sample number and depth 'o °• c u 0 0 Y and other remarks) l3 a or temporary screen interval) B a > S g w fr(A- ( Z I r K 7) ?atm.---, -Ft.-*-sii- r . 3 (2 3s�-p SL-1-- ' ( T S� L� �Z `_� -1 r, S,wS 5,c.r3 50 p c_J D$ . S 8 9 10 ` I , I2 Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Born:Olenmber: Permit Number. FDEP Facility Identification Number Site Name: Borehole Start Date: 9 2 Z/cel Borehole Start lime'. l 1 13$ AM ❑PM (-•f'' C h t OZffro'" I End Date: End Timc: i 45 AM ❑PM Environmental Contractor: Geologist's Name: Environmental'1'c,ch iician's Name:i, E SCIENCES,INC. (/ • til[ `�-._„"(� Drilling Company: Pavement Thickness inches)' Borehole Diameter(inches): Borehole Depth(feet): Drill nPC. Od(s): Apparent Borehole DTW(in feel �leasmed 11'ell DTW(in feet after OVA si modeled check type): from sod moisture content):�— water recharges in well: NONE ' ❑FID ❑PID Disposition of Drill Cuttings fcheck method(s)]: ❑Drum ❑Spread Backfill ❑Stock Pile 0 Other (describe if other or multiple items ore checked): Borehole Completion(check one)' ❑Well ❑Grout ❑Bentonite r.Backfill ❑Other(describe) ss a r, b a o m e ia v: ° c 2 A vt a• 8 2 a o•.. 4 I ; ; v Sample Description y 2 Lab Soil and Groundwater ,e is F P, 75 17 tt rt a C v (include grain she haled on 11SCS,odors,staining, 4e ^ Samples(list sample number and depth 9 $ o w S C , end other remarks) cr c or temporary screen interval) .. - a > _ o I 30,,t-. (.t,t-..., .t pt.' 53.1)5 ((`1 2 1ti -0 2 �� PtlZ*� tom`S"r s"1 3 Srg� vw^ s,-.4.....„ , yrs �� ....., ut \ Sika".‘ €T St.- 5r 2 vc . 00 z (i 8 9 l0 Il 12 Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Boring/Well Number: Permit Number: I FDEP Facility Identification Number: Site Name: `� N1( Borehole Stan Dare: q 121.101 Borehole Stan Time: ti 5.-D M ❑PM l� F C t•-t" W 111J I‘ End Date: l End Time: ,�G,,7 Alit [RPM Environmental Contractor Geologist's Name: Envirogriental Technician's Name: E SCIENCES,INC. G Drug nrpany Pavement Thicle ss,(inches): Borehole Diameteinc)) IRorehole pth(fez)? •Pc, Drilling Method( :A Apparent Borehole DTW(in feet Measured Well DTW tin feet after •OVA(list model and check type): 5 from soil moisture content): water recharges in`(welly NONE ❑FID ❑PID Dis ition of Dn 1 Cuttings(check method(s)1: ❑Drum ❑Spread 47 Backfill ❑Stock Pile ❑Other (describe slother or multiple items are checked). l Borehole Completion(check one): ❑Well n Grout El Bentonite NilBackfill n Other(describe) in C 3 to e ci,n 'o p "n t7 C o B a la 6-ti ^ -0 A A A Sample Description r) 2 Lab Soil and Groundwater ,, w (r' z 5, w eg &. C y (include grain size based on USCS,odors,staining, s n Samples(list sample number and depth .� 7 a < n� u Q 0 < r and other remarks) B a or temporary screen interval) a J A Y Y - o ,(� � c, B+d' Ft s,•--a/ /"rP c-- 12 I S(,Y s /t�Ts ��` p / ( 7 tea,,,,,, c n/tvfo" r,— SM n / Z 2' \ 2 6A-A.1) / 5 t.-1— S,t- l� .12d ....•r' rtHQ c A. p/- 1 V.' q .s-c.7- S ltr4, L/ S 6 8 9 i IO 12 Florida Department of Envinaunental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LAG Page I of Boring'Well Number Permit Number: FDha'Facility Identification Number W53/8628320 Site Name: Borehole Stan Dale: 1/ir�o Of Borehole Start Time: (2d3 ❑AM VI pm .)V fl 6 V' 1End Date: End Time: j 21 5 ❑AM PM I: menta!('urometer: Geologist's Name: Environmcn a Technician's me: E SCIENCES,INC. _ i ' �"�f1,104 . Drilling Compan. Pavement Thic ran s(inches): Borehole Diameter(inchs): / Borehole Depth(teal:_ Drilling Method(s): Apparent Borehole D (in feet Measured Well DTW tin feet alter O\'A(list model and check type): from sot moisture content): water recharges in well): NONE 0 FID ❑PID Disposition of Drill Cuttings check method(s)): 0 Drum 0 Spread ❑Backfill ❑Stock Pile ❑Other /describe Kosher or norhiple hears are checker!): Borehole Completion(check one): ❑welt ❑Grout ❑Bentonite 0 Backfin ❑Other(describe) Y. 1 = € C e. v - 7 z c _ , r —' . •:: Sample Description Lab Soil and Groundwater 7. 0 3 z _ • 8 p (inrhmde grain size based on ltSCS.odors.staining. ..(4) ^ Samples(list sample number and depth v 2 FL. O Y 7-7 and other remarks) o ^. 7-•- „ c. _ = or tetnparar)screen inter,ail A l' ZI ors �0A p ( ZD5- \ „,,i, vc,E i Ssr V A� \liik SA-6132 a �� 8�,� 5 ALTS Jam, / w� SLT Scc. 7� �� 2 f.2.4,14,./..., •-- I \;\ t""k .1:/' .N. y 11 1_' Sample 1 ipe Codes: 1'11=Post Bole: IIA=/land Auger: SS Split Spoon: ST-Shelby Tube: DP,.Direct Push: SC Some Core: DC Drill Cuttings Moisture Content Codes: D- Dry: SI=Moist; W•Wel; S.,Saturated Florida Department of Envimnnrental Protection-Division of Waste Management•Bureau of Petroleum Storage Systems BORING LOG Page I of 13oring•V'cll Nn I'erntit Number FDFP Facility identification Number: (° / 53/8628320 Site Name: Borehole Sian Date: 1 /`ZZ/©C Borehole Stan Time: 1 Z 1 S 0 AM M G..ti0 P. , 4 t (() End Date: 1 ( End Time: 12 Z5. El AM PM Environmental Contractor: Geologist's Name: Environmental Technician's: ante E SCIENCES.INC. Drilling Company: Pavement Thickness(inches): Borehole Diameter(inches): Borehole Depth(feel): Drilling Method(s): Apparent Borehole DTW tin feet Measured Well VFW tin feet after OVA(list model and check type): from soil moisture content): water recharges in welb: NONE El FID 0 PID Disposition of Drill Cuttings)check method(s)): 0 Drum ❑Spread El Backfill El Stock Pile ❑Other (describe itother or aurl(iple items are checked): Borehole Completion(check one): 0 wen El Grout El Bentonite ❑Backfill ❑Other(describe) J. 6 i L e •l. i z o 9°- ' --o A i Sample Description v 2 Lab Soil and Groundwater z o X = S c a O (inchtde Rrain size based on Cti('S,odors.staining. 1 '2.., Samples(list sample ntnntx•r and depth d ? s 0 and other remarks) = _ or temporary screen interval) > _ _ 144 1 \ 1 I 5 Q104.4 D ( L Z O AA'(O+ tr Fe 94 D ' ; Z - •�c� - 5 c- r stomp 4A- 3 , \ Dc. a2,N /0.7,0-...,.z •Fk ik"� -n 'Si� - D . \ 4 , 613a4-("&V 5k1/Dti'le' 4.b cj 03.13 12 Sample Type Codes: Pli Post Hole: HA,blond Auger: SS Split Spoon: ST•Shelby Tube: DP=Direct Push: Sl' Sonic Core: Dl'-Drill Cuttings Moisture Content Codes: D-Dry: M-Moist: W-Wet: S-Saturated Florida Depanment of Environmental Pmiection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Undue Well Number. Permit Number: I I)EP Facility Identification Number 2 8d 53/8628320 Site Name: Borehole Start l Date: (2 i rt' Borehole Start Tiine: i Z s I ❑AM Or I C l'(`'( L �( End Dale: End Time 40t>' ❑AM PM n Fnvimmental Conti aciot Geologist's Name: __ En iu nt.1 .}me mal hniciam's N. E SCIENCES,INC. r Imo, Drilling Company .--5 Pavement Thickngss�inches): Borehole Diameter nches): I Borehole Depth(feel): f�/! N�/jl e 7Z1C Drilling Method(s): Apparent Elm elude DTW(in feet Measured Well DTW tin feet after OVA(list model and check type): • from soil moisture content): nater r charges m welll: NONE ❑FID ❑PID Disposition of l)rXf Cuttings'cheek method(s)J. ❑Drum ❑Spread ❑Backfill ❑Stock Pile ❑Other (describe it other or multiple items ore checked!. Borehole Completion(cheek one): ❑Well ❑Grout ❑Bentonite El Backfill El Other(describe) ee B 3 c " 7 ' I = _ Sample Description a Lab Soil and Groundwater C = - n a ' Q Z m. Cs a a C (include grain size based on US('S,odors.staining. c Samples(list,nmpie number and depth a d e ° C C Y T and other remarks) B e or tentporar)screen interval) 4k i. 1Z \, 13 Stars 5,^ p 60 i 30 0 �k 2 IL _ A-e.e. s s j 5 7Vi- Eiv K~ (D([_ B 40""`' Y t 1 � F SA,4-11 5 r i-TT III vii 4 x ) 13 F'. r 14 Af---0S 5 CT-Sria ,r— Ao s I() II 12 Sample I've Codes: PH-Post lisle: ILA-Hand Auger: SS=Split Spoon: ST=Shelby Tube: DI'=filed Push:: SC=Sonic Core: DC DI ill Couple, Moisture Content Codes: I)=Dry: M=Moist: W=Wet: S=Saturated Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Dor'tg Well Nuuber. Permit Number PU1:P Facility Identification Number: //77 jjjvvvD' / 53/8628320 Site Name: / Borehole Start Date: If(Z ("1 Borehole Start Time: 1W Dv ❑AM PM &I 0 t" (�:i(, �r-iEnd Dale: End Time: f/0 ❑AM ]PM Envirot mental Contractor: Geologist's Name: E noir iii Technician's Nyeit E SCIENCES,INC. l , (i-C'l- - P Drillin e C5pany. Pavement 1 li uk ess(inches): Borehole Diameter(inches): 13o'rehole Depth(feet): N 3.: Drillin Method(s): Apparent Borelrok DTW lin feet Measured Well DTW tin feet after OV el:nil heck type): 5 Iron soil moisture content)' waxer recharges in writ( NONE ❑FID ❑PID Disposition of Drill Cuttings Icheek tnethod(sl] ❑Drum ❑Spread Backfill 0 Stoc 'ile ❑Other (describe if other or nmdhiple•items are checked): Borehole Completion(check one): ❑Well ❑Grout ❑Bentonite s8ackfrll ❑Other(describe) 3 c 7 f7 Z n co O C t' C y v.•B 2 Ec. o -o = m , c Sample Description n c Lab Soil and Groundwater d z Y, a o (include grain size based on US('S,odors.staining, Samples(list sample nuttily/and depth C A ' ° C and other remarks) p e 1 C t Y Q or ttmporar)screen htenaB •44, t ,-7_ \ .0gasr,- ,....-e_ 5.4_--,41. 1 4 i5bevit-A4c- .4,.. ..tti"e'n"1-0-1.-)" it, dyy. 1,_ \ I ..0,.., F.,....-e- rA-v.--ti 5c-r Slurs Sett, `l ./vim t /"E 3 �R'� S L r SG C 75 ifiA 1) ., b AI LI4 0.-- tA.S4.-L t-. ( L a ^'e-S S c,07.50k p �1 roe o o lit 11 12 Sample Type('odes: PI -Pon I tole: 11A (land.Auger: SS-Split Spoon: ST Shelby lube: 1)1' DihCC(I'u,h: S('-Sonic('ore: D('.(hill Cuttings Moisture Content Codes: 0=Dry: M=Moist: W=Wes S=Saturated Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Boring/Well Number: Permit Number: FDEP Facility Identification Number g/S Site Nance: '� Borehole Start Date: 40,..�Af Borehole Start Time: /y im AM PM �'a°r 1 O _G #44te i‘le—e— End Date. End Time: /Lr 2- ❑AM PM FinvirnnnieentalContractor: Geologist's Name l-snvironinenta T hnictmt's atilt E SCIENCES,INC. ��C I)rillir1g,Eolnpany: Pavement'Meknesg(igches) Borehole Diameter(inches:). Borchoc Depth(feet I)iillil;Med (s) Apparent Borehole DTW(in feet Measured Well DW T (in feel after OVA(I in deed check type) _�/t" from soil mmslure content) nater reetmrnes m Well) NONE CI FIB 1=1 PID Disp /tion of Drill Cuttings[check in ❑Drum ❑SDread Backfill ❑Stock Pile ❑Other (describe if other or multiple items are shocked): Borehole Completion(check one). ❑Well ❑Grout ❑Bentonite pi'Beckfill ❑Other(describe) co r o 9 7 3 6.s A ?_ rt 6 A v Sample Description y 2 Lab Soil and Groundwater n ^ m (r' ,_ cc ` 6, Q c (include grain sae based on USCS,odors,staining, , n Samples(list sample number and depth • '-' y C Q n n ° O <O Y m^ and other remarks) B Tz a Q, v or temporary screen interval) Gt. r, R •y a E. • .- (o - Ft,,, 4Z �Z \` 2 „SSD - 5 4.-'C S1 c.TS Sri ilkFmak- QK rr.M. ])3 1-2- , es. S A...1, __ 3 , L7, ( (,t1?/ s � ALT Sc t--t--7-3� Jl V'At b 7 8 9 10 II 12 Florida Department of Environmental Protection-Division of Waste Management-Bureau of Petroleum Storage Systems BORING LOG Page I of Boring/Well Number Permit Number: / FDEP Facility Identification Number: Site Name: Borehole Start Date: of 42/Op Borehole Start Time: i tip) ❑AM;1.'M Ctiy 0 G te42.40#4— End Date: I ( / End Time /4,90 ❑AM PM Environmental Contractor: Geologist's Name: Environmental Technicians Name E SCIENCES,INC. -- , 1-le 'L Drilling Coulpty: Pavement Thickness(inches): Borehole Diameter Ouches). Borehole De tp h(deet): lye l` lA,'j ✓r Itc Drillin� /Method(s): Apparent Borehole DTW Br feet Measured Well DTW(in feet after OVA(hissluipdel- nd check type): .1 A from soil moisture content). r svmcr recharges in will/: NONE ❑FID ❑PID Disposition of Drill Cuttings(check method(s)): ❑Drum ❑Spread 'Backfill ❑Stock Pile ❑Other (describe i/other or-rrrahrple items are checked): Borehole Completion(check one): ❑Well ❑Grout ❑Bentonite 'Backfill ❑Other(describe) v r` to o a m v o `+1 O C o m n e .-.9 V. 1 C Z m tis In• 5 v I p• n A ; " Sample Description n e Lab Soil and Groundwater 7, es ,1 Q x Ls, pt; a O Q (Include grain size bused on USCS,odors,staining, rn 'co � O is ,� samples(list sample number and depth 9 t� o Q p 0 Y and other remarks) 8 0 or temporary screen interval) f-44/pLer 4' 4 1 (z, \ f!tl1 .,., 4--,m /,,,,,,-- 1 *A- Z 1Z 2 VD $tr511- - SM J b(c_ t-f4 ZZs —s.c-77 St- f \ ,,,,..,,, F-,..4.t.- Sh...4) _644 , lifk (,I \ fqj S 6 7 8 5 10 II 12 APPENDIX C 0 z C• .-, U 1 0 X o Wc-i) s S LLJ a_ Q• z Z �� O I- U W U CC H U ", 1..3 Cm :� : j' ci � jto- � U i, o O I- c ~ z lli ZE o )_ � m 2 � Jw M c 0 } 1— Z (/) 0 Z ID Z _> ° -; a w LL rs' I I- � Z w z cn w 3 CL can CI �'� ►J Rt"-- v w c r;--, -a za J ' Vel o .� En w E p� otf v 13 W C.n 8 0 Io L J (/) C4 > �' ` y� , 1J C 7 E.• ° 1 o Q— - o N U) p ^ p 1 0 W mo MO <o o N x 1, a� d I o 5 n_ r� I- � w a Vi Q "q..(Vs Q.( ° (i� - I- N , — Cs) '` w 2 r > tn i. N _,,i y C O c 2" Z o _c ��"111 O ii CC C Q CO p co w C to to m QcC 6 aC CDG_ ----- CO 0 Ce ;'; T C.) _J < ,. ...4......1Ci_ - .-.)c._. 4v J vCO - , .4 ti WO I- ~ Z J Lu g % .1 W UU 'Un M I.0 0 ›- N N • N \ Ce I- z ��`` ff`` V OU Cl) O O o !\ Z o Q •-•( �, 0 w o0c _J a W U W 1L LL I-00 Z V~)�f/l)) Irl CO CO W Z r I E 'D W �I 8 0 a `" l r\1 a J O d F- 1 r 7 `(T thkai ��`? \ W \ o J O d -� VV W 8 A n N o z A a O :- I- _ ` X Ts U) 0 v 0 0 N 9 13 ?a \j'(:) \..., � )` i ) ,,., k 5y , vi ZTo } , > N > _ `» o @'4 co w ^@' v �. - O N C O r + ,- p . 6 b Q o'\ ^\'il � N sli — t'=*--• C Q m O CI CI c es ® co *-3 C/) v tY a 0 Q - C U.) A 0 d U U a Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE SITE NAME: C t or C`L ; ��l/`�r LOCATION: C�. tt�0,,4 r �i t. WELL NO: EA" , 06 SAMPLE ID: 7 tA, . oc l DATE: 9121 v7 o? ffff [/ PURGING DATA WELL ) �/ TUBING y„p !/ WELL SCREEN INTE�jVA STATIC DEPTH / PURGE PUMP TYP DIAMETER(inches): / - DIAMETER(inches): / DEPTH. Z0 feet toe. feet TO ~ (TO WATER(feet): OR BAILER: WELL VOLUME PURGE: 1 WELL VOLUME= (TOTAL WELL DEPTH - STATIC DEP H TO WATER) X WELL APACITY L (only fill out if applicable) P� ON / = ( _ feet- feet) X g lonslfoot gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL=PUMP VOLUME+(TUBING CAPACITY X TUBING GTH)+FLOW CELL VOLUME (only fill out if applicable) = gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBING 1Z FINAL PUMP OR TUBING e el.Z PURGING PURGING 'J TOTAL VOLUME DEPTH IN WELL(feet): ii-- ie DEPTH IN WELL(feet): INITIATED AT:076..' ENDED AT: 0 Qt�7 PURGED(gallons)_ VOLUME CUMUL. DEPTH pH COND. DISSOLVEDOXYGENT. VOLUME PURGE TO TEMP. (circle units) TURBIDITY COLOR ODOR TIME PURGED PURGED RATE WATER (standard (°C) t mhos/cm (circle units) (NTUs) (describe) ! (describe) (gallons) (gallons) (gpm) (feet) units) 4r pS/cm %mg/L Q saturation Oq Q .p ' - -(8 ;04s ,e5-41.? 25/ /.23 ,Oo /fe 'ate 10 3 ) 66M041 ,o g z5� t50 9G 3 o�e DAH — ( II 7-.07 Z5 .!o8 2.3 t f S N [ 3 eLe. Note WELL CAPACITY(Gallons Per Foot): 0.75”=0.02, 1"=0.04; 1.26"=0.06; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 118"=0.0006; 3/16"=0.0014; 1/4"=0.0026; 5/16"=0.004; 3/8"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; PP=Peristaltic Pump; 0=Other(Specify) MPLIN¢ DATA AM D BY(PRINT)/ FI TION: SAMPLER( GNAT E(S):/ / SAMPLING SAMPLING L. tt e )0 L.1e e"Sa (4- +/ INITIATED AT: O ala ENDED AT: /O 00 PUMP OR TUBING T ING l FIELD-FILTERED: Y N, FILTER SIZE: pm f DEPTH IN WELL(feet): MATERIAL CODE: pe Filtration Equipment Type: FIELD DECONTAMINATION: PUMP Y / N TUBING Ci...,' ) N(replaced) DUPLICATE: Y /tv SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED SAMPLING SAMPLE PUMP SAMPLE R MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE ID CODE CONTAINERS CODE VOLUME USED ADDED IN FIELD(mL) pH METHOD CODE (mL per minute) 1w-oS 4 t to 14cC -- Zf Q .0.� 4 ( L ��P � 31r'rW•01 t25-0 ."C b'7+l4t-AG1.9 iz,"1.. kKS repp ,r)*/0 ?fw dS I Gk�1G Z`i0 Ai >vt,� .c dap - 3Q�'f t m- AP p 6.69-9 REMARKS: MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Railer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FCR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:±0.2°C Specific Conductance: ±5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,+0.2 mg/L or+ 10%(whichever is greater) Turbidity:all readings<20 NTU:optionally+5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG F SITE SITE NAME: C f oG 1,14/144-61/1/1 /�W f>' LOCATION: L'�� N� /r` C` WELL NO: • ! I SAMPLE ID: iii .03 I DATE: /�o/ P GING DATA (z,t WELL / TUBING WELL SC EEN INTERVAL STATIC DEPTH PURGE PUMP TYPE DIAMETER(inches): jr DIAMETER(inc es): / DEPTH:70feel to 2 feet TO WATER(feet)~! OR BAILER: .)P WELL VOLUME PURGE: 1 WELL VOLUME= (TOTAL WELL DEPTH - STATIC DEP1fH TO WATER) X WELL CAPACITY r (only fill out if applicable) 5 at M ®W1141 = ( feet- feet) X gallons/foot - gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL.=PUMP VOLUME+(TUBING CAPACITY X TUBING LENGTH)+FLOW CELL VOLUME (only fill out if applicable) gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBINGFINAL PUMP OR TUBING PURGING PURGING TOTAL VOLUME DEPTH IN WELL(feet): N 2'Z DEPTH IN WELL(feet): ~ 2.,0INITIATED AT. /la ENDED AT PURGED(gallons): CUMUL. DEPTH pHCOND. DISSOLVEDOXYGEN1 VOLUME VOLUME PURGE TO TEMP. (circle units) TURBIDITY COLOR ODOR TIME PURGED PURGED RATE WATER (standard o0 (circle units) (gallons) units) ( ) pmhos/cm mg/L or (NTUs) (describe) (describe) (gallons) (gpm) (feet) or IlS/cm %saturation l( 3 Z 0.0q157r/t �( ( 24-q4,1156 04-5 / -co 1 wes` o 14rAt 1( 3 .- b .oar 5utec . 1'S Z(� •e 3 f Sc� Do. (S' (SD ru►1a / 1 ,. c� WELL CAPACITY(Gallons Per Foot): 0.75"=0.02; 1"=0 04; 1.25"=0.06; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 1/8"=0.0006; 3/16"=0.0014: 1/4"=0.0026; 5/16"=0.004; 318"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; PP■Peristaltic Pump; 0=Other(Specify) SAMRE(S)N , TA S)pMP�E/p BY(PRINT)/AF ILIATION: SA P SIGNAT RE(S): SAMPLING SAMPLING t. (�6 N Dille ,�/ i1 � / INITIATED AT: ILO ENDED AT: �ZoD PUMPIIIORMTUBING ? / TUBING • FIELD-FILTERED: YFILTER SIZE: pm DEPTH IN WELL(feet): r 20 MATERIAL CODE: / Filtration Equipment Type. FIELD DECONTAMINATION: PUMP D N TUBING 19 N(replaced) DUPLICATE: Y ��' SAMPLE CONTAINER SPECIFICATIO SAMPLE PRESERVATION INTENDED SA NG SAMPLE PUMP SAMPLE II MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE VOLUME METHOD CODE (mL per minute) ID CODE CONTAINERS CODE USED ADDED IN FIELD(mL) pH rl u''0? '; ( a IQ Pt Ho- v ,,,,0 l�t'L -D.25 -�v-off Z Au _ 137,117o•C7 -1 ,4* 1 lit, .10/4 palitt 4Z* / plbosilrl reitpcpf b.2./ ..1, Iv) I 'R r " • ,rlik J 35a.1— ' ' D• ID9-1 REMARKS' MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon: 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGF OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:±0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,+0.2 mg/L or+ 10%(whichever is greater) Turbidity:all readings<20 NTU;optionally+5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE NAME: CIry O ( lcs? +/T // al/eke ' e,d LOCATION: (_,Lam.. r (ice . WELL NO: drtp D c ( SAMPLE ID: , ).-O L DATE: Aizifr,11111PURGING DATA ( WELL / r TUBING • WELL SCRE N INTERVAL STATIC DEPTH PURGE PUMP TYPE DIAMETER(inches): "DIAMETER(inches).r DEPTH:�, feet to / feel TO WATER(feetr'/er, TOR BAILER: pyC, WELL VOLUME PURGE: 1 WELL VOLUME_ (TOTAL ELL DEPTH - STATIC DE H TO WATER) X WELL C ACITY (only fill out if applicable) rfN ON L _ ( feet- feet) X Cl-00 gall stfoot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL.=PUMP VOLUME 4(TUBING CAPACITY X TUB( G LENGTH)+FLOW CELL VOLUME (only fill out if applicable) = gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBING FINAL PUMP OR TUBING / PURGING PURGING TOTAL VOLUME DEPTH IN WELL(feet): DEPTH IN WELL(feet): J" INITIATED AT: 1010 ENDED AT/O 3B PURGED(gallons): CUMUL. DEPTH pH COND. DISSOLVED VOLUME VOLUME PURGE TO TEMP. (circle units) OXYGEN TURBIDITY COLOR ODOR TIME WATER PURGED PURGED RATE (standard o (circle units) units) ( C) umhoslcm mg/L (NTUs) (describe) (describe) (gallons) (gallons) (gpm) (feet) of uS/cm % �� saturation irsitrit7 I 0•ti rQ' � ^'l 't.qT L.?sl 8,,,t/ / ?-n l©33 4 g.a9 26.3y 7,5-"z g_ o9 lot ' , 1 g g,.0- ?,m,2_,..,913s'?-- 4.,o -co- . `= WELL CAPACITY(Gallons Per Foot): 0.75"=0.02, 1"=0.04; 1.25"=0.06; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1.02, 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 1/8"=0.0006; 3116"=0.0014; 1/4"=0.0026; 5116"=0.004; 3/8"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric ubmersible Pump; PP=Peristaltic Pump; 0=Other(Specify) „SAMPLING ITA 1 LAMPI D BY(PRINT)/ F II IAf(ION SAMPL R £ ATUR ): i // SAMPLING • SAMPLING i1/ ,; JC �SC `,y_-. / %;�I INITIATED AT:l ENDED AT: )a�a • PUMP OR TUBINGTUBING ' 1 FIELD-FILTERED: Y N FILTER SIZE: µm / DEPTH IN WELL(feet): / r✓1 q MATERIAL CODE: p, v Filtration Equipment Type: FIELD DECONTAMINATION: PUMP Y N TUBING Y N(replaced) DUPLICATE: Y N SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED SAMPLING SAMPLE PUMP SAMPLE k MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE VOLUME METHOD CODE (mL per minute) 7 I��E CONT CODE � I�S� ADDED IN FIELD(mL) pH �n,-� ,� Y 3 {J�tsf`R ,at — v� A"TW-tly 2 k4 I t, - -- — 7v . gf,o -rra.o Y I 1. +)J o M�. l`�, . , ?' R ' Q►( 2A3 5v144164-- Tµ'-01 ► P(/ - 4 ,,+ir /350.2 AP? p.0 REMARKS: -- - ---— -. MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; O=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,±0.2 mg/L or±10%(whichever is greater) Turbidity:all readings<20 NTU;optionally+5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE dliE NAME. C�- j 0(r (,L�Mep►( /Wii)'( ' LOCATION CWELL NO: l w 0j„ SAMPLE ID: ,A, f DATE: 9 / (D ti ww PURGING SDATA l� f:! 1 WELL N TUBING 1 9 t/ WELLS /EEN INTER STATIC DEPTH PURGE PUMP TT�YPE DIAMETER(inches) lJ DIAMETER(inches): 14 DEPTH:69 feet to C. feet TO WATER(fed I OR BAILER f- f WELL VOLUME PU GE: 1 WELL VOLUME= (TOTAL WELL DEP1 H - STATIC DEP H TO WATER) X WELL CAPACITY / f (only fill out if applicable) C�w^� y = ( feet- feet) X gallons/foot = _gallons EQUIPMENT VOLUME PURGE; 1 EQUIPMENT VOL.=PUMP VOLUME+(TUBING CAPACITY X TUBING LENGTH)+FLOW CELL VOLUME (only fill out if applicable) gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBING FINAL PUMP OR TUBING PURGINGPURGING TOTAL VOLUME DEPTH IN WELL(feet): DEPTH IN WELL(fee:): INITIATED AT: 210 ENDED AT: /e q.? PURGED(gallons): CUMUL. DEPTH COND. DISSOLVED VOLUME VOLUME PURGE TO pH TEMP. (circle units) OXYGEN TURBIDITY COLOR ODOR TIME PURGED PURGED RATE WATER (standard (<'C) µmhos/cm (circle units) (NTUs) (describe) (describe) (gallons) (gallons) (gpm) (feet) units) frS/cmo mg/L or %saturation jI`� Nib • �" 1 �� — G .e G1 ,Z,97 ��o (LYS.S. l�' 3 `r 7n Sci L/'{fs ii`� �� ,0-i-74, q Ov °• ti - - joo $ I WELL CAPACITY(Gallons Per Foot). 0.75"=0.02; 1"=0.04, 1.25"=0.06; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1 02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gat./Ft.)• 1/8"=0.0006; 3/16"=0.0014; 1/4"=0.0026; 5116"=0.004; 3/8"=0.006; 1/2"=0.010: 518"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; PP=Peristaltic Pump; 0=Other(Specify) ' MPLING.'i ATA • SAMPLE Y(PRINT)/A F4TION: SAMPLER(S :GNATUR S) SAMPLING if Q SAMPLING V' �' l / _ '✓ INITIATED AT: 1 V ENDED AT: I v r PUMP OR TUBING Tu—ObFIELD-FILTERED: Y FILTER SIZE: pm DEPTH IN WELL(feet): MATERIAL CODE: FI. _.\Filtration Equipment Type: FIELD DECONTAMINATION: PUMP N TUBING Y N eplaced) \ DUPLICATE: Y SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVA N / INTENDED SAM G SAMPLE PUMP SAMPLE # MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE ID CODE CONTAINERS CODE VOLUME USED ADDED IN FIELD(mL) pH METHOD CODE (mL per minute) -f tv-ot 5 5,(6, Lk 14 14t, ?.ID 4Wre 2 0 -fel fa)-0e ► VI, Z4oMf,,NrMtc, ki4D • Pete err s tyt , o ery-OV I L I 5OEMAmu&l 'r"'`" p•o ireou , Av... ... ,0.z_ pt,4 6.O f 1 REMARKS: MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) • NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2 00 Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,+0.2 mg/L or+ 10%(whichever is greater) Turbidity:all readings<20 NTU;optionally+5 NTU or+ 10%(whichever is greater) Revision Date: February 12, 2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE SITE NAME: 6 ertt Nr („l0 N7 (((e,0,/T t% LOCATION: G tee e�T rC WELL NO: M w •-• ( 5 SAMPLE ID. 4/�t ' ( S DATE: l /2 2ro 1 PURGING DATA WELL TUBING In / WELL SCREEN INTERV L IS STATIC DEPTH 9 PURGE PUMP YPE DIAMETER(Inches) 2. f DIAMETER(inches): t.( DEPTH feet to 2� .feet TO WATER(feet): `'(�� L Z OR BAILER: 4 WELL VOLUME PURGE: 1 WELL VOLUME_ (TOTAL WELL DEPTH - STATIC DEPTH TO WATER) X WELL CAPACITY (only fill out if applicable) p _ ( •25 feet- 9.4?z- e X gallons/foot = (.&lc gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL.=PUMP VOLUME+(TUBING CAPACITY X TUBING LENGTH)+FLOW CELL VOLUME (only fill out if applicable) = gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBINGFINAL PUMP OR TUBING PURGING /� PURGING pTOTAL VOLUME DEPTH IN WELL(feet): % '1,- DEPTH IN WELL(feet): 1 1 7i INITIATED AT: Q gsti ENDED AT: Q !51 PURGED(gallons) CUMUL. DEPTH COND. DISSOLVED VOLUME VOLUME PURGE TO PH TEMP. (circle units) OXYGEN TURBIDITY COLOR ODOR TIME PURGED PURGED RATE WATER (standard (eC) t�mhos/cm (circle units) (LATUS) (describe) (describe) (gallons) (gallons) (9Pm) (feet) units) or trS/cm mg/L or %saturaton !\o •fi o 0. o • --0 .eq5 oqr - C[c Nom S, a ., r. a _ A, D95 t al- 4`l°I 210.10- too 5.0u1 CtC.f�'G N4)'sot 1 /p)°! �S I) `r ' - / r?9 0 ,oY5 •1 - t,i,cop 7-10.% '7 q- t-' . ( 3 o, 5-1- 047 ` 9 - ? ,l 8o .6(15. 1_11- 1 D 241.LN foo 5 . 0 ? _� I r Ir 1t f 1 V l� .34 •D.o ( .1'?" L/. 73 26,. ti4" / oo ,-. 0 ( t( rr t r WELL CAPACITY(Gallons Per Foot): 0.75"=0.02: 1"=0 04; 1.25"=0.06; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 1/8"=0.0006; 3116"=0.0014; 1/4"=0.0026; 5/16"=0.004; 3/8"=0.006; 1/2"=0.010; 518"=0.016 PURGING EQUIPMENT CODES: B=Bailer, BP=Bladder Pump, ESP=Electric Submersible Pump; PP=Peristaltic Pump; 0=Other(Specify) SAMPLING D 'TA AMP D BY(PRINT)/ FILIATION: SAM" '�)SIGNAT RE(S). SAMPLING I SAMPLING s e11 4h t INITIATED AT: (0 0� ENDED AT: (O( 0 PUMP OR TUBINGI / BING (f i % FIELD-FILTERED: Y © FILTER SIZE: µm DEPTH IN WELL(feet): 1 ,�r'� /MATERIAL CODE: V TE Filtration Equipment Type: FIELD DECONTAMINATION: PUMP '/Y/ N TUBING Y N( placed) DUPLICATE: Y SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATION INTENDED SAMPLING SAMPLE PUMP SAMPLE /I MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE VOLUME METHOD CODE (mL per minute) ID CODE CONTAINERS CODE SED ADDED IN FIELD(mL) pH µau- y L(o„Lt+t- — eo f 0 : 07 5 Mw-11 2 A- b l — to— -ke 6. j `f �+,N,,[s ( L7 !/ '2-50 Pry ft4--� p9124•( aC(' ' , r :17) ..02 3 ►- cs f L _‘,(4,-. f-4 1 ?oo N► . , ,- '�," e.i 4 ickfrtlAkA 55-6.2, REMARKS: MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,+0.2 mg/L or+ 10%(whichever is greater) Turbidity:all readings<20 NTU;optionally±5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE , SITE NAME:�� 0 p- 6(�c"C�"'^�r_ iJV'�(� LOCATION: WELL NO:1ry1vi+ - ,,s+ SAMPLE ID: lou,,, 2 S DATE: Q/l,'/cU tPURGING DATA I 1 WELL TUBING OP L WELL SCREEN INTER�1[A,�� 'vk L STATIC DEPTH PURGE PUMP TYPE DIAMETER(inches) DIAMETER(inches): "/ DEPTH: feet to 9' .feet TO WATER(feet): 11 ,19 OR BAILER: pp WELL VOLUME PURGE: 1 WELL VOLUME= (TOTA WELL DEPTH - STATIC DEPTH TO WATER WELL CAPACITY r�/ (only fill out if applicable) 1. (0-4 `� `J /• `�, EQUIPMENT VOLUME PURGE: 1 EQUIPMENT(VOL PMP VOLUME+(TUBING CAPACITY feet) TUBING LEN• GTH)+FLOW CELL VOLUME gallons (only fill out if applicable) = gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBING FINAL PUMP OR TUBING PURGING PURGING 2 TOTAL VOLUME DEPTH IN WELL(feet): 1Z DEPTH IN WELL(feet): INITIATED AT: (34 ENDED AT: 1,7'v PURGED(gallons): 7 CUMUL. DEPTH COND. DISSOLVED VOLUME VOLUME TIME PURGED PURGED PURGERATETO pH WATER (standard T(°C) (circle units) (Oce units)XYGEN TURBIDITY (describe) (deCOLOR DOR sscrbe) (gallons) (gallons) Wm) (feet) units) Z PS/cm %mg/L g saturation 9 2 i. A l , .}- 6J I' ;11)44- S. -ill ��.-1S52 ',v?- q,g &c- �' I jii (O 6 '?,, j , i / go, H x 5. •43 z17'.- 5-.3 0 .3 11 11) Di z, , A5 1 lib ./0.u / ", l�I( 2 5' Co. I 10 ,Z r. 1 ° o.tib . uYS �4 Q1-' .1 /p. q� _ 12,Zi WELL CAPACITY(Gallons Per Foot): 0.75"=0.02; 1"=0.04; 1.25"=0.08; 2"=0.16; 3"=0.37; 4"=0.65; 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 118"=0,0006; 3116"=0.0014; 1/4"=0.0026; 5116"=0.004; 318"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer, BP=Bladder Pump; E P=Electric Submersible Pump; PP=Peristaltic Pump; 0=Other(Specify) S M IN DATA SAMPLED BY(P 1NT)/ FFILIATION: SA PL S)SI AT S)' SAMPLING L, $ SAMPLING INITIATED AT: ( ENDED AT:PUMP OR TUBINGELD-FILTERED: Y / FILTER SIZE: tun DEPTH IN WELL(feet): "Zj(/ MATERIAL CODE: ,ea/�� Fi ••lion Equipment Type FIELD DECONTAMINATION: PUMP N TUBING ea,.•laced) DUPLICATE: Y LSAMPLE CONTAINER SPECIFICATION SAMPLE 13- SE-•• 10 INTENDED SING SAMPLE PUMP SAMPLE # MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE ID CODE CONTAINERS CODE VOLUME USED ADDED IN FIELD(mL) pH METHOD CODE (ml per minute) 04w-2.3 Z kit l. 0 '' 2. - • ( 2 !o Pim•2> ( IN, !ti N LOW.Alii'DL....^ .--- Rzierki'y ebitla+� • D•O ?•3 Mw-Zs iL S�,pi tbf c kJ) 1 v jc(�--tG!`' p • r 'l G. yMw-IS �(, A1-4 - 35 -0.,Z AT? . f Z 4 REMARKS: MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: t The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,±0.2 mg/L or+10%(whichever is greater) Turbidity:all readings<20 NTU;optionally±5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 21"%2-- GROUNDWATER SAMPLING LOG SITE SITE NAME: (AT 1 0 M ateg t/ (Nr8 (+ LOCATION: f, p'''T p'C A f WELL NO: I W✓3 S I SAMPLE ID wr ?S J OA DATE: o ft�1 11,Q, v PURGING DATA I ff WELL TUBING 00 I WELL SCREEN INT V STATIC DEPTH i" / PURGE PUMP TYPE DIAMETER(inches): 1 DIAMETER(inches): (j DEPTH: feet tc1 7. eet TO WATER(feet):f .10,3 OR BAILER: WELL VOLUME PURGE: 1 WELL VOLUME= (TOTAL WELL DEPTH - STATIC DEPTH TO WAT6VID X WELL CAPACITY (only fill out if applicable) / Q.3Z_ G, ? = ( 3Z. ?'S feet- 1 feet X .allons/foot = gallons EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL.-PUMP VOLUME+(T :I APACITY X TUBING LENGTH)+FLOW CELL VOLUME (only fill out if applicable) = gallons+( gallons/foot X feet)+ gallons = gallons INITIAL PUMP OR TUBINGFINAL PUMP OR TUBING PURGING + PURGING TOTAL VOLUME DEPTH IN WELL(feet) i (. . DEPTH IN WELL(feet). 1(o.j INITIATED Alt .2�j ENDED AT: /�Z PURGED(gallons): �,O CUMUL. DEPTH pH COND. DISSOLVEDOXYGENl VOLUME VOLUME PURGE TO TEMP. (circle units) TURBIDITY COLOR ODOR TIME PURGED PURGED RATE WATER (standard (°C) r,mhos/cm (circle units) (NTUs) (describe) (describe) (gallons) (gallons) (9Pm) (feet) units) or 1,S/cm mg/L or /°saturation 1 iy3e pz 00/6 M.?ie (,..53 . . Gs' /_ ?' L `rte..; jivoetrtY W. .0 r • o—L 1.�, $ �a . .;�I r-- WELL CAPACITY(Gallons Per Foot): 0.76"=0.02; 1"=0.04; 1.25"=0.06; 2"=0.16; 3"=0.37; 4"=0.65, 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./Ft.): 1/8"=0.0006; 3/16"=0 0014; 1/4"=0.0026; 5/16"=0.004; 3/8"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric S mersible Pump; PP•Peristaltic Pump; 0=Other(Specify) JAMPLING D SAMPLED BY(PRINT)/AFFIL TION: SAMP E GNATURE( SAMPLING L SAMPLING t 6" L' INITIATED AT: f Y� ENDED AT:.ii../53PUMP v1'6/%4, TUBI "-TUBING � FIELD-FILTERED: Y N FILTER SIZE: urn DEPTH IN WELL(feet): /(p 'jS' \ MATERIAL CODE: p( - Ea ration Equipment Type. FIELD DECONTAMINATION: PUMP ' Y ) N TUBING Y N replaced) DUPLICATE: Y SAMPLE CONTAINER SPECIFICATION SAMPLE PRESERVATIOA INTENDED CI SAMPLE PUMP SAMPLE il MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/OR EQUIPMENT FLOW RATE ID CODE CONTAINERS CODE VOLUME USED ADDED IN FIELD(mL) pH METHOD CODE (mL per minute) -3s 3 g ate la_ it&I- �refA D, b2P 0. ,35 Z ( L _ se © - _pD. ?b 'N)Y1 '-p1pp JO•o 2, !t„O 131 t P(' cjiMf l Ark L __ ( I tit.610; / C• k D.t 0 REMARKS: MATERIAL CODES: AG=Amber Glass; CG=Clear Glass; PE=Polyethylene: PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer, BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM=Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,±0.2 mg/L or+10%(whichever is greater) Turbidity:all readings<20 NTU;optionally±5 NTU or+ 10%(whichever is greater) Revision Date: February 12,2009 Form FD 9000-24 GROUNDWATER SAMPLING LOG SITE SITE NAME: Lent 0 F' Ci PWr vlv t W var LOCATION: ( Lettil ON 1.- /� WELL NO: i1tw, 55 SAMPLE ID: tit to„ ✓ S DATE: f /2-1/V/f 1 ,•` PURGING DATA IL WELL TUBING 71 0 1 WELL SCREEN INTE 1 STATIC DEPTH r PURGE PUMP T rfe DIAMETER(inches): Z- DIAMETER(inches),/(f DEPTH. feet to)�lieet TO WATER(feet): Z 4'•S OR BAILER: WELL VOLUME PURGE: 1 WELL VOLUME_ (TOTAL WELL DEPTH - STATIC DEPTH TO WATES..X WELL CAPACITY 6 n (only fill out if applicable) - ( 3 6feet) • •�!) . feet- gallons/foot = ` V )lions_ EQUIPMENT VOLUME PURGE: 1 EQUIPMENT VOL.- UM V LUME+(T NG PACITY X TUBING LENGTH)+FLOW CELL VOLUME (only fill out it applicable) = gallons+( gallonslfoot X feet)+ gallons = gallons INITIAL PUMP OR TUBING FINAL PUMP OR TUBING 3 0 PURGING // 15 PURGING t TOTAL VOLUME DEPTH IN WELL(feet): 17 0 DEPTH IN WELL(feet): N INITIATED AT:! -/ • ENDED AT. `S-39 PURGED(gallons): ( f ! •o !/ CUMUL. DEPTH COND. DISSOLVED VOLUME VOLUME PURGE TO pH TEMP (circle units) OXYGEN TURBIDITY COLOR ODOR TIME PURGED RATE WATER (standard C I,mhos/cm (circle units) NTUs (describe) describe A.A.b PURGED (ipc) ( ) (describe) units) mg/L Qr, (gallons) (gallons) (gpm) (feet) or tIS/cm o�saturation rD /8�` 0•I0 p,o1� 'f3 to .19 0 .31 0.p,x 1,ov l l 0 •S o - 8 •o . S.t. 7024.2 .4 I (04 2.a?— i7 (tem' (4 0 0. e0 - 0 •038i-4. aql24-4 z- • 09- / 0.0?-0 I. 031 o-08 2$•751 •f 1 2b.?2 16 t j-2,6 I `7 t i G. WELL CAPACITY(Gallons Per Foot): 0.75"=0.02 1"=0.04; 1.25"=0.06; 2"=0 16; 3"=0.37; 4"=0.65; 5"=1.02; 6"=1.47; 12"=5.88 TUBING INSIDE DIA.CAPACITY(Gal./FL): 1/8"=0.0006; 3/16"=0.0014; 1/4"=0.0026; 5/16"=0.004; 318"=0.006; 1/2"=0.010; 5/8"=0.016 PURGING EQUIPMENT CODES: B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; PP=Peristaltic Pump; 0=Other(Specify) PLING WITA SAMPLED BY(PRI 1 AFFILIATION: SAMPLERf( - NATUR ): / SAMPLING SAMPLING 1 �'� � , INITIATED AT: ,S ENDED AT: PUMP `�G � .7LIBING FIELD-FILTERED: Y / �O FILTER SIZE: um DEPT IN TUBING q,., DEPTH IN WELL(feet): /✓J`� MATERIAL CODE: P+ Filtration Equipment Typ FIELD DECONTAMINATION: PUMP /T) N TUBING Y enlaced) DUPLICATE: Y �� SAMPLE CONTAINER SPECIFICATI SAMPLE PRESERVA INTENDED SAMPLING SAMPLE PUMP SAMPLE ti MATERIAL PRESERVATIVE TOTAL VOL FINAL ANALYSIS AND/0R EQUIPMENT FLOW RATE ID CODE CONTAINERS CODE VOLUME USED ADDED IN FIELD(mL) pH METHOD CODE (mL per minute) Auv-5 1 - - gpp e .6.q Au,,‹s I p ?x M NfY, ArAD Lo P° 1� ' O.036 r Ykw-Ss I r S-Itp li , M VSs ( _ / ,---- .� 4----- 4,..0.,,i�F 350 Q d•Q mi REMARKS: --- -- —- - _- --- MATERIAL CODES: AG=Amber Glass; CG=Clear Glass: PE=Polyethylene; PP=Polypropylene; S=Silicone; T=Teflon; 0=Other(Specify) SAMPLING EQUIPMENT CODES: APP=After Peristaltic Pump; B=Bailer; BP=Bladder Pump; ESP=Electric Submersible Pump; RFPP=Reverse Flow Peristaltic Pump; SM_Straw Method(Tubing Gravity Drain); 0=Other(Specify) NOTES: 1. The above do not constitute all of the information required by Chapter 62-160,F.A.C. 2. STABILIZATION CRITERIA FOR RANGE OF VARIATION OF LAST THREE CONSECUTIVE READINGS(SEE FS 2212,SECTION 3) pH:+0.2 units Temperature:+0.2°C Specific Conductance: +5% Dissolved Oxygen:all readings<20%saturation(see Table FS 2200-2); optionally,+0.2 mg/L or+ 10%(whichever is greater) Turbidity:all readings<20 NTU;optionally+5 NTU or±10%(whichever is greater) Revision Date: February 12,2009 APPENDIX D TestAmerica THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT Job Number: 660-31745-1 Job Description: 1-0888-P17 For: ESciences, Inc. 34 East Pine Street Orlando, FL 32801 Attention: Jeff Peters Approved for release. Judith Beato Project Manager I 10,132009 3:25 PM Judith Beato Project Manager I judith.beato@testamericainc.com 10/13/2009 Revision: 1 Methods: FDEP. DOH Certification#: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories,Inc. TestAmerica Tampa 6712 Benjamin Road,Suite 100,Tampa,FL 33634 P - o'" Tel(813)885-7427 Fax(813)885-7049 www.testamericainc.com r . Page 1 of 166 10/13/2009 Job Narrative 660-J31745-1 Comments **Revised report due to client request to add Total Xylenes to 8260 and 1-methylnaphthalene and 2-methylnaphthalene to 8270 Variations from chain-Full priority pollutant metals done on the water samples and only RCRA 4 metals on the soils. Mercury performed only on the TW water samples Receipt All samples were received in good condition within temperature requirements. GC/MS VOA Method 8260B:The laboratory control sample(LCS)for preparation batch 85350 exceeded control limits for the following analytes: 2-chloroethyl vinyl ether. These analytes were biased high in the LCS and were not detected in the associated samples;therefore.the data have been reported. Method 8260B:All samples for 31745 were improperly preserved in the field. The preservative used is not compatible with acrolein, acrylonitrile and 2-chloroethyl vinyl ether.Client was informed of the discrepancy and analysis was performed and reported with client approval. Method 8260B:The matrix spike(MS)recovery for batch 85350 was outside control limits for acrolein. The associated laboratory control sample(LCS)recovery met acceptance criteria. This was due to the fact that these samples were preserved and the acid preservative degrades acrolein. No other analytical or quality issues were noted. GC/MS Semi VOA Method 8270C:The matrix spike(MS)recoveries for batch 85385 were outside control limits. The associated laboratory control sample (LCS)recovery met acceptance criteria. Method 8270C:The laboratory control sample(LCS)for batch 85385 exceeded control limits for the following analyte: 3,3'-Dichlorobenzidine. Samples were non detect for analyte and are appropriately flagged. No other analytical or quality issues were noted. Metals No analytical or quality issues were noted. General Chemistry Method 350.1:The matrix spike(MS)recoveries for batch 85394 were outside control limits. The associated laboratory control sample (LCS)recovery met acceptance criteria. Method 353.2:The matrix spike/matrix spike duplicate(MS/MSD)recoveries were outside control limits. The associated laboratory control sample(LCS)recovery met acceptance criteria. No other analytical or quality issues were noted. Organic Prep No analytical or quality issues were noted. Page 2 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-1 TW-05 Ammonia(as N) 0.077 0.020 mg/L 350.1 Nitrate Nitrite as N 29 J3 0.50 mg/L 353.2 Nitrate as N 29 0.50 mg/L 353.2 Total Recoverable Zinc 0.012 I 0.020 mg/L 60106 660-31745-2 TW-04 Benzene 5.4 1.0 ug/L 8260B Chlorobenzene 14 1.0 ug/L 82606 Mercury 0.000096 I 0.00020 mg/L 7470A Ammonia(as N) 20 0.20 mg/L 350.1 Nitrate Nitrite as N 0.11 I 0.50 mg/L 353.2 Nitrate as N 0.11 I 0.50 mg/L 353.2 Total Recoverable Chromium 0.0027 I 0.010 mg/L 6010B Zinc 0.0086 I 0.020 mg/L 60106 660-31745-3 TW-03 Benzene 2.2 1.0 ug/L 82608 Ethylbenzene 7.2 1.0 ug/L 8260B Methylene Chloride 12 5.0 ug/L 8260B Toluene 8.8 1.0 ug/L 82606 Xylenes,Total 14 3.0 ug/L 8260B Phenol 3.0 I 3.8 ug/L 8270C Mercury 0.00012 I 0.00020 mg/L 7470A Ammonia(as N) 0.37 0.020 mg/L 350.1 Nitrate Nitrite as N 0.28 I 0.50 mg/L 353.2 Nitrate as N 0.28 I 0.50 mg/L 353.2 Total Recoverable Antimony 0.0043 I 0.020 mg/L 6010B Arsenic 0.016 0.010 mg/L 60106 Chromium 0.052 0.010 mg/L 60106 Copper 0.011 0.010 mg/L 60106 Lead 0.014 0.010 mg/L 60106 Nickel 0.013 0.0080 mg/L 60106 Zinc 0.074 0.020 mg/L 6010B TestAmerica Tampa Page 3 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-4 TW-06 Xylenes,Total 4.2 3.0 ug/L 82608 Mercury 0.00012 I 0.00020 mg/L 7470A Ammonia(as N) 0.14 0.020 mg/L 350.1 Nitrate Nitrite as N 15 0.50 mg/L 353.2 Nitrate as N 15 0.50 mg/L 353.2 Total Recoverable Antimony 0.0044 I 0.020 mg/L 6010B Chromium 0.068 0.010 mg/L 6010B Copper 0.030 0.010 mg/L 60108 Lead 0.082 0.010 mg/L 6010B Nickel 0.031 0.0080 mg/L 6010B Zinc 0.37 0.020 mg/L 6010B 660-31745-5 MW-2S Nitrate Nitrite as N 1.9 0.50 mg/L 353.2 Nitrate as N 1.9 0.50 mg/L 353.2 660-31745-6 MW-3S Nitrate Nitrite as N 0.41 I 0.50 mg/L 353.2 Nitrate as N 0.41 I 0.50 mg/L 353.2 Total Recoverable Zinc 0.014 I 0.020 mg/L 6010B 660-31745-7 MW-5S Ammonia(as N) 0.12 0.020 mg/L 350.1 Nitrate Nitrite as N 0.35 I 0.50 mg/L 353.2 Nitrate as N 0.35 I 0.50 mg/L 353.2 Total Recoverable Arsenic 0.0081 t 0.010 mg/L 6010E 660-31745-8 MW-1S Nitrate Nitrite as N 0.50 I 0.50 mg/L 353.2 Nitrate as N 0.50 I 0.50 mg/L 353.2 Total Recoverable Zinc 0.0081 I 0.020 mg/L 6010B TestAmerica Tampa Page 4 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-9 SB-1@1' Arsenic 0.35 I 0.54 mg/Kg 6010B Cadmium 0.098 I 0.54 mg/Kg 6010B Chromium 6.5 1.1 mg/Kg 6010B Lead 5.1 0.54 mg/Kg 6010B Percent Solids 92 0.10 % Moisture Percent Moisture 8.1 0.10 % Moisture 660-31745-10 SB-1@2' Arsenic 0.33 I 0.53 mg/Kg 6010B Chromium 1.8 1.1 mg/Kg 6010B Lead 2.2 0.53 mg/Kg 6010B Percent Solids 94 0.10 % Moisture Percent Moisture 5.9 0.10 % Moisture 660-31745-11 SB-1@3' Chromium 3.3 1.0 mg/Kg 6010B Lead 1.7 0.52 mg/Kg 6010B Percent Solids 96 0.10 % Moisture Percent Moisture 4.1 0.10 % Moisture 660-31745-12 SB-1@4' Chromium 1.1 1.1 mg/Kg 6010B Lead 0.79 0.55 mg/Kg 6010B Percent Solids 91 0.10 % Moisture Percent Moisture 9.4 0.10 % Moisture 660-31745-13 SB-2@1' Chromium 0.91 I 1.3 mg/Kg 6010B Lead 1.1 0.66 mg/Kg 6010B Percent Solids 75 0.10 % Moisture Percent Moisture 25 0.10 % Moisture 660-31745-14 SB-2@2' Chromium 1.3 1.1 mg/Kg 6010B Lead 0.94 0.54 mg/Kg 6010B Percent Solids 92 0.10 % Moisture Percent Moisture 7.5 0.10 % Moisture TestAmerica Tampa Page 5 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-15 SB-2@3' Chromium 0.74 I 1.3 mg/Kg 6010B Lead 0.61 I 0.67 mg/Kg 6010B Percent Solids 74 0.10 % Moisture Percent Moisture 26 0.10 % Moisture 660-31745-16 SB-2@4' Chromium 0.83 I 1.1 mg/Kg 6010B Lead 0.73 0.53 mg/Kg 6010B Percent Solids 94 0.10 % Moisture Percent Moisture 6.2 0.10 % Moisture 660-31745-17 SB-3@1' Chromium 1.7 1.4 mg/Kg 6010B Lead 2.0 0.68 mg/Kg 6010B Percent Solids 73 0.10 % Moisture Percent Moisture 27 0.10 % Moisture 660-31745-18 SB-3@2' Arsenic 0.30 I 0.52 mg/Kg 60108 Chromium 0.95 I 1.0 mg/Kg 60108 Lead 0.89 0.52 mg/Kg 6010B Percent Solids 96 0.10 % Moisture Percent Moisture 3.8 0.10 % Moisture 660-31745-19 SB-3@3' Chromium 0.90 I 1.4 mg/Kg 6010B Lead 0.82 0.68 mg/Kg 6010B Percent Solids 74 0.10 % Moisture Percent Moisture 26 0.10 % Moisture 660-31745-20 SB-3@4' Chromium 0.91 I 1.1 mg/Kg 6010B Lead 0.86 0.53 mg/Kg 6010B Percent Solids 94 0.10 % Moisture Percent Moisture 6.4 0.10 % Moisture TestAmerica Tampa Page 6 of 166 10/13/2009 EXECUTIVE SUMMARY- Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-21 SB-4@1' Chromium 0.91 I 1.1 mg/Kg 60106 Lead 1.1 0.53 mg/Kg 60106 Percent Solids 95 0.10 % Moisture Percent Moisture 5.0 0.10 % Moisture 660-31745-22 SB-4@2' Chromium 0.67 I 1.1 mg/Kg 60106 Lead 0.68 0.53 mg/Kg 6010E Percent Solids 95 0.10 % Moisture Percent Moisture 5.1 0.10 % Moisture 660-31745-23 SB-4@3' Chromium 0.75 I 1.3 mg/Kg 6010B Lead 0.67 0.63 mg/Kg 60106 Percent Solids 79 0.10 % Moisture Percent Moisture 21 0.10 % Moisture 660-31745-24 SB-4©4' Chromium 0.60 I 1.1 mg/Kg 6010B Lead 0.59 0.57 mg/Kg 60106 Percent Solids 88 0.10 % Moisture Percent Moisture 12 0.10 % Moisture 660-31745-25 SB-5@1' Chromium 1.1 1.0 mg/Kg 6010B Lead 0.93 0.52 mg/Kg 6010B Percent Solids 97 0.10 % Moisture Percent Moisture 3.2 0.10 % Moisture 660-31745-26 SB-5@2' Chromium 1.4 1.4 mg/Kg 6010B Lead 1.2 0.69 mg/Kg 60106 Percent Solids 73 0.10 % Moisture Percent Moisture 27 0.10 % Moisture TestAmerica Tampa Page 7 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-27 SB-5@3' Chromium 1.4 1.0 mg/Kg 60106 Lead 1.1 0.52 mg/Kg 6010B Percent Solids 95 0.10 % Moisture Percent Moisture 4.6 0.10 % Moisture 660-31745-28 SB-5@4' Chromium 1.3 1.1 mg/Kg 6010B Lead 1.0 0.55 mg/Kg 60108 Percent Solids 90 0.10 °A) Moisture Percent Moisture 9.7 0.10 °A) Moisture 660-31745-29 SB-6@1' Chromium 4.2 I 4.4 mg/Kg 6010B Lead 3.5 2.2 mg/Kg 60106 Percent Solids 75 0.10 % Moisture Percent Moisture 25 0.10 % Moisture 660-31745-30 SB-6@2' Arsenic 1.2 I 1.8 mg/Kg 6010B Chromium 5.6 3.7 mg/Kg 6010B Lead 4.4 1.8 mg/Kg 6010B Percent Solids 91 0.10 % Moisture Percent Moisture 9.3 0.10 % Moisture 660-31745-31 SB-6@3' Chromium 5.0 3.6 mg/Kg 60108 Lead 3.6 1.8 mg/Kg 6010B Percent Solids 94 0.10 % Moisture Percent Moisture 6.3 0.10 % Moisture 660-31745-32 SB-6@4' Arsenic 1.4 I 2.0 mg/Kg 6010B Chromium 12 4.1 mg/Kg 6010E Lead 6.2 2.0 mg/Kg 6010B Percent Solids 82 0.10 % Moisture Percent Moisture 18 0.10 % Moisture TestAmerica Tampa Page 8 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-33 SB-7@1' Arsenic 1.2 I 1.8 mg/Kg 6010B Chromium 4.7 3.5 mg/Kg 6010B Lead 3.6 1.8 mg/Kg 6010B Percent Solids 95 0.10 % Moisture Percent Moisture 5.5 0.10 % Moisture 660-31745-34 SB-7@2' Chromium 5.4 3.5 mg/Kg 6010E Lead 4.2 1.8 mg/Kg 6010B Percent Solids 95 0.10 % Moisture Percent Moisture 4.9 0.10 % Moisture 660-31745-35 SB-7@3' Chromium 5.0 3.6 mg/Kg 6010B Lead 3.2 1.8 mg/Kg 6010B Percent Solids 92 0.10 % Moisture Percent Moisture 7.8 0.10 % Moisture 660-31745-36 SB-7@4' Chromium 4.7 4.1 mg/Kg 6010B Lead 2.9 2.1 mg/Kg 6010B Percent Solids 81 0.10 % Moisture Percent Moisture 19 0.10 % Moisture 660-31745-37 SB-8@1' Chromium 4.1 I 4.7 mg/Kg 6010B Lead 4.5 2.3 mg/Kg 6010B Percent Solids 71 0.10 % Moisture Percent Moisture 29 0.10 °A) Moisture 660-31745-38 SB-8@2' Chromium 3.6 I 4.6 mg/Kg 6010B Lead 3.0 2.3 mg/Kg 6010E Percent Solids 73 0.10 % Moisture Percent Moisture 27 0.10 % Moisture TestAmerica Tampa Page 9 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-39 SB-8@3' Chromium 4.7 3.8 mg/Kg 6010B Lead 4.2 1.9 mg/Kg 6010B Percent Solids 88 0.10 % Moisture Percent Moisture 12 0.10 % Moisture 660-31745-40 SB-8@4' Chromium 2.9 I 4.4 mg/Kg 6010B Lead 2.4 2.2 mg/Kg 6010E Percent Solids 75 0.10 % Moisture Percent Moisture 25 0.10 % Moisture 660-31745-41 SB-9@1' Chromium 5.8 4.5 mg/Kg 60106 Lead 7.1 2.2 mg/Kg 6010B Percent Solids 75 0.10 % Moisture Percent Moisture 25 0.10 % Moisture 660-31745-42 SB-9@2' Chromium 6.1 4.1 mg/Kg 6010B Lead 7.4 2.1 mg/Kg 6010B Percent Solids 81 0.10 % Moisture Percent Moisture 19 0.10 % Moisture 660-31745-43 SB-9@3' Chromium 4.9 4.4 mg/Kg 6010B Lead 4.9 2.2 mg/Kg 6010B Percent Solids 75 0.10 % Moisture Percent Moisture 25 0.10 % Moisture 660-31745-44 SB-9@4' Chromium 2.8 I 4.4 mg/Kg 6010B Lead 2.2 2.2 mg/Kg 6010B Percent Solids 76 0.10 % Moisture Percent Moisture 24 0.10 % Moisture TestAmerica Tampa Page 10 of 166 10/13/2009 EXECUTIVE SUMMARY - Detections Client: ESciences, Inc. Job Number: 660-31745-1 Lab Sample ID Client Sample ID Reporting Analyte Result/Qualifier Limit Units Method 660-31745-45 SB-10@1' Chromium 3.4 I 4.5 mg/Kg 6010B Lead 3.5 2.2 mg/Kg 6010B Percent Solids 74 0.10 % Moisture Percent Moisture 26 0.10 % Moisture 660-31745-46 SB-10@2' Chromium 3.2 I 4.4 mg/Kg 6010B Lead 2.7 2.2 mg/Kg 60108 Percent Solids 76 0.10 % Moisture Percent Moisture 24 0.10 % Moisture 660-31745-47 S8-10@3' Chromium 2.7 I 4.3 mg/Kg 6010B Lead 2.5 2.1 mg/Kg 6010B Percent Solids 78 0.10 % Moisture Percent Moisture 22 0.10 % Moisture 660-31745-48 SB-10@4' Chromium 2.7 I 4.3 mg/Kg 6010B Lead 2.3 2.1 mg/Kg 6010B Percent Solids 78 0.10 % Moisture Percent Moisture 22 0.10 % Moisture TestAmerica Tampa Page 11 of 166 10/13/2009 METHOD SUMMARY Client: ESciences, Inc. Job Number: 660-31745-1 Description Lab Location Method Preparation Method Matrix Solid Metals(ICP) TAL TAM SW846 6010B Preparation, Metals TAL TAM SW846 3050B Percent Moisture TAL TAM EPA Moisture Matrix Water Volatile Organic Compounds(GC/MS) TAL TAM SW846 8260B Purge and Trap TAL TAM SW846 5030B Semivolatile Compounds by Gas Chromatography/Mass TAL TAM SW846 8270C Spectrometry(GC/MS) Liquid-Liquid Extraction(Continuous) TAL TAM SW846 3520C Metals(ICP) TAL TAM SW846 6010B Preparation, Total Recoverable or Dissolved Metals TAL TAM SW846 3005A Mercury(CVAA) TAL TAM SW846 7470A Preparation, Mercury TAL TAM SW846 7470A Nitrogen,Ammonia TAL TAM MCAWW 350.1 Nitrogen, Nitrate-Nitrite TAL TAM MCAWW 353.2 Lab References: TAL TAM =TestAmerica Tampa Method References: EPA= US Environmental Protection Agency MCAWW="Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020. March 1983 And Subsequent Revisions. SW846="Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 12 of 166 10/13/2009 METHOD / ANALYST SUMMARY Client: ESciences, Inc. Job Number: 660-31745-1 Method Analyst Analyst ID SW846 8260B Perrin, Todd TP SW846 8270C Subar, Neal NS SW846 6010B Fox, Greg GF SW846 7470A Canales, Richard RC MCAWW 350.1 Mathew, Pinky PM MCAWW 353.2 Steward, Tiffany TS EPA Moisture McNulty, Carol CM EPA Moisture Volz. Charles CV 1 TestAmerica Tampa Page 13 of 166 10/13/2009 SAMPLE SUMMARY Client: ESciences, Inc. Job Number: 660-31745-1 Date/Time Date/Time Lab Sample ID Client Sample ID Client Matrix Sampled Received 660-31745-1 TW-05 Water 09/21/2009 0945 09/23/2009 0830 660-31745-2 TW-04 Water 09/21/2009 1040 09/23/2009 0830 660-31745-3 TW-03 Water 09/21/2009 1150 09/23/2009 0830 660-31745-4 TW-06 Water 09/21/2009 1248 09/23/2009 0830 660-31745-5 MW-2s Water 09/21/2009 1351 09/23/2009 0830 660-31745-6 MW-3s Water 09/21/2009 1443 09/23/2009 0830 660-31745-7 MW-5s Water 09/21/2009 1540 09/23/2009 0830 660-31745-8 MW-1s Water 09/22/2009 1000 09/23/2009 0830 660-31745-9 SB-1@1' Solid 09/22/2009 1106 09/23/2009 0830 660-31745-10 SB-1@2' Solid 09/22/2009 1106 09/23/2009 0830 660-31745-11 SB-1 @3' Solid 09/22/2009 1106 09/23/2009 0830 660-31745-12 SB-1 @4' Solid 09/22/2009 1106 09/23/2009 0830 660-31745-13 SB-2@1' Solid 09/22/2009 1125 09/23/2009 0830 660-31745-14 SB-2@2' Solid 09/22/2009 1125 09/23/2009 0830 660-31745-15 SB-2@3' Solid 09/22/2009 1125 09/23/2009 0830 660-31745-16 SB-2@4' Solid 09/22/2009 1125 09/23/2009 0830 660-31745-17 SB-3@1 Solid 09/22/2009 1140 09/23/2009 0830 660-31745-18 SB-3@2' Solid 09/22/2009 1140 09/23/2009 0830 660-31745-19 SB-3@3' Solid 09/22/2009 1140 09/23/2009 0830 660-31745-20 SB-3@4' Solid 09/22/2009 1140 09/23/2009 0830 660-31745-21 SB-4@1' Solid 09/22/2009 1155 09/23/2009 0830 660-31745-22 SB-4@2' Solid 09/22/2009 1155 09/23/2009 0830 660-31745-23 SB-4@3' Solid 09/22/2009 1155 09/23/2009 0830 660-31745-24 SB-4@4' Solid 09/22/2009 1155 09/23/2009 0830 660-31745-25 SB-5@1' Solid 09/22/2009 1205 09/23/2009 0830 660-31745-26 SB-5@2' Solid 09/22/2009 1205 09/23/2009 0830 660-31745-27 SB-5@3' Solid 09/22/2009 1205 09/23/2009 0830 660-31745-28 SB-5@4' Solid 09/22/2009 1205 09/23/2009 0830 660-31745-29 SB-6@1' Solid 09/22/2009 1220 09/23/2009 0830 660-31745-30 SB-6@2' Solid 09/22/2009 1220 09/23/2009 0830 660-31745-31 SB-6@3' Solid 09/22/2009 1220 09/23/2009 0830 660-31745-32 SB-6@4' Solid 09/22/2009 1220 09/23/2009 0830 660-31745-33 SB-7@1' Solid 09/22/2009 1300 09/23/2009 0830 660-31745-34 SB-7@2' Solid 09/22/2009 1300 09/23/2009 0830 660-31745-35 SB-7@3' Solid 09/22/2009 1300 09/23/2009 0830 660-31745-36 SB-7@4' Solid 09/22/2009 1300 09/23/2009 0830 ' 660-31745-37 SB-8@1' Solid 09/22/2009 1400 09/23/2009 0830 660-31745-38 SB-8@2' Solid 09/22/2009 1400 09/23/2009 0830 660-31745-39 SB-8@3' Solid 09/22/2009 1400 09/23/2009 0830 660-31745-40 SB-8@4' Solid 09/22/2009 1400 09/23/2009 0830 660-31745-41 SB-9@1' Solid 09/22/2009 1420 09/23/2009 0830 660-31745-42 SB-9@2' Solid 09/22/2009 1420 09/23/2009 0830 660-31745-43 SB-9@3' Solid 09/22/2009 1420 09/23/2009 0830 660-31745-44 SB-9@4' Solid 09/22/2009 1420 09/23/2009 0830 660-31745-45 SB-10@1' Solid 09/22/2009 1435 09/23/2009 0830 660-31745-46 SB-10@2' Solid 09/22/2009 1435 09/23/2009 0830 TestAmerica Tampa Page 14 of 166 10/13/2009 SAMPLE SUMMARY Client: ESciences, Inc. Job Number: 660-31745-1 Date/Time Date/Time Lab Sample ID Client Sample ID Client Matrix Sampled Received 660-31745-47 SB-10@3' Solid 09/22/2009 1435 09/23/2009 0830 660-31745-48 SB-10@4' Solid 09/22/2009 1435 09/23/2009 0830 660-31745-49 Trip Blank Water 09/21/2009 0000 09/23/2009 0830 TestAmerica Tampa Page 15 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-05 Lab Sample ID: 660-31745-1 Date Sampled: 09/21/2009 0945 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 82606 Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 50306 Lab File ID: 1H12622.D Dilution: 1.0 Initial WeightNolume: 5 mL Date Analyzed: 09/26/2009 1725 Final Weight/Volume: 5 mL Date Prepared: 09/26/2009 1725 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 104 70-130 Dibromofluoromethane 106 70-130 Toluene-d8(Surr) 101 70-130 TestAmerica Tampa Page 16 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-04 Lab Sample ID: 660-31745-2 Date Sampled: 09/21/2009 1040 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 82606 Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1HI2623.D Dilution: 1.0 Initial WeightNolume: 5 mL Date Analyzed: 09/26/2009 1747 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1747 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 5.4 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 14 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 103 70-130 Dibromofluoromethane 110 70-130 Toluene-d8(Surr) 96 70-130 TestAmerica Tampa Page 17 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-03 Lab Sample ID: 660-31745-3 Date Sampled: 09/21/2009 1150 Client Matrix: Water Date Received: 09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1HI2624.D Dilution: 1.0 Initial Weight/Volume: 5 mL Date Analyzed: 09/26/2009 1808 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1808 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 2.2 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 7.2 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 12 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 8.8 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 14 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 101 70-130 Dibromofluoromethane 99 70-130 Toluene-d8(Surr) 85 70-130 TestAmerica Tampa Page 18 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-06 Lab Sample ID: 660-31745-4 Date Sampled: 09/21/2009 1248 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1H12625.D Dilution: 1.0 Initial WeightNolume: 5 mL Date Analyzed: 09/26/2009 1830 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1830 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 4.2 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 104 70-130 Dibromofluoromethane 111 70-130 Toluene-d8(Surr) 82 70-130 TestAmericaTampa Page 19 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-2s Lab Sample ID: 660-31745-5 Date Sampled: 09/21/2009 1351 Client Matrix: Water Date Received: 09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1H12626.D Dilution: 1.0 Initial WeighWolume: 5 mL Date Analyzed: 09/26/2009 1851 Final WeighWolume: 5 mL Date Prepared: 09/26/2009 1851 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 104 70-130 Dibromofluoromethane 99 70-130 Toluene-d8(Surr) 88 70-130 TestAmerica Tampa Page 20 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-3s Lab Sample ID: 660-31745-6 Date Sampled: 09/21/2009 1443 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1H12627.D Dilution: 1.0 Initial Weight/Volume: 5 mL Date Analyzed: 09/26/2009 1913 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1913 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 104 70- 130 Dibromofluoromethane 107 70- 130 Toluene-d8(Surr) 76 70-130 TestAmerica Tampa Page 21 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-5s Lab Sample ID: 660-31745-7 Date Sampled: 09/21/2009 1540 Client Matrix: Water Date Received: 09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1HI2628.D Dilution: 1.0 Initial WeighWolume: 5 mL Date Analyzed: 09/26/2009 1934 Final WeighWolume: 5 mL Date Prepared: 09/26/2009 1934 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 , Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 I Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 102 70-130 Dibromofluoromethane 112 70-130 Toluene-d8(Surr) 101 70- 130 TestAmerica Tampa Page 22 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-1s Lab Sample ID: 660-31745-8 Date Sampled: 09/22/2009 1000 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 8260B Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1H12629.D Dilution: 1.0 Initial Weight/Volume: 5 mL Date Analyzed: 09/26/2009 1956 Final Weight/Volume: 5 mL Date Prepared: 09/26/2009 1956 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 104 70-130 Dibromofluoromethane 105 70-130 Toluene-d8(Surr) 92 70-130 I TestAmerica Tampa Page 23 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: Trip Blank Lab Sample ID: 660-31745-49 Date Sampled: 09/21/2009 0000 Client Matrix: Water Date Received:09/23/2009 0830 8260B Volatile Organic Compounds(GC/MS) Method: 82608 Analysis Batch:660-85350 Instrument ID: BVMH5973 Preparation: 5030B Lab File ID: 1H12631.D Dilution: 1.0 Initial Weight/Volume: 5 mL Date Analyzed: 09/26/2009 2039 Final WeighWolume: 5 mL Date Prepared: 09/26/2009 2039 Analyte Result(ug/L) Qualifier MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U J3 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Qualifier Acceptance Limits 4-Bromofluorobenzene 106 70-130 Dibromofluoromethane 110 70-130 Toluene-d8(Surr) 83 70- 130 I TestAmerica Tampa Page 24 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-05 Lab Sample ID: 660-31745-1 Date Sampled: 09/21/2009 0945 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1DI30005.D Dilution: 1.0 Initial WeightNolume: 910 mL Date Analyzed: 09/30/2009 1249 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.3 U 2.3 11 2,4-Dichlorophenol 2.0 U 2.0 11 2,4-Dimethylphenol 2.0 U 2.0 11 4,6-Dinitro-2-methylphenol 1.6 U 1.6 55 2,4-Dinitrophenol 6.8 U 6.8 55 2-Nitrophenol 1.3 U 1.3 11 4-Nitrophenol 6.8 U 6.8 55 4-Chloro-3-methylphenol 1.9 U 1.9 11 Pentachlorophenol 1.6 U 1.6 16 Phenol 2.6 U 2.6 4.4 2,4,6-Trichlorophenol 2.1 U 2.1 11 Acenaphthene 1.6 U 1.6 11 Acenaphthylene 2.0 U 2.0 11 Anthracene 1.1 U 1.1 11 Benzo[a]anthracene 1.8 U 1.8 11 Benzo[a]pyrene 1.1 U 1.1 4.4 Benzo[b]fluoranthene 1.8 U 1.8 11 Benzo[g,h,i]perylene 1.2 U 1.2 11 Benzo[k]fluoranthene 1.4 U 1.4 11 Bis(2-chloroethoxy)methane 2.2 U 2.2 11 Bis(2-chloroethyl)ether 2.9 U 2.9 11 Bis(2-ethylhexyl)phthalate 1.4 U 1.4 6.6 4-Bromophenyl phenyl ether 1.9 U 1.9 11 Butyl benzyl phthalate 1.3 U 1.3 11 2-Chloronaphthalene 1.8 U 1.8 11 4-Chlorophenyl phenyl ether 2.0 U 2.0 11 Chrysene 1.3 U 1.3 11 Dibenz(a,h)anthracene 1.1 U 1.1 11 1,2-Dichlorobenzene 1.2 U 1.2 11 1,3-Dichlorobenzene 1.2 U 1.2 11 1,4-Dichlorobenzene 1.3 U 1.3 11 3,3'-Dichlorobenzidine 1.8 U J3 1.8 22 Diethyl phthalate 2.7 U 2.7 11 Dimethyl phthalate 2.7 U 2.7 11 Di-n-butyl phthalate 2.7 U 2.7 11 2,4-Dinitrotoluene 1.0 U 1.0 11 2,6-Dinitrotoluene 0.79 U 0.79 11 Di-n-octyl phthalate 2.7 U 2.7 11 1,2-Diphenylhydrazine 2.3 U 2.3 11 Fluoranthene 1.3 U 1.3 11 Hexachlorobenzene 1.9 U 1.9 4.4 Hexachlorobutadiene 1.1 U 1.1 11 Hexachlorocyclopentadiene 1.3 U 1.3 11 Hexachloroethane 0.93 U 0.93 11 Indeno[1,2,3-cd]pyrene 1.3 U 1.3 11 Isophorone 1.5 U 1.5 11 TestAmerica Tampa Page 25 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-05 Lab Sample ID: 660-31745-1 Date Sampled: 09/21/2009 0945 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch: 660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1DI30005.D Dilution: 1.0 Initial WeighWolume: 910 mL Date Analyzed: 09/30/2009 1249 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.4 U 1.4 11 Nitrobenzene 2.1 U 2.1 11 N-Nitrosodimethylamine 2.6 U 2.6 11 N-Nitrosodi-n-propylamine 2.1 U 2.1 11 N-Nitrosodiphenylamine 1.8 U 1.8 11 Phenanthrene 1.4 U 1.4 11 Pyrene 1.3 U 1.3 11 1,2,4-Trichlorobenzene 1.3 U 1.3 11 2-Methylnaphthalene 1.8 U 1.8 11 1-Methylnaphthalene 1.4 U 1.4 11 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 69 29-143 2-Fluorobiphenyl 45 36-124 2-Fluorophenol 39 29-121 Nitrobenzene-d5 47 34-130 Phenol-d5 32 25-128 Terphenyl-d14 72 14-148 TestAmerica Tampa Page 26 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-04 Lab Sample ID: 660-31745-2 Date Sampled: 09/21/2009 1040 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1CI25009.D Dilution: 1.0 Initial WeighWolume: 1050 mL Date Analyzed: 09/25/2009 2057 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U 2.0 9.5 2,4-Dichlorophenol 1.7 U 1.7 9.5 2,4-Dimethylphenol 1.7 U 1.7 9.5 4,6-Dinitro-2-methylphenol 1.4 U 1.4 48 2,4-Dinitrophenol 5.9 U 5.9 48 2-Nitrophenol 1.1 U 1.1 9.5 4-Nitrophenol 5.9 U 5.9 48 4-Chloro-3-methylphenol 1.6 U 1.6 9.5 Pentachlorophenol 1.4 U 1.4 14 Phenol 2.3 U 2.3 3.8 2,4,6-Trichlorophenol 1.8 U 1.8 9.5 Acenaphthene 1.4 U 1.4 9.5 Acenaphthylene 1.7 U 1.7 9.5 Anthracene 0.95 U 0.95 9.5 Benzo[a]anthracene 1.5 U 1.5 9.5 Benzo[a]pyrene 0.94 U 0.94 3.8 Benzo[b]fluoranthene 1.5 U 1.5 9.5 Benzo[g,h,i]perylene 1.0 U 1.0 9.5 Benzo[k]fluoranthene 1.2 U 1.2 9.5 Bis(2-chloroethoxy)methane 1.9 U 1.9 9.5 Bis(2-chloroethyl)ether 2.5 U 2.5 9.5 Bis(2-ethylhexyl)phthalate 1.2 U 1.2 5.7 4-Bromophenyl phenyl ether 1.6 U 1.6 9.5 Butyl benzyl phthalate 1.1 U 1.1 9.5 2-Chloronaphthalene 1.5 U 1.5 9.5 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.5 Chrysene 1.1 U 1.1 9.5 Dibenz(a,h)anthracene 0.95 U 0.95 9.5 1,2-Dichlorobenzene 1.0 U 1.0 9.5 1,3-Dichlorobenzene 1.0 U 1.0 9.5 1,4-Dichlorobenzene 1.1 U 1.1 9.5 3,3'-Dichlorobenzidine 1.5 U J3 1.5 19 Diethyl phthalate 2.4 U 2.4 9.5 1 Dimethyl phthalate 2.4 U 2.4 9.5 Di-n-butyl phthalate 2.4 U 2.4 9.5 2,4-Dinitrotoluene 0.87 U 0.87 9.5 2,6-Dinitrotoluene 0.69 U 0.69 9.5 Di-n-octyl phthalate 2.4 U 2.4 9.5 1,2-Diphenylhydrazine 2.0 U 2.0 9.5 Fluoranthene 1.1 U 1.1 9.5 Hexachlorobenzene 1.6 U 1.6 3.8 Hexachlorobutadiene 0.95 U 0.95 9.5 Hexachlorocyclopentadiene 1.1 U 1.1 9.5 i Hexachloroethane 0.81 U 0.81 9.5 Indeno[1,2,3-cd]pyrene 1.1 U 1.1 9.5 Isophorone 1.3 U 1.3 9.5 TestAmerica Tampa Page 27 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-04 Lab Sample ID: 660-31745-2 Date Sampled: 09/21/2009 1040 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch: 660-85123 Lab File ID: 1C125009.D Dilution: 1.0 Initial Weight/Volume: 1050 mL Date Analyzed: 09/25/2009 2057 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.2 U 1.2 9.5 Nitrobenzene 1.8 U 1.8 9.5 N-Nitrosodimethylamine 2.3 U 2.3 9.5 N-Nitrosodi-n-propylamine 1.8 U 1.8 9.5 N-Nitrosodiphenylamine 1.5 U 1.5 9.5 Phenanthrene 1.2 U 1.2 9.5 Pyrene 1.1 U 1.1 9.5 1,2,4-Trichlorobenzene 1.1 U 1.1 9.5 2-Methylnaphthalene 1.5 U 1.5 9.5 1-Methylnaphthalene 1.2 U 1.2 9.5 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 67 29-143 2-Fluorobiphenyl 50 36-124 2-Fluorophenol 55 29-121 Nitrobenzene-d5 51 34-130 Phenol-d5 55 25-128 Terphenyl-d14 23 14-148 TestAmerica Tampa Page 28 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-03 Lab Sample ID: 660-31745-3 Date Sampled: 09/21/2009 1150 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch: 660-85123 Lab File ID: 1DI30007.D Dilution: 1.0 Initial WeighWolume: 1050 mL Date Analyzed: 09/30/2009 1344 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U 2.0 9.5 2,4-Dichlorophenol 1.7 U 1.7 9.5 2,4-Dimethylphenol 1.7 U 1.7 9.5 4,6-Dinitro-2-methylphenol 1.4 U 1.4 48 2,4-Dinitrophenol 5.9 U 5.9 48 2-Nitrophenol 1.1 U 1.1 9.5 4-Nitrophenol 5.9 U 5.9 48 4-Chloro-3-methylphenol 1.6 U 1.6 9.5 Pentachlorophenol 1.4 U 1.4 14 Phenol 3.0 I 2.3 3.8 2,4,6-Trichlorophenol 1.8 U 1.8 9.5 Acenaphthene 1.4 U 1.4 9.5 Acenaphthylene 1.7 U 1.7 9.5 Anthracene 0.95 U 0.95 9.5 Benzo[a]anthracene 1.5 U 1.5 9.5 Benzo[a]pyrene 0.94 U 0.94 3.8 Benzo[b]fluoranthene 1.5 U 1.5 9.5 Benzo[g,h,i]perylene 1.0 U 1.0 9.5 Benzo[k]fluoranthene 1.2 U 1.2 9.5 Bis(2-chloroethoxy)methane 1.9 U 1.9 9.5 Bis(2-chloroethyl)ether 2.5 U 2.5 9.5 Bis(2-ethylhexyl)phthalate 1.2 U 1.2 5.7 4-Bromophenyl phenyl ether 1.6 U 1.6 9.5 Butyl benzyl phthalate 1.1 U 1.1 9.5 2-Chloronaphthalene 1.5 U 1.5 9.5 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.5 Chrysene 1.1 U 1.1 9.5 Dibenz(a,h)anthracene 0.95 U 0.95 9.5 1,2-Dichlorobenzene 1.0 U 1.0 9.5 1,3-Dichlorobenzene 1.0 U 1.0 9.5 1,4-Dichlorobenzene 1.1 U 1.1 9.5 3,3'-Dichlorobenzidine 1.5 U J3 1.5 19 Diethyl phthalate 2.4 U 2.4 9.5 Dimethyl phthalate 2.4 U 2.4 9.5 Di-n-butyl phthalate 2.4 U 2.4 9.5 2,4-Dinitrotoluene 0.87 U 0.87 9.5 2,6-Dinitrotoluene 0.69 U 0.69 9.5 Di-n-octyl phthalate 2.4 U 2.4 9.5 1,2-Diphenylhydrazine 2.0 U 2.0 9.5 Fluoranthene 1.1 U 1.1 9.5 Hexachlorobenzene 1.6 U 1.6 3.8 Hexachlorobutadiene 0.95 U 0.95 9.5 Hexachlorocyclopentadiene 1.1 U 1.1 9.5 Hexachloroethane 0.81 U 0.81 9.5 Indeno[1,2,3-cdlpyrene 1.1 U 1.1 9.5 Isophorone 1.3 U 1.3 9.5 TestAmerica Tampa Page 29 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-03 Lab Sample ID: 660-31745-3 Date Sampled: 09/21/2009 1150 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1DI30007.D Dilution: 1.0 Initial Weight/Volume: 1050 mL Date Analyzed: 09/30/2009 1344 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.2 U 1.2 9.5 Nitrobenzene 1.8 U 1.8 9.5 N-Nitrosodimethylamine 2.3 U 2.3 9.5 N-Nitrosodi-n-propylamine 1.8 U 1.8 9.5 N-Nitrosodiphenylamine 1.5 U 1.5 9.5 Phenanthrene 1.2 U 1.2 9.5 Pyrene 1.1 U 1.1 9.5 1,2,4-Trichlorobenzene 1.1 U 1.1 9.5 2-Methylnaphthalene 1.5 U 1.5 9.5 1-Methylnaphthalene 1.2 U 1.2 9.5 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 91 29-143 2-Fluorobiphenyl 45 36-124 2-Fluorophenol 40 29-121 Nitrobenzene-d5 48 34-130 Phenol-d5 37 25-128 Terphenyl-d14 31 14-148 TestAmerica Tampa Page 30 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-06 Lab Sample ID: 660-31745-4 Date Sampled: 09/21/2009 1248 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1DI30006.D Dilution: 1.0 Initial Weight/Volume: 1020 mL Date Analyzed: 09/30/2009 1316 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL ' Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.1 U 2.1 9.8 2,4-Dichlorophenol 1.8 U 1.8 9.8 2,4-Dimethylphenol 1.8 U 1.8 9.8 4,6-Dinitro-2-methylphenol 1.5 U 1.5 49 2,4-Dinitrophenol 6.1 U 6.1 49 2-Nitrophenol 1.2 U 1.2 9.8 4-Nitrophenol 6.1 U 6.1 49 4-Chloro-3-methylphenol 1.7 U 1.7 9.8 Pentachlorophenol 1.5 U 1.5 15 Phenol 2.4 U 2.4 3.9 2,4,6-Trichlorophenol 1.9 U 1.9 9.8 Acenaphthene 1.5 U 1.5 9.8 Acenaphthylene 1.8 U 1.8 9.8 Anthracene 0.98 U 0.98 9.8 Benzo[a]anthracene 1.6 U 1.6 9.8 Benzo[a]pyrene 0.97 U 0.97 3.9 Benzo[b]fluoranthene 1.6 U 1.6 9.8 Benzo[g,h,i]perylene 1.1 U 1.1 9.8 Benzo[k]fluoranthene 1.3 U 1.3 9.8 Bis(2-chloroethoxy)methane 2.0 U 2.0 9.8 Bis(2-chloroethyl)ether 2.5 U 2.5 9.8 Bis(2-ethylhexyl)phthalate 1.3 U 1.3 5.9 4-Bromophenyl phenyl ether 1.7 U 1.7 9.8 Butyl benzyl phthalate 1.2 U 1.2 9.8 2-Chloronaphthalene 1.6 U 1.6 9.8 4-Chlorophenyl phenyl ether 1.8 U 1.8 9.8 Chrysene 1.2 U 1.2 9.8 Dibenz(a,h)anthracene 0.98 U 0.98 9.8 1,2-Dichlorobenzene 1.1 U 1.1 9.8 1,3-Dichlorobenzene 1.1 U 1.1 9.8 1,4-Dichlorobenzene 1.2 U 1.2 9.8 3,3'-Dichlorobenzidine 1.6 U J3 1.6 20 Diethyl phthalate 2.5 U 2.5 9.8 Dimethyl phthalate 2.5 U 2.5 9.8 Di-n-butyl phthalate 2.5 U 2.5 9.8 2,4-Dinitrotoluene 0.89 U 0.89 9.8 2,6-Dinitrotoluene 0.71 U 0.71 9.8 Di-n-octyl phthalate 2.5 U 2.5 9.8 1,2-Diphenylhydrazine 2.1 U 2.1 9.8 Fluoranthene 1.2 U 1.2 9.8 Hexachlorobenzene 1.7 U 1.7 3.9 Hexachlorobutadiene 0.98 U 0.98 9.8 Hexachlorocyclopentadiene 1.2 U 1.2 9.8 Hexachloroethane 0.83 U 0.83 9.8 Indeno[1,2,3-cd]pyrene 1.2 U 1.2 9.8 Isophorone 1.4 U 1.4 9.8 TestAmerica Tampa Page 31 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-06 Lab Sample ID: 660-31745-4 Date Sampled: 09/21/2009 1248 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch: 660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1DI30006.D Dilution: 1.0 Initial WeightNolume: 1020 mL Date Analyzed: 09/30/2009 1316 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.3 U 1.3 9.8 Nitrobenzene 1.9 U 1.9 9.8 N-Nitrosodimethylamine 2.4 U 2.4 9.8 N-Nitrosodi-n-propylamine 1.9 U 1.9 9.8 N-Nitrosodiphenylamine 1.6 U 1.6 9.8 Phenanthrene 1.3 U 1.3 9.8 Pyrene 1.2 U 1.2 9.8 1,2,4-Trichlorobenzene 1.2 U 1.2 9.8 2-Methylnaphthalene 1.6 U 1.6 9.8 1-Methylnaphthalene 1.3 U 1.3 9.8 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 80 29-143 2-Fluorobiphenyl 45 36-124 2-Fluorophenol 39 29-121 Nitrobenzene-d5 42 34-130 Phenol-d5 37 25-128 Terphenyl-d14 36 14-148 TestAmericaTampa Page 32 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-2s Lab Sample ID: 660-31745-5 Date Sampled: 09/21/2009 1351 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1CI25014.D Dilution: 1.0 Initial Weight/Volume: 1030 mL Date Analyzed: 09/25/2009 2235 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U 2.0 9.7 2,4-Dichlorophenol 1.7 U 1.7 9.7 2,4-Dimethylphenol 1.7 U 1.7 9.7 4,6-Dinitro-2-methylphenol 1.5 U 1.5 49 2,4-Dinitrophenol 6.0 U 6.0 49 2-Nitrophenol 1.2 U 1.2 9.7 4-Nitrophenol 6.0 U 6.0 49 4-Chloro-3-methylphenol 1.7 U 1.7 9.7 Pentachlorophenol 1.5 U 1.5 15 Phenol 2.3 U 2.3 3.9 2,4,6-Trichlorophenol 1.8 U 1.8 9.7 Acenaphthene 1.5 U 1.5 9.7 Acenaphthylene 1.7 U 1.7 9.7 Anthracene 0.97 U 0.97 9.7 Benzo[a]anthracene 1.6 U 1.6 9.7 Benzo[a]pyrene 0.96 U 0.96 3.9 Benzo[b]fluoranthene 1.6 U 1.6 9.7 Benzo[g,h,i]perylene 1.1 U 1.1 9.7 Benzo[k]fluoranthene 1.3 U 1.3 9.7 Bis(2-chloroethoxy)methane 1.9 U 1.9 9.7 Bis(2-chloroethyl)ether 2.5 U 2.5 9.7 Bis(2-ethylhexyl)phthalate 1.3 U 1.3 5.8 4-Bromophenyl phenyl ether 1.7 U 1.7 9.7 Butyl benzyl phthalate 1.2 U 1.2 9.7 2-Chloronaphthalene 1.6 U 1.6 9.7 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.7 Chrysene 1.2 U 1.2 9.7 Dibenz(a,h)anthracene 0.97 U 0.97 9.7 1,2-Dichlorobenzene 1.1 U 1.1 9.7 1,3-Dichlorobenzene 1.1 U 1.1 9.7 1,4-Dichlorobenzene 1.2 U 1.2 9.7 3,3'-Dichlorobenzidine 1.6 U J3 1.6 19 Diethyl phthalate 2.4 U 2.4 9.7 Dimethyl phthalate 2.4 U 2.4 9.7 Di-n-butyl phthalate 2.4 U 2.4 9.7 2,4-Dinitrotoluene 0.88 U 0.88 9.7 2,6-Dinitrotoluene 0.70 U 0.70 9.7 Di-n-octyl phthalate 2.4 U 2.4 9.7 1,2-Diphenylhydrazine 2.0 U 2.0 9.7 Fluoranthene 1.2 U 1.2 9.7 Hexachlorobenzene 1.7 U 1.7 3.9 Hexachlorobutadiene 0.97 U 0.97 9.7 Hexachlorocyclopentadiene 1.2 U 1.2 9.7 Hexachloroethane 0.83 U 0.83 9.7 Indeno[1,2,3-cd]pyrene 1.2 U 1.2 9.7 Isophorone 1.4 U 1.4 9.7 TestAmerica Tampa Page 33 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-2s Lab Sample ID: 660-31745-5 Date Sampled: 09/21/2009 1351 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch: 660-85123 Lab File ID: 1C125014.D Dilution: 1.0 Initial Weight/Volume: 1030 mL Date Analyzed: 09/25/2009 2235 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.3 U 1.3 9.7 Nitrobenzene 1.8 U 1.8 9.7 N-Nitrosodimethylamine 2.3 U 2.3 9.7 N-Nitrosodi-n-propylamine 1.8 U 1.8 9.7 N-Nitrosodiphenylamine 1.6 U 1.6 9.7 Phenanthrene 1.3 U 1.3 9.7 Pyrene 1.2 U 1.2 9.7 1,2,4-Trichlorobenzene 1.2 U 1.2 9.7 2-Methylnaphthalene 1.6 U 1.6 9.7 1-Methylnaphthalene 1.3 U 1.3 9.7 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 62 29-143 2-Fluorobiphenyl 41 36-124 2-Fluorophenol 42 29-121 Nitrobenzene-d5 45 34-130 Phenol-d5 37 25-128 Terphenyl-d14 67 14-148 i TestAmerica Tampa Page 34 of 166 10/3.3/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-3s Lab Sample ID: 660-31745-6 Date Sampled: 09/21/2009 1443 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1CI25015.D Dilution: 1.0 Initial WeighWolume: 1030 mL Date Analyzed: 09/25/2009 2254 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U 2.0 9.7 2,4-Dichlorophenol 1.7 U 1.7 9.7 2,4-Dimethylphenol 1.7 U 1.7 9.7 4,6-Dinitro-2-methylphenol 1.5 U 1.5 49 2,4-Dinitrophenol 6.0 U 6.0 49 2-Nitrophenol 1.2 U 1.2 9.7 4-Nitrophenol 6.0 U 6.0 49 4-Chloro-3-methylphenol 1.7 U 1.7 9.7 Pentachlorophenol 1.5 U 1.5 15 Phenol 2.3 U 2.3 3.9 2,4,6-Trichlorophenol 1.8 U 1.8 9.7 Acenaphthene 1.5 U 1.5 9.7 Acenaphthylene 1.7 U 1.7 9.7 Anthracene 0.97 U 0.97 9.7 Benzo[a]anthracene 1.6 U 1.6 9.7 Benzo[a]pyrene 0.96 U 0.96 3.9 Benzo[b]fluoranthene 1.6 U 1.6 9.7 Benzo[g,h,i]perylene 1.1 U 1.1 9.7 Benzo[k]fluoranthene 1.3 U 1.3 9.7 Bis(2-chloroethoxy)methane 1.9 U 1.9 9.7 Bis(2-chloroethyl)ether 2.5 U 2.5 9.7 Bis(2-ethylhexyl)phthalate 1.3 U 1.3 5.8 4-Bromophenyl phenyl ether 1.7 U 1.7 9.7 Butyl benzyl phthalate 1.2 U 1.2 9.7 2-Chloronaphthalene 1.6 U 1.6 9.7 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.7 Chrysene 1.2 U 1.2 9.7 Dibenz(a,h)anthracene 0.97 U 0.97 9.7 1,2-Dichlorobenzene 1.1 U 1.1 9.7 1,3-Dichlorobenzene 1.1 U 1.1 9.7 1,4-Dichlorobenzene 1.2 U 1.2 9.7 3,3'-Dichlorobenzidine 1.6 U J3 1.6 19 Diethyl phthalate 2.4 U 2.4 9.7 Dimethyl phthalate 2.4 U 2.4 9.7 Di-n-butyl phthalate 2.4 U 2.4 9.7 2,4-Dinitrotoluene 0.88 U 0.88 9.7 2,6-Dinitrotoluene 0.70 U 0.70 9.7 Di-n-octyl phthalate 2.4 U 2.4 9.7 1,2-Diphenylhydrazine 2.0 U 2.0 9.7 Fluoranthene 1.2 U 1.2 9.7 Hexachlorobenzene 1.7 U 1.7 3.9 Hexachlorobutadiene 0.97 U 0.97 9.7 Hexachlorocyclopentadiene 1.2 U 1.2 9.7 Hexachloroethane 0.83 U 0.83 9.7 ndeno[1,2,3-cd]pyrene 1.2 U 1.2 9.7 Isophorone 1.4 U 1.4 9.7 TestAmerica Tampa Page 35 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-3s Lab Sample ID: 660-31745-6 Date Sampled: 09/21/2009 1443 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1C125015.D Dilution: 1.0 Initial Weight/Volume: 1030 mL Date Analyzed: 09/25/2009 2254 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.3 U 1.3 9.7 Nitrobenzene 1.8 U 1.8 9.7 N-Nitrosodimethylamine 2.3 U 2.3 9.7 N-Nitrosodi-n-propylamine 1.8 U 1.8 9.7 N-Nitrosodiphenylamine 1.6 U 1.6 9.7 Phenanthrene 1.3 U 1.3 9.7 Pyrene 1.2 U 1.2 9.7 1,2,4-Trichlorobenzene 1.2 U 1.2 9.7 2-Methylnaphthalene 1.6 U 1.6 9.7 1-Methylnaphthalene 1.3 U 1.3 9.7 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 73 29-143 2-Fluorobiphenyl 49 36-124 2-Fluorophenol 47 29-121 Nitrobenzene-d5 54 34-130 Phenol-d5 43 25-128 Terphenyl-d14 87 14- 148 TestAmerica Tampa Page 36 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-5s Lab Sample ID: 660-31745-7 Date Sampled: 09/21/2009 1540 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1C125016.D Dilution: 1.0 Initial WeighWolume: 1040 mL Date Analyzed: 09/25/2009 2314 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U 2.0 9.6 2,4-Dichlorophenol 1.7 U 1.7 9.6 2,4-Dimethylphenol 1.7 U 1.7 9.6 4,6-Dinitro-2-methylphenol 1.4 U 1.4 48 2,4-Dinitrophenol 6.0 U 6.0 48 2-Nitrophenol 1.2 U 1.2 9.6 4-Nitrophenol 6.0 U 6.0 48 4-Chloro-3-methylphenol 1.6 U 1.6 9.6 Pentachlorophenol 1.4 U 1.4 14 Phenol 2.3 U 2.3 3.8 2,4,6-Trichlorophenol 1.8 U 1.8 9.6 Acenaphthene 1.4 U 1.4 9.6 Acenaphthylene 1.7 U 1.7 9.6 Anthracene 0.96 U 0.96 9.6 Benzolalanthracene 1.5 U 1.5 9.6 Benzo[a]pyrene 0.95 U 0.95 3.8 Benzo[b]fluoranthene 1.5 U 1.5 9.6 Benzo[g,h,i]perylene 1.1 U 1.1 9.6 Benzo[k]fluoranthene 1.2 U 1.2 9.6 Bis(2-chloroethoxy)methane 1.9 U 1.9 9.6 Bis(2-chloroethyl)ether 2.5 U 2.5 9.6 Bis(2-ethylhexyl)phthalate 1.2 U 1.2 5.8 4-Bromophenyl phenyl ether 1.6 U 1.6 9.6 Butyl benzyl phthalate 1.2 U 1.2 9.6 2-Chloronaphthalene 1.5 U 1.5 9.6 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.6 Chrysene 1.2 U 1.2 9.6 Dibenz(a,h)anthracene 0.96 U 0.96 9.6 1,2-Dichlorobenzene 1.1 U 1.1 9.6 1,3-Dichlorobenzene 1.1 U 1.1 9.6 1,4-Dichlorobenzene 1.2 U 1.2 9.6 3,3'-Dichlorobenzidine 1.5 U J3 1.5 19 Diethyl phthalate 2.4 U 2.4 9.6 Dimethyl phthalate 2.4 U 2.4 9.6 Di-n-butyl phthalate 2.4 U 2.4 9.6 2,4-Dinitrotoluene 0.88 U 0.88 9.6 2,6-Dinitrotoluene 0.69 U 0.69 9.6 Di-n-octyl phthalate 2.4 U 2.4 9.6 1,2-Diphenylhydrazine 2.0 U 2.0 9.6 Fluoranthene 1.2 U 1.2 9.6 Hexachlorobenzene 1.6 U 1.6 3.8 Hexachlorobutadiene 0.96 U 0.96 9.6 Hexachlorocyclopentadiene 1.2 U 1.2 9.6 Hexachloroethane 0.82 U 0.82 9.6 Indeno[1,2,3-cd]pyrene 1.2 U 1.2 9.6 Isophorone 1.3 U 1.3 9.6 TestAmerica Tampa Page 37 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-5s Lab Sample ID: 660-31745-7 Date Sampled: 09/21/2009 1540 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch: 660-85123 Lab File ID: 1CI25016.D Dilution: 1.0 Initial Weight/Volume: 1040 mL Date Analyzed: 09/25/2009 2314 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.2 U 1.2 9.6 Nitrobenzene 1.8 U 1.8 9.6 N-Nitrosodimethylamine 2.3 U 2.3 9.6 N-Nitrosodi-n-propylamine 1.8 U 1.8 9.6 N-Nitrosodiphenylamine 1.5 U 1.5 9.6 Phenanthrene 1.2 U 1.2 9.6 Pyrene 1.2 U 1.2 9.6 1,2,4-Trichlorobenzene 1.2 U 1.2 9.6 2-Methylnaphthalene 1.5 U 1.5 9.6 1-Methylnaphthalene 1.2 U 1.2 9.6 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 69 29-143 2-Fluorobiphenyl 38 36-124 2-Fluorophenol 32 29-121 Nitrobenzene-d5 42 34-130 Phenol-d5 29 25-128 Terphenyl-d14 59 14-148 i TestAmerica Tampa Page 38 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-1s Lab Sample ID: 660-31745-8 Date Sampled: 09/22/2009 1000 Client Matrix: Water Date Received:09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch:660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch:660-85123 Lab File ID: 1CI25017.D Dilution: 1.0 Initial Weight/Volume: 1060 mL Date Analyzed: 09/25/2009 2334 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL 2-Chlorophenol 2.0 U J3 2.0 9.4 2,4-Dichlorophenol 1.7 U J3 1.7 9.4 2,4-Dimethylphenol 1.7 U J3 1.7 9.4 4,6-Dinitro-2-methylphenol 1.4 U 1.4 47 2,4-Dinitrophenol 5.8 U 5.8 47 2-Nitrophenol 1.1 U J3 1.1 9.4 ' 4-Nitrophenol 5.8 U 5.8 47 4-Chloro-3-methylphenol 1.6 U 1.6 9.4 Pentachlorophenol 1.4 U 1.4 14 Phenol 2.3 U 2.3 3.8 2,4,6-Trichlorophenol 1.8 U 1.8 9.4 Acenaphthene 1.4 U 1.4 9.4 Acenaphthylene 1.7 U 1.7 9.4 Anthracene 0.94 U 0.94 9.4 Benzo[a]anthracene 1.5 U 1.5 9.4 Benzo[a]pyrene 0.93 U 0.93 3.8 Benzo[b]fluoranthene 1.5 U 1.5 9.4 Benzo[g,h,i]perylene 1.0 U 1.0 9.4 Benzo[k]fluoranthene 1.2 U 1.2 9.4 Bis(2-chloroethoxy)methane 1.9 U J3 1.9 9.4 Bis(2-chloroethyl)ether 2.5 U J3 2.5 9.4 Bis(2-ethylhexyl)phthalate 1.2 U 1.2 5.7 4-Bromophenyl phenyl ether 1.6 U 1.6 9.4 Butyl benzyl phthalate 1.1 U 1.1 9.4 2-Chloronaphthalene 1.5 U J3 1.5 9.4 4-Chlorophenyl phenyl ether 1.7 U 1.7 9.4 Chrysene 1.1 U 1.1 9.4 Dibenz(a,h)anthracene 0.94 U 0.94 9.4 1,2-Dichlorobenzene 1.0 U J3 1.0 9.4 1,3-Dichlorobenzene 1.0 U J3 1.0 9.4 1,4-Dichlorobenzene 1.1 U J3 1.1 9.4 3,3'-Dichlorobenzidine 1.5 U J3 1.5 19 Diethyl phthalate 2.4 U 2.4 9.4 Dimethyl phthalate 2.4 U 2.4 9.4 Di-n-butyl phthalate 2.4 U 2.4 9.4 2,4-Dinitrotoluene 0.86 U 0.86 9.4 2,6-Dinitrotoluene 0.68 U 0.68 9.4 Di-n-octyl phthalate 2.4 U 2.4 9.4 1,2-Diphenylhydrazine 2.0 U 2.0 9.4 Fluoranthene 1.1 U 1.1 9.4 1 Hexachlorobenzene 1.6 U 1.6 3.8 Hexachlorobutadiene 0.94 U J3 0.94 9.4 Hexachlorocyclopentadiene 1.1 U 1.1 9.4 1 Hexachloroethane 0.80 U J3 0.80 9.4 Indeno[1,2,3-cd]pyrene 1.1 U 1.1 9.4 Isophorone 1.3 U J3 1.3 9.4 TestAmerica Tampa Page 39 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-1s Lab Sample ID: 660-31745-8 Date Sampled: 09/22/2009 1000 Client Matrix: Water Date Received: 09/23/2009 0830 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry(GC/MS) Method: 8270C Analysis Batch: 660-85385 Instrument ID: BSMC5973 Preparation: 3520C Prep Batch: 660-85123 Lab File ID: 1C125017 D Dilution: 1.0 Initial Weight/Volume: 1060 mL Date Analyzed: 09/25/2009 2334 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result(ug/L) Qualifier MDL PQL Naphthalene 1.2 U J3 1.2 9.4 Nitrobenzene 1.8 U J3 1.8 9.4 N-Nitrosodimethylamine 2.3 U 2.3 9.4 N-Nitrosodi-n-propylamine 1.8 U J3 1.8 9.4 N-Nitrosodiphenylamine 1.5 U 1.5 9.4 Phenanthrene 1.2 U 1.2 9.4 Pyrene 1.1 U 1.1 9.4 1,2,4-Trichlorobenzene 1.1 U J3 1.1 9.4 2-Methylnaphthalene 1.5 U J3 1.5 9.4 1-Methylnaphthalene 1.2 U J3 1.2 9.4 Surrogate %Rec Qualifier Acceptance Limits 2,4,6-Tribromophenol 54 29-143 2-Fluorobiphenyl 40 36- 124 2-Fluorophenol 36 29- 121 Nitrobenzene-d5 44 34- 130 Phenol-d5 30 25- 128 Terphenyl-d14 21 14- 148 TestAmerica Tampa Page 40 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-05 Lab Sample ID: 660-31745-1 Date Sampled: 09/21/2009 0945 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial Weight/Volume: 50 mL Date Analyzed: 09/29/2009 1201 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Antimony 0.0040 U 0.0040 0.020 Arsenic 0.0040 U 0.0040 0.010 Beryllium 0.00050 U 0.00050 0.0020 Cadmium 0.0010 U 0.0010 0.0040 Chromium 0.0020 U 0.0020 0.010 Copper 0.0029 U 0.0029 0.010 Lead 0.0020 U 0.0020 0.010 Nickel 0.0020 U 0.0020 0.0080 Selenium 0.0050 U 0.0050 0.020 Silver 0.0010 U 0.0010 0.0040 Thallium 0.0050 U 0.0050 0.020 Zinc 0.012 I 0.0050 0.020 7470A Mercury(CVAA) Method: 7470A Analysis Batch:660-85289 Instrument ID: PS20011 Preparation: 7470A Prep Batch:660-85254 Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 25 mL Date Analyzed: 09/28/2009 1440 Final WeightNolume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Result(mg/L) Qualifier MDL PQL Mercury 0.000072 U 0.000072 0.00020 TestAmerica Tampa Page 41 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-04 Lab Sample ID: 660-31745-2 Date Sampled: 09/21/2009 1040 Client Matrix: Water Date Received: 09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch: 660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeightNolume: 50 mL Date Analyzed: 09/29/2009 1225 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Antimony 0.0040 U 0.0040 0.020 Arsenic 0.0040 U 0.0040 0.010 Beryllium 0.00050 U 0.00050 0.0020 Cadmium 0.0010 U 0.0010 0.0040 Chromium 0.0027 I 0.0020 0.010 Copper 0.0029 U 0.0029 0.010 Lead 0.0020 U 0.0020 0.010 Nickel 0.0020 U 0.0020 0.0080 Selenium 0.0050 U 0.0050 0.020 Silver 0.0010 U 0.0010 0.0040 Thallium 0.0050 U 0.0050 0.020 Zinc 0.0086 I 0.0050 0.020 7470A Mercury(CVAA) Method: 7470A Analysis Batch:660-85289 Instrument ID: PS2001I Preparation: 7470A Prep Batch:660-85254 Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 25 mL Date Analyzed: 09/28/2009 1452 Final WeightNolume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Result(mg/L) Qualifier MDL PQL Mercury 0.000096 I 0.000072 0.00020 TestAmericaTampa Page 42 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-03 Lab Sample ID: 660-31745-3 Date Sampled: 09/21/2009 1150 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeightNolume: 50 mL Date Analyzed: 09/29/2009 1232 Final WeightNolume: 50 mL i Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Antimony 0.0043 I 0.0040 0.020 Arsenic 0.016 0.0040 0.010 Beryllium 0.00050 U 0.00050 0.0020 Cadmium 0.0010 U 0.0010 0.0040 Chromium 0.052 0.0020 0.010 Copper 0.011 0.0029 0.010 Lead 0.014 0.0020 0.010 Nickel 0.013 0.0020 0.0080 Selenium 0.0050 U 0.0050 0.020 Silver 0.0010 U 0.0010 0.0040 Thallium 0.0050 U 0.0050 0.020 Zinc 0.074 0.0050 0.020 7470A Mercury(CVAA) Method: 7470A Analysis Batch: 660-85289 Instrument ID: PS2001I Preparation: 7470A Prep Batch:660-85254 Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 25 mL Date Analyzed: 09/28/2009 1454 Final WeightNolume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Result(mg/L) Qualifier MDL PQL Mercury 0.00012 I 0.000072 0.00020 TestAmericaTampa Page 43 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: TW-06 Lab Sample ID: 660-31745-4 Date Sampled: 09/21/2009 1248 Client Matrix: Water Date Received: 09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9129A Dilution: 1.0 Initial WeighWolume: 50 mL Date Analyzed: 09/29/2009 1238 Final WeighWolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Antimony 0.0044 I 0.0040 0.020 Arsenic 0.0040 U 0.0040 0.010 Beryllium 0.00050 U 0.00050 0.0020 Cadmium 0.0010 U 0.0010 0.0040 Chromium 0.068 0.0020 0.010 Copper 0.030 0.0029 0.010 Lead 0.082 0.0020 0.010 Nickel 0.031 0.0020 0.0080 Selenium 0.0050 U 0.0050 0.020 Silver 0.0010 U 0.0010 0.0040 Thallium 0.0050 U 0.0050 0.020 Zinc 0.37 0.0050 0.020 7470A Mercury(CVAA) Method: 7470A Analysis Batch:660-85289 Instrument ID: PS20011 Preparation: 7470A Prep Batch:660-85254 Lab File ID: N/A Dilution: 1.0 Initial WeighWolume: 25 mL Date Analyzed: 09/28/2009 1457 Final Weight/Volume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Result(mg/L) Qualifier MDL PQL Mercury 0.00012 I 0.000072 0.00020 TestAmerica Tampa Page 44 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-2s Lab Sample ID: 660-31745-5 Date Sampled: 09/21/2009 1351 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeighWolume: 50 mL Date Analyzed: 09/29/2009 1256 Final WeighWolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Arsenic 0.0040 U 0.0040 0.010 Cadmium 0.0010 U 0.0010 0.0040 Lead 0.0020 U 0.0020 0.010 Chromium 0.0020 U 0.0020 0.010 Antimony 0.0040 U 0.0040 0.020 Beryllium 0.00050 U 0.00050 0.0020 Thallium 0.0050 U 0.0050 0.020 Nickel 0.0020 U 0.0020 0.0080 Silver 0.0010 U 0.0010 0.0040 Copper 0.0029 U 0.0029 0.010 Zinc 0.0050 U 0.0050 0.020 Selenium 0.0050 U 0.0050 0.020 I TestAmericaTampa Page 45 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-3s Lab Sample ID: 660-31745-6 Date Sampled: 09/21/2009 1443 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeightNolume: 50 mL Date Analyzed: 09/29/2009 1302 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Arsenic 0.0040 U 0.0040 0.010 Cadmium 0.0010 U 0.0010 0.0040 Lead 0.0020 U 0.0020 0.010 Chromium 0.0020 U 0.0020 0.010 Antimony 0.0040 U 0.0040 0.020 Beryllium 0.00050 U 0.00050 0.0020 Thallium 0.0050 U 0.0050 0.020 Nickel 0.0020 U 0.0020 0.0080 Silver 0.0010 U 0.0010 0.0040 Copper 0.0029 U 0.0029 0.010 Zinc 0.014 I 0.0050 0.020 Selenium 0.0050 U 0.0050 0.020 TestAmerlca Tampa Page 46 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-5s Lab Sample ID: 660-31745-7 Date Sampled: 09/21/2009 1540 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9129A Dilution: 1.0 Initial WeighWolume: 50 mL Date Analyzed: 09/29/2009 1307 Final WeighWolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Arsenic 0.0081 I 0.0040 0.010 Cadmium 0.0010 U 0.0010 0.0040 Lead 0.0020 U 0.0020 0.010 Chromium 0.0020 U 0.0020 0.010 Antimony 0.0040 U 0.0040 0.020 Beryllium 0.00050 U 0.00050 0.0020 Thallium 0.0050 U 0.0050 0.020 Nickel 0.0020 U 0.0020 0.0080 Silver 0.0010 U 0.0010 0.0040 Copper 0.0029 U 0.0029 0.010 Zinc 0.0050 U 0.0050 0.020 Selenium 0.0050 U 0.0050 0.020 I • TestAmerica Tampa Page 47 of 166 10/13/2009 I Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: MW-1s Lab Sample ID: 660-31745-8 Date Sampled: 09/22/2009 1000 Client Matrix: Water Date Received:09/23/2009 0830 6010B Metals(ICP)-Total Recoverable Method: 6010B Analysis Batch:660-85336 Instrument ID: ICPA Preparation: 3005A Prep Batch:660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeighWolume: 50 mL Date Analyzed: 09/29/2009 1313 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result(mg/L) Qualifier MDL PQL Arsenic 0.0040 U 0.0040 0.010 Cadmium 0.0010 U 0.0010 0.0040 Lead 0.0020 U 0.0020 0.010 Chromium 0.0020 U 0.0020 0.010 Antimony 0.0040 U 0.0040 0.020 Beryllium 0.00050 U 0.00050 0.0020 Thallium 0.0050 U 0.0050 0.020 Nickel 0.0020 U 0.0020 0.0080 Silver 0.0010 U 0.0010 0.0040 Copper 0.0029 U 0.0029 0.010 Zinc 0.0081 I 0.0050 0.020 Selenium 0.0050 U 0.0050 0.020 TestAmerica Tampa Page 48 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-1@1' Lab Sample ID: 660-31745-9 Date Sampled: 09/22/2009 1106 Client Matrix: Solid %Moisture: 8.1 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 60106 Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 30506 Prep Batch: 660-85255 Lab File ID: 91296 Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 0901 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.35 I 0.25 0.54 Cadmium 0.098 I 0.095 0.54 Chromium 6.5 0.18 1.1 Lead 5.1 0.16 0.54 TestAmerica Tampa Page 49 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-1@2' a Lab Sample ID: 660-31745-10 Date Sampled: 09/22/2009 1106 Client Matrix: Solid %Moisture: 5.9 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 0919 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.33 I 0.24 0.53 Cadmium 0.092 U 0.092 0.53 Chromium 1.8 0.18 1.1 Lead 2.2 0.16 0.53 TestAmerica Tampa Page 50 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-1@3' Lab Sample ID: 660-31745-11 Date Sampled: 09/22/2009 1106 Client Matrix: Solid %Moisture: 4.1 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 0924 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.24 U 0.24 0.52 Cadmium 0.091 U 0.091 0.52 Chromium 3.3 0.18 1.0 Lead 1.7 0.16 0.52 TestAmerica Tampa Page 51 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-1@4' Lab Sample ID: 660-31745-12 Date Sampled: 09/22/2009 1106 Client Matrix: Solid %Moisture: 9.4 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 0928 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.25 U 0.25 0.55 Cadmium 0.096 U 0.096 0.55 Chromium 1.1 0.19 1.1 Lead 0.79 0.17 0.55 TestAmerica Tampa Page 52 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-2@1' Lab Sample ID: 660-31745-13 Date Sampled: 09/22/2009 1125 Client Matrix: Solid %Moisture: 24.6 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial Weight/Volume: 1.0 g Date Analyzed: 09/29/2009 0942 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.31 U 0.31 0.66 Cadmium 0.12 U 0.12 0.66 Chromium 0.91 I 0.23 1.3 Lead 1.1 0.20 0.66 TestAmericaTampa Page 53 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-2@2' Lab Sample ID: 660-31745-14 Date Sampled: 09/22/2009 1125 Client Matrix: Solid %Moisture: 7.5 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 0947 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.25 U 0.25 0.54 Cadmium 0.094 U 0.094 0.54 Chromium 1.3 0.18 1.1 Lead 0.94 0.16 0.54 TestAmerica Tampa Page 54 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-2@3' Lab Sample ID: 660-31745-15 Date Sampled: 09/22/2009 1125 Client Matrix: Solid %Moisture: 25.6 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch: 660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial Weight/Volume: 1.0 g Date Analyzed: 09/29/2009 0952 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.31 U 0.31 0.67 Cadmium 0.12 U 0.12 0.67 Chromium 0.74 I 0.23 1.3 Lead 0.61 I 0.20 0.67 TestAmerica Tampa Page 55 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-2@4' Lab Sample ID: 660-31745-16 Date Sampled: 09/22/2009 1125 Client Matrix: Solid %Moisture: 6.2 Date Received: 09/23/2009 0830 60106 Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial Weight/Volume: 1.0 g Date Analyzed: 09/29/2009 0956 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.25 U 0.25 0.53 Cadmium 0.093 U 0.093 0.53 Chromium 0.83 I 0.18 1.1 Lead 0.73 0.16 0.53 TestAmerica Tampa Page 56 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-3@1' Lab Sample ID: 660-31745-17 Date Sampled: 09/22/2009 1140 Client Matrix: Solid %Moisture: 26.5 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1001 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.31 U 0.31 0.68 Cadmium 0.12 U 0.12 0.68 Chromium 1.7 0.23 1.4 Lead 2.0 0.20 0.68 TestAmerica Tampa Page 57 of 166 10/13/2009 Analytical Data w Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-3@2' Lab Sample ID: 660-31745-18 Date Sampled: 09/22/2009 1140 Client Matrix: Solid %Moisture: 3.8 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1006 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.30 I 0.24 0.52 Cadmium 0.090 U 0.090 0.52 Chromium 0.95 I 0.18 1.0 Lead 0.89 0.16 0.52 TestAmericaTampa Page 58 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-3@3' Lab Sample ID: 660-31745-19 Date Sampled: 09/22/2009 1140 Client Matrix: Solid %Moisture: 26.0 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1010 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.31 U 0.31 0.68 Cadmium 0.12 U 0.12 0.68 Chromium 0.90 I 0.23 1.4 Lead 0.82 0.20 0.68 TestAmerica Tampa Page 59 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-3@4' Lab Sample ID: 660-31745-20 Date Sampled: 09/22/2009 1140 Client Matrix: Solid %Moisture: 6.4 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 1015 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.25 U 0.25 0.53 Cadmium 0.093 U 0.093 0.53 Chromium 0.91 I 0.18 1.1 Lead 0.86 0.16 0.53 TestAmerica Tampa Page 60 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-4@1' Lab Sample ID: 660-31745-21 Date Sampled: 09/22/2009 1155 Client Matrix: Solid %Moisture: 5.0 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 1019 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.24 U 0.24 0.53 Cadmium 0.092 U 0.092 0.53 Chromium 0.91 I 0.18 1.1 Lead 1.1 0.16 0.53 TestAmerica Tampa Page 61 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-4@2' Lab Sample ID: 660-31745-22 Date Sampled: 09/22/2009 1155 Client Matrix: Solid %Moisture: 5.1 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9l29B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1024 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.24 U 0.24 0.53 Cadmium 0.092 U 0.092 0.53 Chromium 0.67 I 0.18 1.1 Lead 0.68 0.16 0.53 TestAmerica Tampa Page 62 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-4@3' Lab Sample ID: 660-31745-23 Date Sampled: 09/22/2009 1155 Client Matrix: Solid %Moisture: 20.6 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch: 660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch: 660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1038 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.29 U 0.29 0.63 Cadmium 0.11 U 0.11 0.63 Chromium 0.75 I 0.21 1.3 Lead 0.67 0.19 0.63 , TestAmerica Tampa Page 63 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-4@4' Lab Sample ID: 660-31745-24 Date Sampled: 09/22/2009 1155 Client Matrix: Solid %Moisture: 11.5 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 1043 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.26 U 0.26 0.57 Cadmium 0.098 U 0.098 0.57 Chromium 0.60 I 0.19 1.1 Lead 0.59 0.17 0.57 TestAmerica Tampa Page 64 of 166 10/13/2009 I Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-5n@1' Lab Sample ID: 660-31745-25 Date Sampled: 09/22/2009 1205 Client Matrix: Solid %Moisture: 3.2 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1047 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.24 U 0.24 0.52 Cadmium 0.090 U 0.090 0.52 Chromium 1.1 0.18 1.0 Lead 0.93 0.15 0.52 4 TestAmerica Tampa Page 65 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-5@2' Lab Sample ID: 660-31745-26 Date Sampled: 09/22/2009 1205 Client Matrix: Solid %Moisture: 27.2 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 1052 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL 1 Arsenic 0.32 U 0.32 0.69 Cadmium 0.12 U 0.12 0.69 Chromium 1.4 0.23 1.4 Lead 1.2 0.21 0.69 TestAmerica Tampa Page 66 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-5@3' Lab Sample ID: 660-31745-27 Date Sampled: 09/22/2009 1205 Client Matrix: Solid %Moisture: 4.6 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 60106 Analysis Batch: 660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 1056 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.24 U 0.24 0.52 Cadmium 0.091 U 0.091 0.52 Chromium 1.4 0.18 1.0 Lead 1.1 0.16 0.52 TestAmerica Tampa Page 67 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-5@4' Lab Sample ID: 660-31745-28 Date Sampled: 09/22/2009 1205 Client Matrix: Solid %Moisture: 9.7 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85255 Lab File ID: 9I29B Dilution: 1.0 Initial Weight/Volume: 1.0 g Date Analyzed: 09/29/2009 1101 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.25 U 0.25 0.55 Cadmium 0.096 U 0.096 0.55 Chromium 1.3 0.19 1.1 Lead 1.0 0.17 0.55 TestAmerica Tampa Page 68 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-6@1' Lab Sample ID: 660-31745-29 Date Sampled: 09/22/2009 1220 Client Matrix: Solid %Moisture: 24.6 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1130 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.38 U 0.38 2.2 Chromium 4.2 I 0.75 4.4 Lead 3.5 0.66 2.2 1 TestAmerica Tampa Page 69 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-6@2' Lab Sample ID: 660-31745-30 Date Sampled: 09/22/2009 1220 Client Matrix: Solid %Moisture: 9.3 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial Weight/Volume: 0.3 g Date Analyzed: 09/29/2009 1158 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.2 I 0.85 1.8 Cadmium 0.32 U 0.32 1.8 Chromium 5.6 0.62 3.7 Lead 4.4 0.55 1.8 1 1 TestAmerica Tampa Page 70 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-6@3' Lab Sample ID: 660-31745-31 Date Sampled: 09/22/2009 1220 Client Matrix: Solid %Moisture: 6.3 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch: 660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1203 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.82 U 0.82 1.8 Cadmium 0.31 U 0.31 1.8 Chromium 5.0 0.60 3.6 Lead 3.6 0.53 1.8 TestAmericaTampa Page 71 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-6@4' Lab Sample ID: 660-31745-32 Date Sampled: 09/22/2009 1220 Client Matrix: Solid %Moisture: 17.9 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch: 660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch: 660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1207 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.4 I 0.93 2.0 Cadmium 0.35 U 0.35 2.0 Chromium 12 0.69 4.1 Lead 6.2 0.61 2.0 TestAmerica Tampa Page 72 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-7@1' Lab Sample ID: 660-31745-33 Date Sampled: 09/22/2009 1300 Client Matrix: Solid %Moisture: 5.5 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 30508 Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1212 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.2 I 0.81 1.8 Cadmium 0.31 U 0.31 1.8 Chromium 4.7 0.60 3.5 Lead 3.6 0.53 1.8 TestAmerica Tampa Page 73 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-7@2' Lab Sample ID: 660-31745-34 Date Sampled: 09/22/2009 1300 Client Matrix: Solid %Moisture: 4.9 Date Received: 09/23/2009 0830 601013 Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 91298 Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1217 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.81 U 0.81 1.8 Cadmium 0.30 U 0.30 1.8 Chromium 5.4 0.60 3.5 Lead 4.2 0.53 1.8 TestAmerica Tampa Page 74 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-7@3' Lab Sample ID: 660-31745-35 Date Sampled: 09/22/2009 1300 Client Matrix: Solid %Moisture: 7.8 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1221 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.83 U 0.83 1.8 Cadmium 0.31 U 0.31 1.8 Chromium 5.0 0.61 3.6 Lead 3.2 0.54 1.8 TestAmerica Tampa Page 75 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-7@:41' Lab Sample ID: 660-31745-36 Date Sampled: 09/22/2009 1300 Client Matrix: Solid %Moisture: 18.9 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1226 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.94 U 0.94 2.1 Cadmium 0.36 U 0.36 2.1 Chromium 4.7 0.70 4.1 Lead 2.9 0.62 2.1 TestAmerica Tampa Page 76 of 166 10/13/2009 I Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-8@1' Lab Sample ID: 660-31745-37 Date Sampled: 09/22/2009 1400 Client Matrix: Solid %Moisture: 28.9 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9I29B Dilution: 1.0 Initial Weight/Volume: 0.3 g Date Analyzed: 09/29/2009 1240 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.1 U 1.1 2.3 Cadmium 0.41 U 0.41 2.3 Chromium 4.1 I 0.80 4.7 Lead 4.5 0.70 2.3 TestAmericaTampa Page 77 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-8@2' Lab Sample ID: 660-31745-38 Date Sampled: 09/22/2009 1400 Client Matrix: Solid %Moisture: 26.9 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 60106 Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 30506 Prep Batch:660-85267 Lab File ID: 91296 Dilution: 1.0 Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1245 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.3 Cadmium 0.40 U 0.40 2.3 Chromium 3.6 I 0.78 4.6 Lead 3.0 0.68 2.3 TestAmericaTampa Page 78 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-8@3' Lab Sample ID: 660-31745-39 Date Sampled: 09/22/2009 1400 Client Matrix: Solid %Moisture: 12.4 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1249 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.88 U 0.88 1.9 —Cadmium 0.33 U 0.33 1.9 Chromium 4.7 0.65 3.8 Lead 4.2 0.57 1.9 TestAmericaTampa Page 79 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-8@4' Lab Sample ID: 660-31745-40 Date Sampled: 09/22/2009 1400 Client Matrix: Solid %Moisture: 25.0 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1254 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.39 U 0.39 2.2 Chromium 2.9 I 0.76 4.4 Lead 2.4 0.67 2.2 TestAmerica Tampa Page 80 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-9@1' Lab Sample ID: 660-31745-41 Date Sampled: 09/22/2009 1420 Client Matrix: Solid %Moisture: 25.4 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch: 660-85267 Lab File ID: 9I29B Dilution: 1.0 Initial Weight/Volume: 0.3 g Date Analyzed: 09/29/2009 1258 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 , Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.39 U 0.39 2.2 Chromium 5.8 0.76 4.5 Lead 7.1 0.67 2.2 I TestAmericaTampa Page 81 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-9@2' Lab Sample ID: 660-31745-42 Date Sampled: 09/22/2009 1420 Client Matrix: Solid %Moisture: 19.3 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1303 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.95 U 0.95 2.1 Cadmium 0.36 U 0.36 2.1 Chromium 6.1 0.70 4.1 Lead 7.4 0.62 2.1 TestAmerica Tampa Page 82 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-9@3' Lab Sample ID: 660-31745-43 Date Sampled: 09/22/2009 1420 Client Matrix: Solid %Moisture: 24.9 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1308 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.39 U 0.39 2.2 Chromium 4.9 0.75 4.4 Lead 4.9 0.67 2.2 TestAmerica Tampa Page 83 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-9@4' Lab Sample ID: 660-31745-44 Date Sampled: 09/22/2009 1420 Client Matrix: Solid %Moisture: 24.3 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1312 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.38 U 0.38 2.2 Chromium 2.8 I 0.75 4.4 Lead 2.2 0.66 2.2 TestAmerica Tampa Page 84 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-10@1' Lab Sample ID: 660-31745-45 Date Sampled: 09/22/2009 1435 Client Matrix: Solid %Moisture: 25.6 Date Received: 09/23/2009 0830 60108 Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1317 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.39 U 0.39 2.2 Chromium 3.4 I 0.76 4.5 Lead 3.5 0.67 2.2 TestAmerica Tampa Page 85 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-10@2' Lab Sample ID: 660-31745-46 Date Sampled: 09/22/2009 1435 Client Matrix: Solid %Moisture: 24.1 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1322 Final Weight/Volume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 1.0 U 1.0 2.2 Cadmium 0.38 U 0.38 2.2 Chromium 3.2 I 0.75 4.4 Lead 2.7 0.66 2.2 TestAmerica Tampa Page 86 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-10@3' Lab Sample ID: 660-31745-47 Date Sampled: 09/22/2009 1435 Client Matrix: Solid %Moisture: 21.6 Date Received:09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9I29B Dilution: 1.0 Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1335 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected: Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.98 U 0.98 2.1 Cadmium 0.37 U 0.37 2.1 Chromium 2.7 I 0.72 4.3 Lead 2.5 0.64 2.1 TestAmerica Tampa Page 87 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 Client Sample ID: SB-10@4' Lab Sample ID: 660-31745-48 Date Sampled: 09/22/2009 1435 Client Matrix: Solid %Moisture: 22.1 Date Received: 09/23/2009 0830 6010B Metals(ICP) Method: 6010B Analysis Batch:660-85323 Instrument ID: ICPB Preparation: 3050B Prep Batch:660-85267 Lab File ID: 9I29B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1340 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte DryWt Corrected:Y Result(mg/Kg) Qualifier MDL PQL Arsenic 0.98 U 0.98 2.1 Cadmium 0.37 U 0.37 2.1 Chromium 2.7 I 0.73 4.3 Lead 2.3 0.64 2.1 TestAmericaTampa Page 88 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: TW-05 Lab Sample ID: 660-31745-1 Date Sampled: 09/21/2009 0945 Client Matrix. Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method Ammonia(as N) 0.077 mg/L 0.010 0.020 1.0 350.1 Analysis Batch: 660-85393 Date Analyzed: 09/30/2009 1424 Nitrate Nitrite as N 29 J3 mg/L 0.10 0 50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U J3 mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 29 mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 TestAmerica Tampa Page 89 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: TW-04 Lab Sample ID: 660-31745-2 Date Sampled: 09/21/2009 1040 Client Matrix: Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL DiI Method Ammonia(as N) 20 mg/L 0.10 0.20 • 10 350.1 Analysis Batch:660-85394 Date Analyzed: 09/30/2009 1457 Nitrate Nitrite as N 0.11 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 0.11 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed:09/23/2009 1000 • TestAmericaTampa Page 90 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: TW-03 Lab Sample ID: 660-31745-3 Date Sampled: 09/21/2009 1150 Client Matrix: Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL DO Method Ammonia(as N) 0.37 mg/L 0.010 0.020 1.0 350.1 Analysis Batch:660-85393 Date Analyzed: 09/30/2009 1429 Nitrate Nitrite as N 0.28 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed:09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed:09/23/2009 1000 Nitrate as N 0.28 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 TestAmerica Tampa Page 91 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: TW-06 Lab Sample ID: 660-31745-4 Date Sampled: 09/21/2009 1248 Client Matrix: Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method Ammonia(as N) 0.14 mg/L 0.010 0.020 1.0 350.1 Analysis Batch:660-85393 Date Analyzed: 09/30/2009 1430 Nitrate Nitrite as N 15 mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 15 mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 TestAmerica Tampa Page 92 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: MW-2s Lab Sample ID: 660-31745-5 Date Sampled: 09/21/2009 1351 Client Matrix: Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method Ammonia(as N) 0.010 U mg/L 0.010 0.020 1.0 350.1 Analysis Batch: 660-85393 Date Analyzed: 09/30/2009 1431 Nitrate Nitrite as N 1.9 mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 1.9 mg/L 0.10 0.50 1.0 353.2 Analysis Batch: 660-85136 Date Analyzed: 09/23/2009 1000 I I TestAmerica Tampa Page 93 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: MW-3s Lab Sample ID: 660-31745-6 Date Sampled: 09/21/2009 1443 Client Matrix: Water Date Received:09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method Ammonia(as N) 0.010 U mg/L 0.010 0.020 1.0 350.1 Analysis Batch: 660-85393 Date Analyzed: 09/30/2009 1432 Nitrate Nitrite as N 0.41 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 0.41 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed:09/23/2009 1000 TestAmericaTampa Page 94 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: MW-5s Lab Sample ID: 660-31745-7 Date Sampled: 09/21/2009 1540 Client Matrix: Water Date Received: 09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method ---------- Ammonia(as N) 0.12 mg/L 0.010 0.020 1.0 350.1 Analysis Batch:660-85393 Date Analyzed: 09/30/2009 1433 Nitrate Nitrite as N 0.35 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed:09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 0.35 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 TestAmerica Tampa Page 95 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: MW-1s Lab Sample ID: 660-31745-8 Date Sampled: 09/22/2009 1000 Client Matrix: Water Date Received:09/23/2009 0830 Analyte Result Qual Units MDL PQL Dil Method Ammonia(as N) 0.010 U mg/L 0.010 0.020 1.0 350.1 Analysis Batch:660-85393 Date Analyzed: 09/30/2009 1434 Nitrate Nitrite as N 0.50 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrite as N 0.10 U mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed: 09/23/2009 1000 Nitrate as N 0.50 I mg/L 0.10 0.50 1.0 353.2 Analysis Batch:660-85136 Date Analyzed:09/23/2009 1000 TestAmerica Tampa Page 96 of 166 10/13/2009 I Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-1@1' Lab Sample ID: 660-31745-9 Date Sampled: 09/22/2009 1106 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 92 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1839 DryWt Corrected: N Percent Moisture 8.1 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1839 DryWt Corrected: N TestAmerica Tampa Page 97 of 166 10/13/2009 I Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-1@2' Lab Sample ID: 660-31745-10 Date Sampled: 09/22/2009 1106 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 94 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1637 DryWt Corrected: N Percent Moisture 5.9 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1637 DryWt Corrected: N TestAmerica Tampa Page 98 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-1@3' Lab Sample ID: 660-31745-11 Date Sampled: 09/22/2009 1106 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 96 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1632 DryWt Corrected: N Percent Moisture 4.1 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1632 DryWt Corrected: N TestAmerica Tampa Page 99 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-1@4' Lab Sample ID: 660-31745-12 Date Sampled: 09/22/2009 1106 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 91 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1639 DryWt Corrected: N Percent Moisture 9.4 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1639 DryWt Corrected: N TestAmericaTampa Page 100 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-2@1' Lab Sample ID: 660-31745-13 Date Sampled: 09/22/2009 1125 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 75 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 0919 DryWt Corrected: N Percent Moisture 25 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 0919 DryWt Corrected: N TestAmerica Tampa Page 101 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-2@2' Lab Sample ID: 660-31745-14 Date Sampled: 09/22/2009 1125 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 92 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1728 DryWt Corrected: N Percent Moisture 7.5 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1728 DryWt Corrected: N TestAmericaTampa Page 102 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-2@3' Lab Sample ID: 660-31745-15 Date Sampled: 09/22/2009 1125 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 74 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 0903 Drywt Corrected: N Percent Moisture 26 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 0903 DryWt Corrected: N TestAmericaTampa Page 103 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-2@4' Lab Sample ID: 660-31745-16 Date Sampled: 09/22/2009 1125 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 94 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1749 DryWt Corrected: N Percent Moisture 6.2 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1749 DryWt Corrected: N TestAmericaTampa Page 104 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-3@1' Lab Sample ID: 660-31745-17 Date Sampled: 09/22/2009 1140 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 73 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1017 DryWt Corrected: N Percent Moisture 27 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1017 DryWt Corrected: N TestAmerica Tampa Page 105 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-3@2' Lab Sample ID: 660-31745-18 Date Sampled: 09/22/2009 1140 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 96 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1727 DryWt Corrected: N Percent Moisture 3.8 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1727 DryWt Corrected: N TestAmericaTampa Page 106 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-3@3' Lab Sample ID: 660-31745-19 Date Sampled: 09/22/2009 1140 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 74 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 1019 DryWt Corrected: N Percent Moisture 26 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 1019 DryWt Corrected: N TestAmerica Tampa Page 107 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-3 a@4' Lab Sample ID: 660-31745-20 Date Sampled: 09/22/2009 1140 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 94 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1749 DryWt Corrected: N Percent Moisture 6.4 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1749 DryWt Corrected: N TestAmericaTampa Page 108 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-4@1' Lab Sample ID: 660-31745-21 Date Sampled: 09/22/2009 1155 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 95 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed:09/24/2009 1803 DryWt Corrected: N Percent Moisture 5.0 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1803 DryWt Corrected: N TestAmericaTampa Page 109 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-4@2' Lab Sample ID: 660-31745-22 Date Sampled: 09/22/2009 1155 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 95 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1641 DryWt Corrected: N Percent Moisture 5.1 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1641 DryWt Corrected: N TestAmerica Tampa Page 110 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-443' Lab Sample ID: 660-31745-23 Date Sampled: 09/22/2009 1155 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 79 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1054 DryWt Corrected: N Percent Moisture 21 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1054 DryWt Corrected: N TestAmericaTampa Page 111 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-444' Lab Sample ID: 660-31745-24 Date Sampled: 09/22/2009 1155 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 88 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1820 DryWt Corrected: N Percent Moisture 12 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1820 DryWt Corrected: N TestAmerica Tampa Page 112 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-5@1' Lab Sample ID: 660-31745-25 Date Sampled: 09/22/2009 1205 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 97 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1805 DryWt Corrected: N Percent Moisture 3.2 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1805 DryWt Corrected: N • TestAmerica Tampa Page 113 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-5@2' Lab Sample ID: 660-31745-26 Date Sampled: 09/22/2009 1205 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 73 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1912 Drywt Corrected: N Percent Moisture 27 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1912 DryWt Corrected: N TestAmerica Tampa Page 114 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-5@3' Lab Sample ID: 660-31745-27 Date Sampled: 09/22/2009 1205 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 95 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1802 DryWt Corrected: N Percent Moisture 4.6 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1802 DryWt Corrected: N TestAmericaTampa Page 115 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-5@4' Lab Sample ID: 660-31745-28 Date Sampled: 09/22/2009 1205 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 90 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1819 DryWt Corrected: N Percent Moisture 9.7 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1819 DryWt Corrected: N 1 TestAmerica Tampa Page 116 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-6@1' Lab Sample ID: 660-31745-29 Date Sampled: 09/22/2009 1220 Client Matrix. Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 75 % 0.10 0.10 1.0 Moisture Analysis Batch 660-85167 Date Analyzed: 09/24/2009 1849 DryWt Corrected: N Percent Moisture 25 % 0.10 0.10 1.0 Moisture Analysis Batch. 660-85167 Date Analyzed: 09/24/2009 1849 DryWt Corrected: N TestAmerica Tampa Page 117 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-6@2' Lab Sample ID: 660-31745-30 Date Sampled: 09/22/2009 1220 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 91 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1833 DryWt Corrected: N Percent Moisture 9.3 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1833 DryWt Corrected: N TestAmerica Tampa Page 118 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-6@3' Lab Sample ID: 660-31745-31 Date Sampled: 09/22/2009 1220 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 94 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed:09/24/2009 1826 DryWt Corrected: N Percent Moisture 6.3 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1826 DryWt Corrected: N TestAmericaTampa Page 119 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-6@4' Lab Sample ID: 660-31745-32 Date Sampled: 09/22/2009 1220 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 82 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1859 DryWt Corrected: N Percent Moisture 18 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1859 DryWt Corrected: N TestAmerica Tampa Page 120 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-7@1' Lab Sample ID: 660-31745-33 Date Sampled: 09/22/2009 1300 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 95 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1809 DryWt Corrected: N Percent Moisture 5.5 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1809 DryWt Corrected: N TestAmericaTampa Page 121 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-7@2' Lab Sample ID: 660-31745-34 Date Sampled: 09/22/2009 1300 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 95 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed: 09/24/2009 1825 DryWt Corrected: N Percent Moisture 4.9 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1825 DryWt Corrected: N TestAmerica Tampa Page 122 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-7@3' Lab Sample ID: 660-31745-35 Date Sampled: 09/22/2009 1300 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 92 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed:09/24/2009 1833 DryWt Corrected: N Percent Moisture 7.8 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed:09/24/2009 1833 DryWt Corrected: N TestAmericaTampa Page 123 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-7@4' Lab Sample ID: 660-31745-36 Date Sampled: 09/22/2009 1300 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 81 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1901 DryWt Corrected: N Percent Moisture 19 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1901 DryWt Corrected: N TestAmericaTampa Page 124 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-8@1' Lab Sample ID: 660-31745-37 Date Sampled: 09/22/2009 1400 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 71 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 0926 DryWt Corrected: N Percent Moisture 29 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 0926 DryWt Corrected: N TestAmerica Tampa Page 125 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-8@2' Lab Sample ID: 660-31745-38 Date Sampled: 09/22/2009 1400 Client Matrix. Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 73 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0844 Drywt Corrected N Percent Moisture 27 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0844 DryWt Corrected: N TestAmerica Tampa Page 126 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-8@3' Lab Sample ID: 660-31745-39 Date Sampled: 09/22/2009 1400 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 88 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1839 DryWt Corrected: N Percent Moisture 12 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1839 DryWt Corrected: N TestAmerica Tampa Page 127 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-8@4' Lab Sample ID: 660-31745-40 Date Sampled: 09/22/2009 1400 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 75 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0943 DryWt Corrected: N Percent Moisture 25 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0943 DryWt Corrected: N TestAmerica Tampa Page 128 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-9@1' Lab Sample ID: 660-31745-41 Date Sampled: 09/22/2009 1420 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 75 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85167 Date Analyzed:09/24/2009 1848 DryWt Corrected: N Percent Moisture 25 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed:09/24/2009 1848 DryWt Corrected: N II TestAmerica Tampa Page 129 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-9@2' Lab Sample ID: 660-31745-42 Date Sampled: 09/22/2009 1420 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 81 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1812 DryWt Corrected: N Percent Moisture 19 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85167 Date Analyzed: 09/24/2009 1812 DryWt Corrected: N TestAmerica Tampa Page 130 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-9@3' Lab Sample ID: 660-31745-43 Date Sampled: 09/22/2009 1420 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 75 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1037 DryWt Corrected: N Percent Moisture 25 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1037 DryWt Corrected: N TestAmericaTampa Page 131 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-9 a@4' Lab Sample ID: 660-31745-44 Date Sampled: 09/22/2009 1420 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 76 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 1047 DryWt Corrected: N Percent Moisture 24 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed: 09/25/2009 1047 DryWt Corrected: N TestAmericaTampa Page 132 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-10@1' Lab Sample ID: 660-31745-45 Date Sampled: 09/22/2009 1435 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 74 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0906 DryWt Corrected: N Percent Moisture 26 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0906 DryWt Corrected: N TestAmericaTampa Page 133 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-10@2' Lab Sample ID: 660-31745-46 Date Sampled: 09/22/2009 1435 Client Matrix: Solid Date Received: 09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 76 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0945 DryWt Corrected: N Percent Moisture 24 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed: 09/25/2009 0945 DryWt Corrected: N TestAmerica Tampa Page 134 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-10@3' Lab Sample ID: 660-31745-47 Date Sampled: 09/22/2009 1435 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 78 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 1030 DryWt Corrected: N Percent Moisture 22 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 1030 DryWt Corrected: N TestAmericaTampa Page 135 of 166 10/13/2009 Analytical Data Client: ESciences, Inc. Job Number: 660-31745-1 General Chemistry Client Sample ID: SB-10@4' Lab Sample ID: 660-31745-48 Date Sampled: 09/22/2009 1435 Client Matrix: Solid Date Received:09/23/2009 0830 Analyte Result Qual Units PQL PQL Dil Method Percent Solids 78 % 0.10 0.10 1.0 Moisture Analysis Batch: 660-85194 Date Analyzed:09/25/2009 0842 DryWt Corrected: N Percent Moisture 22 % 0.10 0.10 1.0 Moisture Analysis Batch:660-85194 Date Analyzed:09/25/2009 0842 DryWt Corrected: N TestAmerica Tampa Page 136 of 166 10/13/2009 DATA REPORTING QUALIFIERS Client: ESciences, Inc. Job Number: 660-31745-1 Lab Section Qualifier Description GC/MS VOA J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. GC/MS Semi VOA J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. Metals U Indicates that the compound was analyzed for but not detected. The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. General Chemistry J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. TestAmerica Tampa Page 137 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85350 Method: 8260B Preparation: 5030B Lab Sample ID: MB 660-85350/4 Analysis Batch: 660-85350 Instrument ID: BVMH GC/MS Client Matrix: Water Prep Batch: N/A Lab File ID: 1HI2608.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 5 mL Date Analyzed: 09/26/2009 1227 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1227 Analyte Result Qual MDL PQL Acrolein 3.8 U 3.8 100 Acrylonitrile 1.2 U 1.2 100 Benzene 0.50 U 0.50 1.0 Bromoform 0.58 U 0.58 1.0 Carbon tetrachloride 0.42 U 0.42 1.0 Chlorobenzene 0.63 U 0.63 1.0 Chlorodibromomethane 0.34 U 0.34 1.0 Chloroethane 2.5 U 2.5 5.0 2-Chloroethyl vinyl ether 0.95 U 0.95 5.0 Chloroform 0.90 U 0.90 1.0 Dichlorobromomethane 0.35 U 0.35 1.0 1,1-Dichloroethane 0.52 U 0.52 1.0 1,2-Dichloroethane 0.57 U 0.57 1.0 1,1-Dichloroethene 0.45 U 0.45 1.0 1,2-Dichloropropane 0.52 U 0.52 1.0 cis-1,3-Dichloropropene 0.14 U 0.14 1.0 trans-1,3-Dichloropropene 0.14 U 0.14 1.0 Ethylbenzene 0.44 U 0.44 1.0 Bromomethane 2.5 U 2.5 5.0 Chloromethane 1.0 U 1.0 4.0 Methylene Chloride 4.0 U 4.0 5.0 1,1,2,2-Tetrachloroethane 0.15 U 0.15 1.0 Tetrachloroethene 0.50 U 0.50 1.0 Toluene 0.51 U 0.51 1.0 trans-1,2-Dichloroethene 0.44 U 0.44 1.0 1,1,1-Trichloroethane 0.46 U 0.46 1.0 1,1,2-Trichloroethane 0.47 U 0.47 1.0 Trichloroethene 0.50 U 0.50 1.0 Vinyl chloride 0.50 U 0.50 1.0 Xylenes,Total 0.50 U 0.50 3.0 Surrogate %Rec Acceptance Limits 4-Bromofluorobenzene 103 70-130 Dibromofluoromethane 106 70-130 Toluene-d8(Surr) 80 70- 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 138 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Lab Control Sample-Batch: 660-85350 Method: 8260B Preparation: 5030B Lab Sample ID: LCS 660-85350/3 Analysis Batch: 660-85350 Instrument ID: BVMH GC/MS Client Matrix: Water Prep Batch: N/A Lab File ID: 1 H12605.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 5 mL Date Analyzed: 09/26/2009 1122 Final WeightNolume: 5 mL Date Prepared: 09/26/2009 1122 Analyte Spike Amount Result %Rec. Limit Qual Acrolein 400 221 55 54-145 Acrylonitrile 200 216 108 10- 183 Benzene 20.0 21.4 107 64- 140 Bromoform 20.0 20.0 100 65- 130 Carbon tetrachloride 20.0 22.5 113 53-145 Chlorobenzene 20.0 19.2 96 70- 130 Chlorodibromomethane 20.0 19.5 98 70- 130 Chloroethane 20.0 27.0 135 39- 174 2-Chloroethyl vinyl ether 40.0 99.3 248 10-177 J3 Chloroform 20.0 21.8 109 59-130 Dichlorobromomethane 20.0 20.1 100 70-130 1,1-Dichloroethane 20.0 22.5 113 60-132 1,2-Dichloroethane 20.0 21.5 108 70-130 1,1-Dichloroethene 20.0 22.1 111 51 -157 1,2-Dichloropropane 20.0 20.4 102 70-130 cis-1,3-Dichloropropene 20.0 20.6 103 70-130 trans-1,3-Dichloropropene 20.0 20.5 103 62-130 Ethylbenzene 20.0 20.0 100 69-131 Bromomethane 20.0 34.4 172 14-184 Chloromethane 20.0 22.1 110 35-153 Methylene Chloride 20.0 21.4 107 57-130 1,1,2,2-Tetrachloroethane 20.0 18.9 95 67-130 Tetrachloroethene 20.0 20.5 103 47-143 Toluene 20.0 20.0 100 70-131 trans-1,2-Dichloroethene 20.0 21.6 108 55-145 1,1,1-Trichloroethane 20.0 23.0 115 57-135 1,1,2-Trichloroethane 20.0 20.3 101 69-130 Trichloroethene 20.0 22.5 113 59-142 Vinyl chloride 20.0 23.9 120 48-147 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 139 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike-Batch: 660-85350 Method: 82606 Preparation: 5030B Lab Sample ID: 660-31756-B-7 MS Analysis Batch: 660-85350 Instrument ID: BVMH GC/MS Client Matrix: Water Prep Batch: N/A Lab File ID: 1 HI2618.D Dilution: 1.0 Units: ug/L Initial Weight/Volume: 5 mL Date Analyzed: 09/26/2009 1559 Final WeighWolume: 5 mL Date Prepared: 09/26/2009 1559 Analyte Sample Result/Qual Spike Amount Result %Rec. Limit Qual Acrolein 3.8 U 1000 3.8 0 54- 145 U J3 i Acrylonitrile 1.2 U 500 563 113 10- 183 Benzene 0.50 U 50.0 62.8 126 64- 140 Bromoform 0.58 U 50.0 51.9 104 65- 130 Carbon tetrachloride 0.42 U 50.0 61.2 122 53- 145 Chlorobenzene 0.63 U 50.0 57.7 115 70- 130 Chlorodibromomethane 0.34 U 50.0 53.3 107 70- 130 Chloroethane 2.5 U 50.0 62.9 126 39- 174 2-Chloroethyl vinyl ether 0.95 U 100 17.9 18 10- 177 Chloroform 0.90 U 50.0 61.1 122 59- 130 Dichlorobromomethane 0.35 U 50.0 56.5 113 70- 130 1,1-Dichloroethane 0.52 U 50.0 61.7 123 60- 132 1,2-Dichloroethane 0.57 U 50.0 61.7 123 70- 130 1,1-Dichloroethene 0.45 U 50.0 68.9 138 51 - 157 1,2-Dichloropropane 0.52 U 50.0 57.4 115 70- 130 cis-1,3-Dichloropropene 0.14 U 50.0 48.4 97 70- 130 trans-1,3-Dichloropropene 0.14 U 50.0 49.5 99 62- 130 Ethylbenzene 0.44 U 50.0 58.2 116 69- 131 Bromomethane 2.5 U 50.0 48.4 97 14-184 Chloromethane 1.0 U 50.0 52.3 105 35- 153 Methylene Chloride 4.0 U 50.0 58.6 117 57- 130 1,1,2,2-Tetrachloroethane 0.15 U 50.0 52.4 105 67- 130 Tetrachloroethene 0.50 U 50.0 55.0 110 47- 143 Toluene 0.51 U 50.0 62.8 126 70-131 trans-1,2-Dichloroethene 0.85 I 50.0 65.8 130 55-145 1,1,1-Trichloroethane 0.46 U 50.0 65.9 132 57- 135 1,1,2-Trichloroethane 0.47 U 50.0 62.4 125 69- 130 Trichloroethene 0.50 U 50.0 65.4 131 59- 142 Vinyl chloride 0.50 U 50.0 59.4 119 48- 147 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 140 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Duplicate-Batch: 660-85350 Method: 8260B Preparation: 5030B Lab Sample ID: 660-31756-B-2 DU Analysis Batch: 660-85350 Instrument ID: BVMH GC/MS Client Matrix: Water Prep Batch: N/A Lab File ID: 1 H12612.D Dilution: 1.0 Units: ug/L Initial WeighWolume: 5 mL Date Analyzed: 09/26/2009 1351 Final Weight/Volume: 5 mL Date Prepared: 09/26/2009 1351 Analyte Sample Result/Qual Result RPD Limit Qual Acrolein 3.8 U 3.8 NC 30 U Acrylonitrile 1.2 U 1.2 NC 30 U Benzene 0.50 U 0.50 NC 30 U Bromoform 0.58 U 0.58 NC 30 U Carbon tetrachloride 0.42 U 0.42 NC 30 U Chlorobenzene 0.63 U 0.63 NC 30 U Chlorodibromomethane 0.34 U 0.34 NC 30 U Chloroethane 2.5 U 2.5 NC 30 U 2-Chloroethyl vinyl ether 0.95 U 0.95 NC 30 U J3 Chloroform 0.90 U 0.90 NC 30 U Dichlorobromomethane 0.35 U 0.35 NC 30 U 1,1-Dichloroethane 0.52 U 0.52 NC 30 U 1,2-Dichloroethane 0.57 U 0.57 NC 30 U 1,1-Dichloroethene 0.45 U 0.45 NC 30 U 1,2-Dichloropropane 0.52 U 0.52 NC 30 U cis-1,3-Dichloropropene 0.14 U 0.14 NC 30 U trans-1,3-Dichloropropene 0.14 U 0.14 NC 30 U Ethylbenzene 0.44 U 0.44 NC 30 U Bromomethane 2.5 U 2.5 NC 30 U Chloromethane 1.0 U 1.0 NC 30 U Methylene Chloride 4.0 U 4.0 NC 30 U 1,1,2,2-Tetrachloroethane 0.15 U 0.15 NC 30 U Tetrachloroethene 0.50 U 0.50 NC 30 U Toluene 0.51 U 0.51 NC 30 U trans-1,2-Dichloroethene 0.44 U 0.44 NC 30 U 1,1,1-Trichloroethane 0.46 U 0.46 NC 30 U 1,1,2-Trichloroethane 0.47 U 0.47 NC 30 U Trichloroethene 0.50 U 0.50 NC 30 U Vinyl chloride 0.50 U 0.50 NC 30 U Xylenes,Total 0.50 U 0.50 NC 30 U Surrogate %Rec Acceptance Limits 4-Bromofluorobenzene 103 70-130 Dibromofluoromethane 107 70- 130 Toluene-d8(Surr) 102 70- 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 141 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: MB 660-85123/1-A Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1C125006.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 1000 mL Date Analyzed: 09/25/2009 1957 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result Qual MDL PQL 2-Chlorophenol 2.1 U 2.1 10 2,4-Dichlorophenol 1.8 U 1.8 10 2,4-Dimethylphenol 1.8 U 1.8 10 4,6-Dinitro-2-methylphenol 1.5 U 1.5 50 2,4-Dinitrophenol 6.2 U 6.2 50 2-Nitrophenol 1.2 U 1.2 10 4-Nitrophenol 6.2 U 6.2 50 4-Chloro-3-methylphenol 1.7 U 1.7 10 Pentachlorophenol 1.5 U 1.5 15 Phenol 2.4 U 2.4 4.0 2,4,6-Trichlorophenol 1.9 U 1.9 10 Acenaphthene 1.5 U 1.5 10 Acenaphthylene 1.8 U 1.8 10 Anthracene 1.0 U 1.0 10 Benzo[a]anthracene 1.6 U 1.6 10 Benzo[a]pyrene 0.99 U 0.99 4.0 Benzo[b]fluoranthene 1.6 U 1.6 10 Benzo[g,h,i]perylene 1.1 U 1.1 10 Benzo[k]fluoranthene 1.3 U 1.3 10 Bis(2-chloroethoxy)methane 2.0 U 2.0 10 Bis(2-chloroethyl)ether 2.6 U 2.6 10 Bis(2-ethylhexyl)phthalate 1.3 U 1.3 6.0 4-Bromophenyl phenyl ether 1.7 U 1.7 10 Butyl benzyl phthalate 1.2 U 1.2 10 2-Chloronaphthalene 1.6 U 1.6 10 4-Chlorophenyl phenyl ether 1.8 U 1.8 10 Chrysene 1.2 U 1.2 10 Dibenz(a,h)anthracene 1.0 U 1.0 10 1,2-Dichlorobenzene 1.1 U 1.1 10 1,3-Dichlorobenzene 1.1 U 1.1 10 1,4-Dichlorobenzene 1.2 U 1.2 10 3,3'-Dichlorobenzidine 1.6 U 1.6 20 Diethyl phthalate 2.5 U 2.5 10 Dimethyl phthalate 2.5 U 2.5 10 Di-n-butyl phthalate 2.5 U 2.5 10 2,4-Dinitrotoluene 0.91 U 0.91 10 2,6-Dinitrotoluene 0.72 U 0.72 10 Di-n-octyl phthalate 2.5 U 2.5 10 1,2-Diphenylhydrazine 2.1 U 2.1 10 Fluoranthene 1.2 U 1.2 10 Hexachlorobenzene 1.7 U 1.7 4.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 142 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: MB 660-85123/1-A Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1CI25006.D Dilution: 1.0 Units: ug/L Initial Weight/Volume: 1000 mL Date Analyzed: 09/25/2009 1957 Final Weight/Volume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Result Qual MDL PQL Hexachlorobutadiene 1.0 U 1.0 10 Hexachlorocyclopentadiene 1.2 U 1.2 10 Hexachloroethane 0.85 U 0.85 10 Indeno[1,2,3-cd]pyrene 1.2 U 1.2 10 Isophorone 1.4 U 1.4 10 Naphthalene 1.3 U 1.3 10 Nitrobenzene 1.9 U 1.9 10 N-Nitrosodimethylamine 2.4 U 2.4 10 N-Nitrosodi-n-propylamine 1.9 U 1.9 10 N-Nitrosodiphenylamine 1.6 U 1.6 10 Phenanthrene 1.3 U 1.3 10 Pyrene 1.2 U 1.2 10 1,2,4-Trichlorobenzene 1.2 U 1.2 10 2-Methylnaphthalene 1.6 U 1.6 10 1-Methylnaphthalene 1.3 U 1.3 10 Surrogate %Rec Acceptance Limits 2,4,6-Tribromophenol 91 29-143 2-Fluorobiphenyl 68 36- 124 2-Fluorophenol 80 29- 121 Nitrobenzene-d5 78 34- 130 Phenol-d5 61 25- 128 Terphenyl-d14 85 14- 148 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 143 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Lab Control Sample -Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: LCS 660-85123/2-A Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1CI25007.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 1000 mL Date Analyzed: 09/25/2009 2017 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Spike Amount Result % Rec. Limit Qual 2-Chlorophenol 100 71.6 72 40-130 2,4-Dichlorophenol 100 76.3 76 40- 135 2,4-Dimethylphenol 100 68.1 68 44- 130 4,6-Dinitro-2-methylphenol 100 91.5 91 10-197 2,4-Dinitrophenol 100 60.1 60 10-375 2-Nitrophenol 100 77.1 77 44- 134 4-Nitrophenol 100 64.4 64 19- 130 4-Chloro-3-methylphenol 100 74.6 75 41 - 130 Pentachlorophenol 100 83.1 83 30- 134 Phenol 100 56.1 56 18- 130 2,4,6-Trichlorophenol 100 82.1 82 47- 131 Acenaphthene 100 77.7 78 46- 130 Acenaphthylene 100 82.1 82 51 - 130 Anthracene 100 77.1 77 53- 131 Benzo[a]anthracene 100 78.4 78 46-130 Benzo[alpyrene 100 73.4 73 27-153 Benzo[b]fluoranthene 100 89.9 90 26-167 Benzo[g,h,i]perylene 100 104 104 16-163 Benzo[k]fluoranthene 100 86.7 87 34-155 Bis(2-chloroethoxy)methane 100 72.5 72 39-132 Bis(2-chloroethyl)ether 100 72.6 73 34-135 Bis(2-ethylhexyl)phthalate 100 79.7 80 45-134 4-Bromophenyl phenyl ether 100 82.2 82 46-141 Butyl benzyl phthalate 100 66.2 66 43- 135 2-Chloronaphthalene 100 75.2 75 45- 130 4-Chlorophenyl phenyl ether 100 81.0 81 45- 134 Chrysene 100 71.6 72 50- 130 Dibenz(a,h)anthracene 100 109 109 17-174 1,2-Dichlorobenzene 100 60.5 60 35- 130 1,3-Dichlorobenzene 100 58.2 58 33- 130 1,4-Dichlorobenzene 100 59.0 59 38- 130 3,3'-Dichlorobenzidine 100 1.6 0 10-130 J3 Diethyl phthalate 100 82.2 82 50-132 Dimethyl phthalate 100 78.9 79 52-132 Di-n-butyl phthalate 100 80.0 80 50-144 2,4-Dinitrotoluene 100 76.6 77 38- 131 2,6-Dinitrotoluene 100 75.5 76 54- 132 Di-n-octyl phthalate 100 68.3 68 37-136 Fluoranthene 100 80.7 81 53-140 Hexachlorobenzene 100 81.9 82 35-136 Hexachlorobutadiene 100 58.1 58 34-130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 144 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Lab Control Sample-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: LCS 660-85123/2-A Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1CI25007.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 1000 mL Date Analyzed: 09/25/2009 2017 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Spike Amount Result %Rec. Limit Qual Hexachlorocyclopentadiene 100 32.4 32 10- 130 Hexachloroethane 100 56.2 56 31 - 130 Indenol1,2,3-cdipyrene 100 104 104 17- 171 Isophorone 100 73.5 74 46- 150 Naphthalene 100 70.5 70 42- 130 Nitrobenzene 100 75.4 75 45- 130 N-Nitrosodimethylamine 100 64.0 64 24- 130 N-Nitrosodi-n-propylamine 100 78.0 78 37- 130 N-Nitrosodiphenylamine 100 49.0 49 28- 139 Phenanthrene 100 83.1 83 51 - 140 Pyrene 100 77.7 78 52- 130 1,2,4-Trichlorobenzene 100 62.1 62 39- 130 2-Methylnaphthalene 100 74.5 75 45- 130 1-Methylnaphthalene 100 70.3 70 40- 133 1 f Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 145 of 166 10/13/2009 Quality Control Results J Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: 660-31745-8 Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1C125019.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 1000 mL Date Analyzed: 09/26/2009 0013 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Sample Result/Qual Spike Amount Result %Rec. Limit Qual 2-Chlorophenol 2.0 U 100 30.5 30 40-130 J3 2,4-Dichlorophenol 1.7 U 100 34.3 34 40-135 J3 2,4-Dimethylphenol 1.7 U 100 28.8 29 44-130 J3 4,6-Dinitro-2-methylphenol 1.4 U 100 67.4 67 10-197 2,4-Dinitrophenol 5.8 U 100 47.5 47 10-375 2-Nitrophenol 1.1 U 100 36.8 37 44-134 J3 4-Nitrophenol 5.8 U 100 50.4 50 19-130 4-Chloro-3-methylphenol 1.6 U 100 42.0 42 41 -130 Pentachlorophenol 1.4 U 100 74.0 74 30-134 Phenol 2.3 U 100 23.7 24 18-130 2,4,6-Trichlorophenol 1.8 U 100 47.2 47 47-131 Acenaphthene 1.4 U 100 48.8 49 46-130 Acenaphthylene 1.7 U 100 51.4 51 51 -130 Anthracene 0.94 U 100 65.3 65 53-131 Benzo[a]anthracene 1.5 U 100 60.8 61 46-130 Benzo[a]pyrene 0.93 U 100 46.5 46 27-153 Benzo[b]fluoranthene 1.5 U 100 51.9 52 26-167 Benzo[g,h,i]perylene 1.0 U 100 62.6 63 16-163 Benzo[k]fluoranthene 1.2 U 100 57.8 58 34- 155 Bis(2-chloroethoxy)methane 1.9 U 100 34.1 34 39-132 J3 Bis(2-chloroethyl)ether 2.5 U 100 32.8 33 34-135 J3 Bis(2-ethylhexyl)phthalate 1.2 U 100 56.3 56 45-134 4-Bromophenyl phenyl ether 1.6 U 100 64.3 64 46-141 Butyl benzyl phthalate 1.1 U 100 58.8 59 43- 135 2-Chloronaphthalene 1.5 U 100 42.2 42 45- 130 J3 4-Chlorophenyl phenyl ether 1.7 U 100 57.7 58 45-134 Chrysene 1.1 U 100 54.9 55 50-130 Dibenz(a,h)anthracene 0.94 U 100 64.9 65 17-174 1,2-Dichlorobenzene 1.0 U 100 29.4 29 35-130 J3 1,3-Dichlorobenzene 1.0 U 100 26.6 27 33-130 J3 1,4-Dichlorobenzene 1.1 U 100 26.9 27 38-130 J3 3,3'-Dichlorobenzidine 1.5 U 100 27.2 27 10- 130 Diethyl phthalate 2.4 U 100 64.4 64 50-132 Dimethyl phthalate 2.4 U 100 58.1 58 52-132 Di-n-butyl phthalate 2.4 U 100 71.4 71 50-144 2,4-Dinitrotoluene 0.86 U 100 63.0 63 38-131 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 146 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: 660-31745-8 Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1C125019.D Dilution: 1.0 Units: ug/L Initial WeightNolume: 1000 mL Date Analyzed: 09/26/2009 0013 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Sample Result/Qual Spike Amount Result %Rec. Limit Qual 2,6-Dinitrotoluene 0.68 U 100 56.2 56 54-132 Di-n-octyl phthalate 2.4 U 100 49.1 49 37-136 Fluoranthene 1.1 U 100 72.3 72 53-140 Hexachlorobenzene 1.6 U 100 61.0 61 35-136 Hexachlorobutadiene 0.94 U 100 26.5 26 34-130 J3 Hexachlorocyclopentadiene 1.1 U 100 16.2 16 10-130 Hexachloroethane 0.80 U 100 22.0 22 31 -130 J3 Indeno[1,2,3-cdipyrene 1.1 U 100 62.8 63 17-171 Isophorone 1.3 U 100 39.0 39 46-150 J3 Naphthalene 1.2 U 100 34.0 34 42-130 J3 Nitrobenzene 1.8 U 100 37.4 37 45-130 J3 N-Nitrosodimethylamine 2.3 U 100 27.5 28 24-130 N-Nitrosodi-n-propylamine 1.8 U 100 33.8 34 37-130 J3 N-Nitrosodiphenylamine 1.5 U 100 51.1 51 28-139 Phenanthrene 1.2 U 100 69.7 70 51 -140 Pyrene 1.1 U 100 68.4 68 52-130 1,2,4-Trichlorobenzene 1.1 U 100 30.0 30 39-130 J3 2-Methylnaphthalene 1.5 U 100 38.3 38 45-130 J3 1-Methylnaphthalene 1.2 U 100 36.2 36 40-133 J3 I Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 147 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Duplicate-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: 660-31745-7 Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1C125018.D Dilution: 1.0 Units: ug/L Initial WeighWolume: 1000 mL Date Analyzed: 09/25/2009 2353 Final WeightNolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Sample Result/Qual Result RPD Limit Qual 2-Chlorophenol 2.0 U 2.1 NC 34 U 2,4-Dichlorophenol 1.7 U 1.8 NC 30 U 2,4-Dimethylphenol 1.7 U 1.8 NC 43 U 4,6-Dinitro-2-methylphenol 1.4 U 1.5 NC 33 U 2,4-Dinitrophenol 6.0 U 6.2 NC 63 U 2-Nitrophenol 1.2 U 1.2 NC 24 U 4-Nitrophenol 6.0 U 6.2 NC 44 U 4-Chloro-3-methylphenol 1.6 U 1.7 NC 31 U Pentachlorophenol 1.4 U 1.5 NC 33 U Phenol 2.3 U 2.4 NC 36 U 2,4,6-Trichlorophenol 1.8 U 1.9 NC 22 U Acenaphthene 1.4 U 1.5 NC 35 U Acenaphthylene 1.7 U 1.8 NC 28 U Anthracene 0.96 U 1.0 NC 21 U Benzo[a]anthracene 1.5 U 1.6 NC 34 U Benzo[a]pyrene 0.95 U 0.99 NC 24 U Benzo[b]fluoranthene 1.5 U 1.6 NC 32 U Benzo[g,h,i]perylene 1.1 U 1.1 NC 39 U Benzo[k]fluoranthene 1.2 U 1.3 NC 34 U Bis(2-chloroethoxy)methane 1.9 U 2.0 NC 20 U Bis(2-chloroethyl)ether 2.5 U 2.6 NC 58 U Bis(2-ethylhexyl)phthalate 1.2 U 1.3 NC 26 U 4-Bromophenyl phenyl ether 1.6 U 1.7 NC 26 U Butyl benzyl phthalate 1.2 U 1.2 NC 41 U 2-Chloronaphthalene 1.5 U 1.6 NC 22 U 4-Chlorophenyl phenyl ether 1.7 U 1.8 NC 26 U Chrysene 1.2 U 1.2 NC 31 U Dibenz(a,h)anthracene 0.96 U 1.0 NC 35 U 1,2-Dichlorobenzene 1.1 U 1.1 NC 30 U 1,3-Dichlorobenzene 1.1 U 1.1 NC 26 U 1,4-Dichlorobenzene 1.2 U 1.2 NC 31 U 3,3'-Dichlorobenzidine 1.5 U 1.6 NC 72 U J3 Diethyl phthalate 2.4 U 2.5 NC 49 U Dimethyl phthalate 2.4 U 2.5 NC 31 U Di-n-butyl phthalate 2.4 U 2.5 NC 29 U 2,4-Dinitrotoluene 0.88 U 0.91 NC 32 U 2,6-Dinitrotoluene 0.69 U 0.72 NC 24 U Di-n-octyl phthalate 2.4 U 2.5 NC 33 U 1,2-Diphenylhydrazine 2.0 U 2.1 NC 50 U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 148 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Duplicate-Batch: 660-85123 Method: 8270C Preparation: 3520C Lab Sample ID: 660-31745-7 Analysis Batch: 660-85385 Instrument ID: BSMC5973 Client Matrix: Water Prep Batch: 660-85123 Lab File ID: 1CI25018.D Dilution: 1.0 Units: ug/L Initial WeighWolume: 1000 mL Date Analyzed: 09/25/2009 2353 Final WeighWolume: 1 mL Date Prepared: 09/24/2009 1059 Injection Volume: 1.0 uL Analyte Sample Result/Qual Result RPD Limit Qual Fluoranthene 1.2 U 1.2 NC 24 U Hexachlorobenzene 1.6 U 1.7 NC 31 U Hexachlorobutadiene 0.96 U 1.0 NC 30 U Hexachlorocyclopentadiene 1.2 U 1.2 NC 67 U Hexachloroethane 0.82 U 0.85 NC 35 U Indeno[1,2,3-cd]pyrene 1.2 U 1.2 NC 38 U Isophorone 1.3 U 1.4 NC 33 U Naphthalene 1.2 U 1.3 NC 33 U Nitrobenzene 1.8 U 1.9 NC 21 U N-Nitrosodimethylamine 2.3 U 2.4 NC 31 U N-Nitrosodi-n-propylamine 1.8 U 1.9 NC 30 U N-Nitrosodiphenylamine 1.5 U 1.6 NC 25 U Phenanthrene 1.2 U 1.3 NC 20 U Pyrene 1.2 U 1.2 NC 42 U 1,2,4-Trichlorobenzene 1.2 U 1.2 NC 28 U 2-Methylnaphthalene 1.5 U 1.6 NC 30 U 1-Methylnaphthalene 1.2 U 1.3 NC 50 U Surrogate %Rec Acceptance Limits 2,4,6-Tribromophenol 58 29-143 2-Fluorobiphenyl 42 36-124 2-Fluorophenol 34 29-121 Nitrobenzene-d5 46 34-130 Phenol-d5 30 25-128 Terphenyl-d14 56 14-148 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 149 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85214 Method: 60106 Preparation: 3005A Total Recoverable Lab Sample ID: MB 660-85214/1-A Analysis Batch: 660-85336 Instrument ID: TJA ICP TRACE Client Matrix: Water Prep Batch: 660-85214 Lab File ID: 9I29A Dilution: 1.0 Units: mg/L Initial Weight/Volume: 50 mL Date Analyzed: 09/29/2009 1143 Final Weight/Volume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Result Qual MDL PQL Arsenic 0.0040 U 0.0040 0.010 Cadmium 0.0010 U 0.0010 0.0040 Lead 0.0020 U 0.0020 0.010 Chromium 0.0020 U 0.0020 0.010 Antimony 0.0040 U 0.0040 0.020 Beryllium 0.00050 U 0.00050 0.0020 Thallium 0.0050 U 0.0050 0.020 Nickel 0.0020 U 0.0020 0.0080 Silver 0.0010 U 0.0010 0.0040 Copper 0.0029 U 0.0029 0.010 Zinc 0.0050 U 0.0050 0.020 Selenium 0.0050 U 0.0050 0.020 Lab Control Sample-Batch: 660-85214 Method: 60106 Preparation: 3005A Total Recoverable Lab Sample ID: LCS 660-85214/2-A Analysis Batch: 660-85336 Instrument ID: TJA ICP TRACE Client Matrix: Water Prep Batch: 660-85214 Lab File ID: 9I29A Dilution: 1.0 Units: mg/L Initial Weight/Volume: 50 mL Date Analyzed: 09/29/2009 1149 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 Analyte Spike Amount Result %Rec. Limit Qual Arsenic 1.00 1.01 101 75- 125 Cadmium 1.00 1.05 105 75- 125 Lead 1.00 1.04 104 75- 125 Chromium 0.990 1.00 101 75- 125 Antimony 1.00 0.964 96 75- 125 Beryllium 1.00 1.03 103 75- 125 Thallium 1.00 1.01 101 75- 125 Nickel 1.00 1.04 104 75- 125 Silver 1.00 0.986 99 75-125 Copper 1.00 1.02 102 75-125 Zinc 1.00 1.06 106 75-125 Selenium 1.00 0.962 96 75- 125 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 150 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike/ Method: 6010B Matrix Spike Duplicate Recovery Report-Batch: 660-85214 Preparation: 3005A Total Recoverable MS Lab Sample ID: 660-31745-1 Analysis Batch: 660-85336 Instrument ID: TJA ICP TRACE Client Matrix: Water Prep Batch: 660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial WeighWolume: 50 mL Date Analyzed: 09/29/2009 1207 Final WeighWolume: 50 mL Date Prepared: 09/25/2009 1336 MSD Lab Sample ID: 660-31745-1 Analysis Batch: 660-85336 Instrument ID: TJA ICP TRACE Client Matrix: Water Prep Batch: 660-85214 Lab File ID: 9I29A Dilution: 1.0 Initial Weight/Volume: 50 mL Date Analyzed: 09/29/2009 1213 Final WeightNolume: 50 mL Date Prepared: 09/25/2009 1336 %Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Arsenic 101 101 75-125 0 20 Cadmium 103 103 75-125 0 20 Lead 102 103 75-125 1 20 Chromium 101 102 75-125 1 20 Antimony 96 97 75-125 0 20 Beryllium 103 104 75-125 0 20 Thallium 101 100 75-125 1 20 Nickel 103 103 75-125 0 20 Silver 99 99 75-125 0 20 Copper 102 102 75-125 0 20 Zinc 103 103 75- 125 1 20 Selenium 96 96 75-125 0 20 1 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 151 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85255 Method: 6010B Preparation: 3050B Lab Sample ID: MB 660-85255/1-A Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85255 Lab File ID: 9129B Dilution: 1.0 Units: mg/Kg Initial Weight/Volume: 1.0 g Date Analyzed: 09/29/2009 0847 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte Result Qual MDL PQL Arsenic 0.23 U 0.23 0.50 Cadmium 0.087 U 0.087 0.50 Lead 0.15 U 0.15 0.50 Chromium 0.17 U 0.17 1.0 Lab Control Sample-Batch: 660-85255 Method: 6010B Preparation: 3050B Lab Sample ID: LCS 660-85255/2-A Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85255 Lab File ID: 9I29B Dilution: 1.0 Units: mg/Kg Initial WeighWolume: 1.0 g Date Analyzed: 09/29/2009 0851 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 Analyte Spike Amount Result %Rec. Limit Qual Arsenic 50.0 47.5 95 75-125 Cadmium 50.0 51.1 102 75-125 Lead 50.0 49.3 99 75-125 Chromium 49.5 48.2 97 75-125 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 152 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike/ Method: 6010B Matrix Spike Duplicate Recovery Report-Batch: 660-85255 Preparation: 3050B MS Lab Sample ID: 660-31745-9 Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 0905 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 MSD Lab Sample ID: 660-31745-9 Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85255 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 1.0 g Date Analyzed: 09/29/2009 0910 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1048 %Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Arsenic 88 94 75-125 7 20 Cadmium 94 102 75-125 7 20 Lead 90 99 75-125 8 20 Chromium 89 105 75-125 15 20 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 153 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85267 Method: 6010B Preparation: 3050B Lab Sample ID: MB 660-85267/1-A Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85267 Lab File ID: 9129B Dilution: 1.0 Units: mg/Kg Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1117 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte Result Qual MDL PQL Arsenic 0.77 U 0.77 1.7 Cadmium 0.29 U 0.29 1.7 Lead 0.50 U 0.50 1.7 Chromium 0.57 U 0.57 3.3 Lab Control Sample-Batch: 660-85267 Method: 60106 Preparation: 3050B Lab Sample ID: LCS 660-85267/2-A Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85267 Lab File ID: 9129B Dilution: 1.0 Units: mg/Kg Initial WeighWolume: 0.3 g Date Analyzed: 09/29/2009 1121 Final WeighWolume: 50 mL Date Prepared: 09/28/2009 1144 Analyte Spike Amount Result %Rec. Limit Qual Arsenic 167 162 97 75- 125 Cadmium 167 173 104 75- 125 Lead 167 168 101 75- 125 Chromium 165 162 98 75- 125 P Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 154 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike/ Method: 6010B Matrix Spike Duplicate Recovery Report-Batch: 660-85267 Preparation: 30508 MS Lab Sample ID: 660-31745-29 Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85267 Lab File ID: 9129B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1144 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 MSD Lab Sample ID: 660-31745-29 Analysis Batch: 660-85323 Instrument ID: TJA ICP Client Matrix: Solid Prep Batch: 660-85267 Lab File ID: 9I29B Dilution: 1.0 Initial WeightNolume: 0.3 g Date Analyzed: 09/29/2009 1149 Final WeightNolume: 50 mL Date Prepared: 09/28/2009 1144 % Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Arsenic 92 97 75-125 5 20 Cadmium 99 104 75-125 5 20 Lead 97 102 75-125 5 20 Chromium 94 99 75-125 5 20 e Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 155 of 166 10/13/2009 I Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85254 Method: 7470A Preparation: 7470A Lab Sample ID: MB 660-85254/1-A Analysis Batch: 660-85289 Instrument ID: Hg Analyzer Client Matrix: Water Prep Batch: 660-85254 Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial WeighWolume: 25 mL Date Analyzed: 09/28/2009 1434 Final Weight/Volume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Result Qual MDL PQL Mercury 0.000072 U 0.000072 0.00020 Lab Control Sample-Batch: 660-85254 Method: 7470A Preparation: 7470A Lab Sample ID: LCS 660-85254/2-A Analysis Batch: 660-85289 Instrument ID: Hg Analyzer Client Matrix: Water Prep Batch: 660-85254 Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial Weight/Volume: 25 mL Date Analyzed: 09/28/2009 1436 Final Weight/Volume: 25 mL Date Prepared: 09/28/2009 1047 Analyte Spike Amount Result % Rec. Limit Qual Mercury 0.00100 0.000942 94 80- 120 Matrix Spike/ Method: 7470A Matrix Spike Duplicate Recovery Report-Batch: 660-85254 Preparation: 7470A MS Lab Sample ID: 660-31745-1 Analysis Batch: 660-85289 Instrument ID: Hg Analyzer Client Matrix: Water Prep Batch: 660-85254 Lab File ID: N/A Dilution: 1.0 Initial Weight/Volume: 25 mL Date Analyzed: 09/28/2009 1443 Final WeighWolume: 25 mL Date Prepared: 09/28/2009 1047 MSD Lab Sample ID: 660-31745-1 Analysis Batch: 660-85289 Instrument ID: Hg Analyzer Client Matrix: Water Prep Batch: 660-85254 Lab File ID: N/A Dilution: 1.0 Initial Weight/Volume: 25 mL Date Analyzed: 09/28/2009 1445 Final Weight/Volume: 25 mL Date Prepared: 09/28/2009 1047 %Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Mercury 102 98 80-120 4 20 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 156 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85393 Method: 350.1 Preparation: N/A Lab Sample ID: MB 660-85393/11 Analysis Batch: 660-85393 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial WeightNolume: 1.0 mL Date Analyzed: 09/30/2009 1421 Final WeightNolume: 1.0 mL Date Prepared: N/A Analyte Result Qual MDL PQL Ammonia(as N) 0.010 U 0.010 0.020 Lab Control Sample-Batch: 660-85393 Method: 350.1 Preparation: N/A Lab Sample ID: LCS 660-85393/12 Analysis Batch: 660-85393 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial Weight/Volume: 10 mL Date Analyzed: 09/30/2009 1423 Final WeightNolume: 10 mL Date Prepared: N/A Analyte Spike Amount Result %Rec. Limit Qual Ammonia(as N) 0.500 0.490 98 90- 110 Matrix Spike/ Method: 350.1 Matrix Spike Duplicate Recovery Report-Batch: 660-85393 Preparation: N/A MS Lab Sample ID: 660-31745-1 Analysis Batch: 660-85393 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 10 mL Date Analyzed: 09/30/2009 1425 Final WeightNolume: 10 mL Date Prepared: N/A MSD Lab Sample ID: 660-31745-1 Analysis Batch: 660-85393 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 10 mL Date Analyzed: 09/30/2009 1426 Final WeightNolume: 10 mL Date Prepared: N/A %Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Ammonia(as N) 99 98 90-110 1 30 I P Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 157 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85394 Method: 350.1 Preparation: N/A Lab Sample ID: MB 660-85394/12 Analysis Batch: 660-85394 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial WeighWolume: 1.0 mL Date Analyzed: 09/30/2009 1453 Final WeighWolume: 1.0 mL Date Prepared: N/A Analyte Result Qual MDL PQL Ammonia(as N) 0.010 U 0.010 0.020 Lab Control Sample-Batch: 660-85394 Method: 350.1 Preparation: N/A Lab Sample ID: LCS 660-85394/13 Analysis Batch: 660-85394 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial Weight/Volume: 10 mL Date Analyzed: 09/30/2009 1455 Final Weight/Volume: 10 mL Date Prepared: N/A Analyte Spike Amount Result %Rec. Limit Qual Ammonia(as N) 0.500 0.483 97 90- 110 Matrix Spike/ Method: 350.1 Matrix Spike Duplicate Recovery Report-Batch: 660-85394 Preparation: N/A MS Lab Sample ID: 660-31806-F-1 MS Analysis Batch: 660-85394 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial WeighWolume: 10 mL Date Analyzed: 09/30/2009 1459 Final Weight/Volume: 10 mL Date Prepared: N/A MSD Lab Sample ID: 660-31806-F-1 MSD Analysis Batch: 660-85394 Instrument ID: Autoanalyzer Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 10 mL Date Analyzed: 09/30/2009 1500 Final Weight/Volume: 10 mL Date Prepared: N/A %Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Ammonia(as N) 89 90 90-110 1 30 J3 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 158 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Method Blank-Batch: 660-85136 Method: 353.2 Preparation: N/A Lab Sample ID: MB 660-85136/1 Analysis Batch: 660-85136 Instrument ID: No Equipment Assigned Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial WeighWolume: 50 mL Date Analyzed: 09/23/2009 1000 Final Weight/Volume: 50 mL Date Prepared: N/A Analyte Result Qual MDL PQL Nitrate Nitrite as N 0.10 U 0.10 0.50 Nitrite as N 0.10 U 0.10 0.50 Nitrate as N 0.10 U 0.10 0.50 Lab Control Sample-Batch: 660-85136 Method: 353.2 Preparation: N/A Lab Sample ID: LCS 660-85136/2 Analysis Batch: 660-85136 Instrument ID: No Equipment Assigned Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Units: mg/L Initial WeighWolume: 100 mL Date Analyzed: 09/23/2009 1000 Final WeighWolume: 100 mL Date Prepared: N/A Analyte Spike Amount Result %Rec. Limit Qual Nitrate Nitrite as N 1.00 0.988 99 90- 110 Nitrite as N 1.00 1.07 107 90- 110 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 159 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Matrix Spike/ Method: 353.2 Matrix Spike Duplicate Recovery Report-Batch: 660-85136 Preparation: N/A MS Lab Sample ID: 660-31745-1 Analysis Batch: 660-85136 Instrument ID: No Equipment Assigned Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial Weight/Volume: 50 mL Date Analyzed: 09/23/2009 1000 Final Weight/Volume: 50 mL Date Prepared: N/A MSD Lab Sample ID: 660-31745-1 Analysis Batch: 660-85136 Instrument ID: No Equipment Assigned Client Matrix: Water Prep Batch: N/A Lab File ID: N/A Dilution: 1.0 Initial WeightNolume: 50 mL Date Analyzed: 09/23/2009 1000 Final WeightNolume: 50 mL Date Prepared: N/A Rec. Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual Nitrate Nitrite as N 88 84 90-110 0 30 J3 J3 Nitrite as N 117 118 90-110 1 30 J3 J3 I Calculations are performed before rounding to avoid round-off errors in calculated results. r TestAmerica Tampa Page 160 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 161 of 166 10/13/2009 Quality Control Results Client: ESciences, Inc. Job Number: 660-31745-1 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 162 of 166 10/13/2009 A 77' A m" O' �_ ma TnO4 Dm �4 n g @ m 8 Y lid Zr �' --;.- ----\—\\ !�d r 'i b2. m OJ rB i¢ W$ (ni m n 1111 plia cn ��Q 1 L i t Q 0 3 u, N ew DiD g \ L1 N N N 1 �I VV O 0 Q) % '.. S m 6 O W ., U' n m (..3 2 3 n w 5 ti w ... 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Tit 0 v ..- -113 -- C) c L m p_ r W p. In o M COco 'C �' 0 u a Z N ° 1.: ' a b 0 i . 2. jjLj 1 co "C4 ki,4 - etc m� is; ON3 \ •....r.,_ , , „„,..._ ....i...,. .....k..hiiii.c..iT;', --• 21:1 2 x o ll } f� CQ.) Q r.. a r-L_ U 'V\ 0 Q U1\I\ V\ Am n OJ a f� -,;—• 3a ` :.sQ9 W so- w 1 n 0 3 O o g) g' 0 0 'o g' T o b) i' r E a a� a 5. i5: n n o. 4. 5- o. a o. ... c i kk m = a ai �v 9f. d v O a 4 FIel B fifsi'1S ifili.BiS? 'T•No�u . "� s. v M i 1 $ CAA : ,X50.1-Ammonia(as N) N .g\y mV, N ✓ is� .Aee801OB,7470A (Asi Cd4 cr..�` ta i T 82608-PRIORITY POLLUTANTS� oo X S \ I (g. '7 8270C•Priority Pollutants 3 g n c i x W 80108,7471 A ...Z3 0 a 2 3 - s� en -1 c• it, a Q .L\ t o d -.0 d N a c o 3 a - 0. a a `i.. 1 � 1112. i, W •2 i1 ,4 E{�T� tr 3 I o \ O D sr ,q q_��• pp T�, t ,r 1.41, ••••-. .g c' I• I � 2 ,��nnc--2Q'imOf)wD •c ;01gl}Q{ ,t N. 11 1 FR ,4 S O U_ 0 N '_i" \-Y 1 G > a p 7 N N Q Q 5. G f.Fi 0C nt i) i) i) i 03 ;• N*GC-•1N A(jaO Z; �! 3 55 ( �i gi O : 0 C3�.D 16g1, 0, 3 ...'(-5. N Ms. p C�t/?oOt4 m z CD :Z 9 �5lrOj (nU �• • 1-'1 2 l 1 I I I 1 I 1 1 1 1 - 1 r��C zed--off- O 10713%2009 TestAmerica TM£LEADER IN ENVIROM.:ENTAL'ES`WG PRESERVATION CONFIR ATION FORM papal-) • JOB NUMBER: (.,(e1).- 3/7 Logged In TALS B : , /� P-. ......... Cooler Received on(date) V1' -09 .And Opened By(full name): 1V 1-f'_ C--S\)--in. 1. Shipper (circle one) FEDEX UPS DHL WALK-IN COURIER OTHER: 2. Tracking# () \3. Temperature of rep.sample or temp blank when opened: . 0 Degrees Celsius 4. Number of H2SO4(sulfuric acid)preserved containers: All containers pH<2? \•) � If not please comment below: • 5. Number of HCL(hydrochloric acid)preserved containers: All containers pH<2? If not please comment below: 6. Number of HNO3(nitric acid)preserved containers: • All containers pH<2? V---J If not please comment below: 7. Number of NaOH(sodium hydroxide)preserved containers: All containers pH>12? If not please comment below: 8. Number of Unpreserved containers: Ail containers pH between 6 and 8? v i'.c If not please comment below: 9. Was chlorine present in any of the unpreserved containers? C7 If yes,which samples? FWI-CU-002:09.16 08 1 Revision 1-9/16/08 Page 165 of 166 10/13/2009 Login Sample Receipt Check List Client: ESciences, Inc. Job Number: 660-31745-1 Login Number: 31745 List Source: TestAmerica Tampa Creator: Harrison,Amanda List Number: 1 Question T/F/NA Comment Radioactivity either was not measured or, if measured, is at or below N/A background The cooler's custody seal, if present. is intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True 2.6, 3.9, 2.8, 3.6, and 3.0 degrees C CU-07 COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. False COC does not show all samples. Each soil sample should be 4 seperate samples There are no discrepancies between the sample IDs on the containers and True the COC. Samples are received within Holding Time. True Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True There is sufficient vol. for all requested analyses. incl. any requested True MS/MSDs VOA sample vials do not have headspace or bubble is<6mm (1/4") in True diameter. If necessary. staff have been informed of any short hold time or quick TAT True needs Multiphasic samples are not present. True Samples do not require splitting or compositing. True Is the Field Sampler's name present on COC? True Sample Preservation Verified True TestAmerica Tampa Page 166 of 166 10/13/2009 ENGINEERING Sciences ENVIRONMENTAL 4101, ECOLOGICAL www.esciencesi nc.com